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Effect of Pb based flux on the Microwave Dielectric Properties of PCFN-PZW System

PCFN-PZW계의 마이크로파 유전 특성에 미치는 Pb계 Flux의 영향

  • 강동헌 (수원대학교 전자재료공학과) ;
  • 설충의 (수원대학교 전자재료공학과) ;
  • 차훈주 (수원대학교 전자재료공학과) ;
  • 김영호 (수원대학교 전자재료공학과) ;
  • 길상근 (수원대학교 전자공학과) ;
  • 조봉희 (수원대학교 전기공학과)
  • Published : 2002.12.01

Abstract

(Pb$\_$0.4/Ca$\_$0.6/)(Fe$\_$1/2/Nb$\_$1/2/)O$_3$ system was modified by 10 mol% Pb(Zn$\_$1/2/W$\_$1/2/)O$_3$ addition and their sinterability and microwave properties were investigated as a function of the amount of flux (0.975PbO-0.025SnO$_2$). With increasing flux content, single perovskite phase was maintained up to 3 wt% flux addition and further addition led to the presence of Pb-rich second phase which was confirmed by EDS analysis. The apparent densities of PCFN-PZW specimen increased and showed maximum values at 2.5 wt% flux addition for the Ts=1000$^{\circ}C$ and 2.0wt% flux addition for the Ts=1050$^{\circ}C$, respectively. The dielectric constant and Q$.$f values strongly depended on the variation of density and microstructure, where the optimum values of $\varepsilon$$\_$r/ = 91.95, Q$.$f = 5938GHz, TCF = +8.15ppm/$^{\circ}C$ were obtained for the 2.5wt% flux added PCFN-PZW specimen sintered at 1000$^{\circ}C$ for 4h.

Keywords

References

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