• Title/Summary/Keyword: H2TS

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Conformational Preference of Pseudo-Proline Dipeptide in the Gas Phase and Solutions

  • Park, Hae-Sook;Kang, Young-Kee
    • Proceedings of the Korean Biophysical Society Conference
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    • 2003.06a
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    • pp.74-74
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    • 2003
  • We report here the results on N-acetyl-N'-methylamide of oxazolidine (Ac-Oxa-NHMe) calculated using the ab initio molecular orbital method with the self-consistent reaction field (SCRF) theory at the HF level of theory with the 6-3l+G(d) basis set. The displacement of the $\square$-CH$_2$ group in proline ring by oxygen atom has affected the structure of proline, cis$\^$∼/ trans equilibrium, and rotational barrier. The up-puckered structure is found to be prevalent for the trans conformers of the Oxa amide. The higher cis populations of the Oxa amide can be interpreted due to the longer distance between the acetyl methyl group and the 5-methylene group of the ring for the trans conformer of the Oxa amide than that of the Pro amide. The changes in charge of the prolyl nitrogen and the decrease in electron overlap of the C$\^$∼/ N bond for TS structures seem to play a role in lowering rotational barriers of the Oxa amide compared to that of the Pro amide. The calculated preferences for cis conformers in the order of Oxa > Pro amides and for trans-to-cis rotational barriers in the order of Pro > Oxa amide in water are consistent with experimental results on Oxa-containing peptides. The pertinent distance between the prolyl nitrogen and the N$\^$∼/ H amide group to form a hydrogen bond might indicate that this intramolecular hydrogen bond could contribute in stabilizing the TS structures of Oxa and Pro amides and play a role in prolyl isomerization.

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The Reduction of Waterworks Sludge by Hydrogen Peroxide Treatment (과산화수소 산화처리에 의한 정수슬러지의 감량화)

  • Kwon, Jae-Hyun;Kim, Young-Do;Park, Ki-Young;Lee, Seock-Heon;Kim, II-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.1
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    • pp.123-130
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    • 2007
  • The effects of hydrogen peroxide treatment on the reduction of waterworks sludge were investigated in this study. Sludge treated by peroxidation $H_2O_2$ oxidation) was dewatered using a pressure filter at 3atm. It was observed that $H_2O_2$ treatment at the acidic condition significantly reduce both cake water content and specific resistance to filtration (SRF), indicating the enhancement of dewaterability and filterability. The filterability by hydrogen peroxide treatment at pH 3.5 was better than acidic treatment and became comparable with polymer conditioning. The sludge filterability evaluated by SRF was optimal at a dose 2ml $H_2O_2$/sludge($0.02g\;H_2O_2/gTS$) after adjusting of pH to 3.5. The $H_2O_2$ oxidation at pH 3.5 also produced even more dewatered cake when compared with polymer conditioning. The reduction rate of sludge mass at an optimal condition showed 34% compared with untreated sludge. The effects of peroxidation on sludge properties including zeta potential, bound water and particle size were also evaluated. Peroxidation at the acidic condition reduced both bound water and zeta potential. By $H_2O_2$ combined with sulfuric acid leached iron caused Fenton's reaction, which showed a potential to significantly reduce the amount of solids mass and to produce more compact cake with higher filterability.

Dietary Iron Intake and Body Iron Status of Myocardial Infarction Patients in Chunan Area

  • Kim, Hee-Seon
    • Journal of Community Nutrition
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    • v.1 no.2
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    • pp.140-147
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    • 1999
  • It has been known for some time that elevated body iron could be a risk factor for coronary heart disease. The present study was conducted to determine body iron status and dietary iron intake of patients with myocardial infarction(MI). Seventy five patients from the Chunam area with their first MI history within he past 2 months were recruited. The serum iron concentration, total iron binding capacity(TIBC) and percent transferrin saturation(TS) were selected as indicators of body iron status. Twenty four hour recall was conducted by trained interviewers to asses the dietary intake. Most women (91.3%) showed waist to hip ratio(W/H) greater than 0.85 while 17.3% of men were assessed to have a tendency of abdominal obesity(W/H>0.95). The average BMI of women was 25.80 and that of men was 23.98. The average diet intake of participants was below the recommended dietary allowances (RDA) for most nutrients. He average dietary iron intake was 10.03 mg/day for all subjects while women's iron intake was significantly lower than men's. However, a great proportion of participants (77%) showed a tendency to have normal iron status. About 9% of the participants were assessed as iron deficient and 14% had an iron overload. The mean serum iron concentration was 125 g/dl ranging from 13.3 to 280.6 g/dl. Iron intake from animal sources were significantly associated with body iron status (r=0.257, p=0.026) when TIBC was used as an iron status indicator. When iron status was assessed with TS, it was directly associated with iron intake from animal sources(r=0.278, p=0.05) for he subjects in the normal iron status group. He results of the present study showed that the nutrient intake of Mi patients in Chunan was not quite adequate while iron status was mostly in the normal range. Further studies are needed to investigated whether there is a possible difference in iron metabolism of the MI patients.

