• Title/Summary/Keyword: H2Pc

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Laboratory investigations on the effects of acid attack on concrete containing portland cement partially replaced with ambient-cured alkali-activated binders

  • Ramagiri, Kruthi K.;Patil, Swaraj;Mundra, Harsh;Kar, Arkamitra
    • Advances in concrete construction
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    • v.10 no.3
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    • pp.221-236
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    • 2020
  • To reduce the CO2 emissions associated with the manufacture of portland cement (PC), an efficient alternative like an alkali-activated binder (AAB) is the requirement of the industry. To promote the use of AAB in construction activities, a practically implementable mix proportion is required. Owing to the several raw ingredients of AAB concrete and their associated uncertainties, partial replacement of PC by AAB may be adopted instead of complete replacement as per industrial requirements. Hence, the present study aims to determine an optimal proportion for partial replacement of PC with AAB and recommend a technique for it based on site conditions. Three modes of partial replacement are followed: combining all the dry ingredients for AAB and PC followed by the addition of the requisite liquids (PAM); combining the PC and the AAB concrete in two horizontal layers (PAH); and two vertical layers (PAV). 28-day old specimens are exposed to 10% v/v solutions of HCl, H2SO4, and HNO3 to evaluate changes in mechanical, physical, and microstructural characteristics through compressive strength, corrosion depth, and microscopy. Based on deterioration in strength and integrity, PAH or PAV can be adopted in absence of acid attack, whereas PAM is recommended in presence of acid attack.

Electroless Ni Plating on PC to Improve Adhesion by DBD Plasma Treatment

  • Song, T.H.;Lee, J.K.;Park, S.Y.
    • Corrosion Science and Technology
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    • v.4 no.6
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    • pp.222-225
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    • 2005
  • The adhesion strength of metal plating on PC was studied. In this study, surface was treated by chemical agents or DBD(dielectric barrier discharge) plasma to imporve the adhesion. The surface roughness, contact angle, gloss of plating and adhesive strength were measured. Adhesion strengths of Ni plating on prepared PC by NaOH and KOH solution were $12.3kgf/cm^2$ and $7.5kgf/cm^2$, respectively. The highest adhesion strength was obtained in the plasma treated one, $27.8kgf/cm^2$.

EL Properties of OLEDs with Different Crystal Structures of Hole Injection Layers of Copper(II)-phthalocyanine (정공 주입층 Copper(II)-phthalocyanine의 결정 변화에 따른 유기발광소자의 발광특성연구)

  • 임은주;이기진;한우미;이정윤;차덕준;이용산;김진태
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.2
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    • pp.113-119
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    • 2003
  • We report the electrical properties of copper(II)-phthalocyanine(Cu-Pc) as a hole injaction layer in organic light-emitting diode (OLED). OLEDs were constructed by the following material structure : indium tin oxaide (ITO)/ CuPc/ triphenyl-diamine (TPD)/ tris-(8-hydroxyquinoline)aluminum (Alq3)/4-(Dicyanomethlene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM)/ Al. we observed that the change of recombination zone by using a DCM detection thin layer (6 ${\AA}$) in a Alq$_3$ emitting layer. layer. Recombination zone was moved toward the cathode as the hole mobility increased due to the heat-treatment temperature of cupc layer increased.

Hole transport properties of organic EL devices using a copper(II)-phthalocyanine (Copper(II)-phthalocyanine을 이용한 유기 EL 소자의 정공 전송 특성)

  • 한우미;임은주;이정윤;김명식;이기진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.927-930
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    • 2001
  • We studied the electrical properties of Copper(II)-phthalocyanine (Cu-Pc) as a hole transport layer in organic light emitting devices (OLEDs). OLEDs were constructed with ITO/CU-Pc/triphenyl-diamine (TPD)/tris-(8-hydroxyquinoline) aluminum ( Alq$_3$) + 4- (Dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM)/Al. It was consisted of a thin DCM in Alq$_3$emission layer. We observed that the change of recombination zone was moved toward the cathode as the hole mobility increased due to the heat-treatment temperature of Cu-Pc layer increased.