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Channel Transition Analysis of Smart HLS with Dynamic Single Buffering Scheme (동적 단일 버퍼링 기법을 적용한 스마트 HLS의 채널변경 분석)

  • Kim, Chong-il;Kang, Min-goo;Kim, Dong-hyun;Kim, In-ki;Han, Kyung-sik
    • Journal of Internet Computing and Services
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    • v.17 no.6
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    • pp.9-15
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    • 2016
  • In this paper, we propose a smart HLS(HTTP Live Stream) platform with dynamic single buffering for the best transmission of adaptive video bit-rates. This smart HLS can optimizes the channel transition zapping-time with the monitoring of bandwidth between HLS server and OTT(Over The Top) client. This platform is designed through the control of video stream due to proper multi-bitrates and bandwidths. This proposed OTT can decode the live and VOD(Video On Demand) videos with the buffering of optimumal bitrate. And, the HLS can be cooperated with a smart OTT, and segmented for the m3u8 files of H.265 MPEG-2 TS(Transport Stream) videos. As a resullt, this single buffer based smart OTT can transmit optimal videos with the maximum data buffering according to the adaptive bit-rate depending on the network bandwidth efficiency and the decoded VOD video, too.

Effect of dopants(Tri-valent, Penta-valent) on the electrical and optical properties of SnO2 based transparent electrodes

  • Kim, G.W.;Sung, C.H.;Seo, Y.J.;Park, K.Y.;Heo, S.N.;Lee, S.H.;Koo, B.H.
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.394-397
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    • 2012
  • In this work, we studied the influence of the dopant elements concentration on the properties of SnO2 thin films deposited by pulsed laser deposition. X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Hall effect measurement and UV-Vis studies were performed to characterize the deposited films. XRD results showed that the films had polycrystalline nature with tetragonal rutile structure. FE-SEM micrographs revealed that the as deposited films composed of dense microstructures with uniform grain size distribution. All the films show n-type conduction and the best transparent conductive oxide (TCO) performance was obtained on 6 wt% Sb2O5 doped SnO2 film prepared at pO2 of 60mtorr and Ts of 500 ℃. Its resitivity, optical transmittance, figure of merit are 7.8 × 10-4 Ω cm, 85% and 1.2 × 10-2 Ω-1, respectively.

Assessment on Environmental Stabilization of Used Open Dumping Landfill - A Case Study of Kamkok Landfill - (사용종료 비위생 매립지의 환경 안정성 평가 - 감곡 매립지 사례 연구 -)

  • Park, Sangchan;Cho, Byeongreal;Jeong, Jihye;Lee, Minhee;Kim, Taeyoung;Park, Jongho
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.6
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    • pp.13-19
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    • 2008
  • The objectives of this paper are to investigate states of these open dumping landfills for managing, utilizing and stabilization of a municipal solid waste landfill site in environmentally secure conditions. The result of the physical analysis of the landfill showed that it is composed of between 29.72-63.84% organic matter, 32.88% vinyl plastic. The environmental assessment of the landfill site confirmed that the landfill is at a maturation phase due to 0.18 of $BOD_5$/CODcr of leachate. VS and FS of TS Was respectively 30.37%, 32.34% and C/N ratio was 21.8. Surface water around landfill was BOD 10.7 mg/g, SS 37.8 mg/g, E-Coli 31,157(MPN/$100m{\ell}$) and Ground water was $COD_{Mn}$ 1.13-1.38 mg/g, $NO_3-N$ 1.025-4.075 mg/g. Leachat indicated T-P 0.002-0.028 mg/g, $NH_3-N$ 4.0-21.0 mg/g. The soil contamination of around landfill didn't appear as below of the regulation of Soil Environment Conservation Act. The Landfill Gas was $CH_4$ 13.25%, $CO_2$ 6.17%, H2S and CO was not detected. Also Surface Water was not detected $CO_2$, $CH_4$, $H_2S$, CO.

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A study on correlations between tongue with skeletal pattern and intermaxillary space in Class II malocclusion adult patients (골격성 II급 성인 부정교합자에서 혀와 두개안면골격 및 악간공간과의 상관관계에 관한 연구)

  • Kang, Hyun-Hee;Park, Soo-Byung
    • The korean journal of orthodontics
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    • v.29 no.5 s.76
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    • pp.575-587
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    • 1999
  • This study was designed to evaluate the correlations between tongue with skeletal pattern and intermaxillary space in Class II malocclusion adult patients. Craniofacial skeletal pattern was analyzed on the lateral cephalometric radiograph and the subjects were devided two groups by facial ratio, the 30 subjects of hyperdivergent group and the 30 subjects of hypodivergent group. The size and posture of tongue and intermaxillary space were measured on the lateral cephalometric radiograph. These data were statistically analyzed to examine significant differences between both groups and compared the correlation between tongue with skeletal measurements and intermaxillary space in each group. The results of this study were as follows. 1. In comparison of the tongue and intermaxillary space, the measurement of TS/IS showed significantly larger in hyperdivergent group and PIH and IS showed significantly larger in hypodivergent group. There were no statistically significant differences in the measurements of the height and posture of tongue. 2. In correlation between tongue with craniofacial skeletal measurements, the length and height of tongue showed the highest correlation with AFH(anterior facial height) in both groups(p<0.01). And that measurements showed high correlation with PFH(posterior facial height) in hypodivergent group. 3. In both groups, most measurements of tongue showed high correlation with intermaxillary space and the height and space of tongue showed high correlation with AIH and PIH(p<0.01).

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Effect of Pb based flux on the Microwave Dielectric Properties of PCFN-PZW System (PCFN-PZW계의 마이크로파 유전 특성에 미치는 Pb계 Flux의 영향)

  • 강동헌;설충의;차훈주;김영호;길상근;조봉희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.12
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    • pp.1027-1032
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    • 2002
  • (Pb$\_$0.4/Ca$\_$0.6/)(Fe$\_$1/2/Nb$\_$1/2/)O$_3$ system was modified by 10 mol% Pb(Zn$\_$1/2/W$\_$1/2/)O$_3$ addition and their sinterability and microwave properties were investigated as a function of the amount of flux (0.975PbO-0.025SnO$_2$). With increasing flux content, single perovskite phase was maintained up to 3 wt% flux addition and further addition led to the presence of Pb-rich second phase which was confirmed by EDS analysis. The apparent densities of PCFN-PZW specimen increased and showed maximum values at 2.5 wt% flux addition for the Ts=1000$^{\circ}C$ and 2.0wt% flux addition for the Ts=1050$^{\circ}C$, respectively. The dielectric constant and Q$.$f values strongly depended on the variation of density and microstructure, where the optimum values of $\varepsilon$$\_$r/ = 91.95, Q$.$f = 5938GHz, TCF = +8.15ppm/$^{\circ}C$ were obtained for the 2.5wt% flux added PCFN-PZW specimen sintered at 1000$^{\circ}C$ for 4h.

Sweating Rates and Thermoregulation in Male and Female Bali Cattle

  • Kasa, I Wayan
    • Asian-Australasian Journal of Animal Sciences
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    • v.10 no.2
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    • pp.201-205
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    • 1997
  • An experiment has been conducted to compare the sweating rate between male and female Bali cattle under tropical conditions in Bali, Indonesia with dry bulb (DB) temperatures varying from 25 to $34.5^{\circ}C$ and relative humidity (RH) 70 to 98%. Rectal temperature (Tr) was significantly different (p < 0.05) between males and females (39.7 vs $39.4^{\circ}C$ compared to 39.2 vs $38.8^{\circ}C$ on weeks 1 and 8 respectively). There were significant effects on RR associated with both $week{\times}sex$ (p < 0.01) and $sex{\times}time$ (p < 0.01) interactions, with values for males higher than females. Skin temperature (Ts) differed significantly between sexes (p <0.05), weeks (p < 0.05) and times (p < 0.01); being lower in females (36 vs $36.4^{\circ}C$). With prolonged working, there were marked increase in RR were recorded after 30 minutes (the overall increase was $12.4^{\circ}C$). Sweating rate (SR) differed significantly between sexes (p < 0.05), weeks (p < 0.01) and times (p < 0.01) during exercise. Females had a lower mean SR ($225.3g/m^2/h$) than males ($238.8g/m^2/h$). With increasing time, the highest SR was achieved after 30 minutes of exercise of $313.3g/m^2/h$.

Preparation of Gelatin Film Containing Grapefruit Seed Extract and Its Antimicrobial Effect (자몽종자 추출물을 함유한 Gelatin Film의 항균 효과)

  • Lim, Geum-Ok;Hong, Youn-Hee;Song, Kyung-Bin
    • Food Science and Preservation
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    • v.16 no.1
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    • pp.134-137
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    • 2009
  • The gelatin film containing grapefruit seed extract (GSE) was prepared by incorporating different amounts (0, 0.02, 0.05, 0.08, 0.1%) of GSE into the film. The tensile strength (TS) of the film increased by the addition of GSE, and water vapor permeability (WVP) of the film decreased. In particular, the gelatin film containing 0.1% GSE had a TS of 10.28 MPa, while the control had 8.68 MPa. WVP of the film containing 0.1% GSE decreased to 2.18 ng m/m2 s Pa, compared to 2.48 ng $m/m^{2}s$ Pa of the control. In addition, incorporation of 0.1% GSE to the gelatin film decreased the populations of Escherichia coli O157:H7 and Listeria monocytogenes by 2.67 and 3.15 log CFU/g, respectively, compared to the control. These results suggest that as a packaging material, gelatin film containing GSE can have antimicrobial activity against pathogenic microorganisms in foods.