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Transesterification and Compatibilization in the Blends of Bisphenol-A Polycarbonate and Poly(trimethylene terephthalate)

  • Na Sang-Kuwon;Kong Byeong-Gi;Choi Changyong;Jang Mi-Kyeong;Nah Jae-Woon;Kim Jung-Gyu;Jo Byung-Wook
    • Macromolecular Research
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    • v.13 no.2
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    • pp.88-95
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    • 2005
  • Melt blending of Bisphenol A polycarbonate (PC) and poly(trimethylene terephthalate) (PTT) was carried out over the entire composition range. The mixing time was varied up to 90 min. The resulting samples were analyzed by FT-IR, DSC, XRD, DMTA, $^{1}H NMR$, and SEM. The process of transesterification between the two polymers and their resulting compatibilization were observed. The behaviors of the PTT-rich and PC-rich blends were different and an equilibrium was found to exist. Peculiar behavior, which was different from that of the PTT-rich and PC-rich blends, was exhibited by the 50/50 (PTT/PC) blend.

Development of Three-Dimensional Flow Velocity Component Measurement System with Straight-Type Five-Hole Pressure Probe Using Ch Language (Ch를 이용한 직선형 5공 압력 프로브의 3차원 유동속도 계측시스템 개발)

  • Oh, S.H.;Kim, J.K.
    • Journal of Power System Engineering
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    • v.14 no.1
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    • pp.40-46
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    • 2010
  • This paper shows the development process for measuring three-dimensional flow velocity components in a web-browser. The system is developed in an embeddable C/C++ interpreter Ch and Ch-CGI toolkit. The interface for the web-based measurement system consists of a set of web HTML files and Ch files for CGI. All of data in web browser are passed to Ch-CGI script to generate the output of new HTML file. PC-Server and PC-Client can submit measurement parameters and receive the text/graphical results each other. PC-Client can control the test equipment by using a parameters that received from PC-Server. It also can pass the test results between the web-based measurement system. In summary, the designed measurement system is evaluated, the outputs shown well on the web browser.

Development of a PC-based Ship Maneuvering Simulator (소형 컴퓨터를 이용한 선박 조종 시뮬레이터 개발)

  • Lee, C.M.;Kang, C.G.;Gong, I.Y.;Kim, Y.G.
    • Journal of Korean Port Research
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    • v.5 no.2
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    • pp.39-63
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    • 1991
  • A PC-based ship maneuvering simulator was developed which was configured in a high performance IBM PC compatible i486 and i286 computer with a TMS 340 graphic signal processor and 10 MBPS Ethernet Cards. A real-time ship maneuvering simulation program was developed which includes computer generated imagery (CGI) for bird's eye view type and perspective view type. The simulator H/W was designed and manufactured and S/W for interface of various navigation equipments was made Especially, programs for output, analysis, and assessment of simulations results were developed. Communications between PC's are made by using Ethernet bus type LAN system. Simulations could be performed under various environments (current, wind, wave etc.) using data base of harbors and ships. This system can be used for various purposes such as crew's training, harbor and waterway design, and assessment of ship maneuverability in harbor.

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Anticancer and Antioxidant Activities of Coriolus versicolor Culture Extracts Cultivated in the Citrus Extracts. (감귤 농축액에서 배양한 운지버섯 배양추출물의 항산화 및 항암활성)

  • 이세진;문성훈;김택;김진용;서정식;김대선;김율리아;김영준;박용일
    • Microbiology and Biotechnology Letters
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    • v.31 no.4
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    • pp.362-367
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    • 2003
  • Coriolus versicolor was grown in a defined synthetic liquid medium and citrus extracts, and the culture extracts were examined for antioxidant activity, nitrite scavenging activity, and in vitro anticancer activity against HeLa, PC-3, HepG2, and A-549 cells. Whereas the culture extracts obtained from the synthetic medium and the un-inoculated citrus extract showed 60 and 22% of the 1,1-diphenyl-2-picrylhydrazyl radical scavenger activity, the culture extracts obtained from the citrus extracts medium exhibited antioxidant activity up to 89%. The nitrite scavenging activity of the culture extracts obtained from the citrus extracts medium and the synthetic liquid medium, and the un-inoculated citrus extract at pH 1.2 were up to 67, 55, and 34%, respectively. The culture extract obtained from the synthetic liquid medium inhibited the growth of HeLa, PC-3, HepG2, and A-549 up to 66, 23, 18, 10% at 48 h of incubation, respectively; however, the culture extract obtained from the citrus extracts medium inhibited the growth of HeLa, PC-3, HepG2, and A-549 up to 75, 82, 55, and 82%, respectively. As a negative control, the un-inoculated citrus extract was examined in the same way and inhibited the growth of HeLa, PC-3, and HepG2 cells 20, 6, and 15% at 48 h incubation, respectively; the inhibition of A-549 cell growth was negligible. These results clearly showed that the fermentation of C. versicolor in the citrus extracts rather than in the defined synthetic medium significantly enhanced the anticancer activity, antioxidant activity, and nitrite scavenging activity.

Neuronal Cell Protective Effects of Hot Water Extracts from Guava (Psidium guajava L.) Fruit and Leaf (구아바 열매와 잎 열수 추출물의 신경세포 보호효과)

  • Jeong, Chang-Ho;Jeong, Hee-Rok;Choi, Gwi-Nam;Kwak, Ji-Hyun;Kim, Ji-Hye;Park, Soo-Jeong;Kim, Dae-Ok;Shim, Ki-Hwan;Choi, Sung-Gil;Heo, Ho-Jin
    • Food Science and Preservation
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    • v.18 no.1
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    • pp.124-129
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    • 2011
  • PC12 neuronal cell-protective effects of hot water extracts of guava fruit and leaf were evaluated. Total phenolic levels in fruit and leaf were 11.75 and 293.25 mg/g, respectively. Gallic acid, the predominant phenoic, was detected in both extracts. Intracellular reactive oxygen species (ROS) accumulation after $H_2O_2$ treatment was significantly reduced when the hot water extract of guava leaf was added to cell medium, compared to PC12 cells treated with $H_2O_2$ only. In a cell viability assay using 3-(4,5-dimethyl-thiazol-2-yl)-2,5-diphenyl- tetrazoliumbromide (MTT), the hot water extracts of fruit and leaf protected against $H_2O_2$-induced neurotoxicity. The leaf extract was more effective in terms of inhibition of lactate dehydrogenase (LDH) release into medium, compared to the fruit extract. These in vitro data suggest that hot water extracts of guava fruit and leaf may be useful in treatment of neurodegenerative conditions such as Alzheimer's disease.

Inhibition of Tyrosine Hydroxylase by $(1R,9S)-{\beta}-Hydrastine$ Hydrochloride in PC12 cells

  • Yin, Shou-Yu;Kim, Yu-Mi;Lee, Jae-Joon;Jin, Chun-Mei;Yang, Yoo-Jung;Lim, Kyo-Whan;Kang, Min-Hee;Lee, Myung-Koo
    • Natural Product Sciences
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    • v.10 no.3
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    • pp.114-118
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    • 2004
  • It is reported that $(1R,9S)-{\beta}-Hydrastine$ hydrochloride (BHSH) decreased the intracellular dopamine content by inhibiting tyrosine hydroxylase (TH) activity in PC12 cells. In this study, the inhibitory mechanisms on TH activity by BHSH in PC12 cells were investigated. BHSH treatment caused a reduction of TH activity and TH mRNA level in a dose-dependent manner. After the treatment of $20\;{\mu}M$ BHSH, TH activity and TH mRNA content were reduced at 15 min, reached the minimal levels at 6-24 h, and then recovered gradually to the control level. BHSH at $10-50\;{\mu}M$ caused a decrease in the basal intracellular cyclic AMP levels at 10 min in a concentration-dependent manner. In addition, BHSH at $20-100\;{\mu}M$ decreased the basal intracellular $Ca^{2+}$ concentration $([Ca^{2+}]_i)$ immediately in a dose-dependent manner. BHSH also inhibited the 56 mM $K^+ $ depolarization-induced elevation in $[Ca^{2+}]_i$, and blocked caffeine-activated store-operated $Ca^{2+}$ entry in PC12 cells. These data suggest that BHSH inhibits TH activity and TH gene expression, in part, through reducing cyclic AMP content and basal $[Ca^{2+}]_i$ in PC12 cells.