• 제목/요약/키워드: H143

검색결과 690건 처리시간 0.024초

Equilibrium, kinetic and thermodynamic studies of the adsorption of acidic dye onto bagasse fly ash

  • Shouman, Mona A.;Fathy, Nady A.;El-Khouly, Sahar M.;Attia, Amina A.
    • Carbon letters
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    • 제12권3호
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    • pp.143-151
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    • 2011
  • Bagasse fly ash (BFA) is one of the important wastes generated in the sugar industry; it has been studied as a prospective low-cost adsorbent in the removal of congo red (CR) from aqueous solutions. Chemical treatment with $H_2O_2$ was applied in order to modify the adsorbability of the raw BFA. Batch studies were performed to evaluate the influence of various experimental parameters such as dye solution pH, contact time, adsorbent dose, and temperature. Both the adsorbents were characterized by Fourier-transform infrared spectrometer, energy-dispersive X-ray spectrophotometer and nitrogen adsorption at 77 K. Equilibrium isotherms for the adsorption of CR were analyzed by Langmuir, Freundlich and Temkin models using non-linear regression technique. Intraparticle diffusion seems to control the CR removal process. The obtained experimental data can be well described by Langmuir and also followed second order kinetic models. The calculated thermodynamic parameters indicate the feasibility of the adsorption process for the studied adsorbents. The results indicate that BFA can be efficiently used for the treatment of waste water containing dyes.

이중봉 정수압 압출의 실용적 유한요소해석 모델 (A Practical Finite Element Analysis Model for Hydrostatic Extrusion of a Biaxial Bar)

  • 윤상헌;박훈재;김응주;이상목;이종섭;이근안;김용배;이용신
    • 소성∙가공
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    • 제22권3호
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    • pp.143-149
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    • 2013
  • A new finite element model for the hydrostatic extrusion of a biaxial bar is introduced. In this model, a penalty contact algorithm, which is adopted to replace the traction boundary conditions due to the fluid in the container of the extruder, is incorporated into a consistent penalty finite element formulation for the viscoplastic deformation of a work piece during hydrostatic extrusion. Two parameters, introduced in the penalty contact algorithm in this study, a critical penalty contact pressure $P_0$ and a critical penalty contact distance $D_c$, are carefully examined for various process conditions. The proposed finite element model is applied to the hydrostatic extrusion of a Cu-clad Al bar. The extrusion loads and thickness ratios of the clad materials by the proposed model are compared in detail to values from experiments reported in the literature. Finally, it is concluded that the proposed finite element model is useful in practical implementations.

MJO의 다중스케일 분석을 통한 수십년 변동성 (A multi-scale analysis of the interdecadal change in the Madden-Julian Oscillation)

  • 이상헌;서경환
    • 대기
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    • 제21권2호
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    • pp.143-149
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    • 2011
  • A new multi-timescale analysis method, Ensemble Empirical Mode Decomposition (EEMD), is used to diagnose the variation of the MJO activity determined by 850hPa and 200hPa zonal winds from the National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP/NCAR) Reanalysis data for the 56-yr period from 1950 to 2005. The results show that MJO activity can be decomposed into 9 quasi-periodic oscillations and a trend. With each level of contribution of the quasi-periodic oscillation discussed, the bi-seasonal oscillation, the interannual oscillation and the trend of the MJO activity are the most prominent features. The trend increases almost linearly, so that prior to around 1978 the activity of the MJO is lower than that during the latter part. This may be related to the tropical sea surface temperature(SST). It is speculated that the interdecadal change in the MJO activity appeared in around 1978 is related to the warmer SST in the equatorial warm pool, especially over the Indian Ocean.

Characterization of odourous compounds in air, leachate, stream and well in and around Taju-Bello Dumpsite, Lagos, Nigeria

  • Azeez, L.;Oyedeji, O.A.;Abdulsalami, I.O.;Adewuyi, S.O.
    • Advances in environmental research
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    • 제2권2호
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    • pp.143-153
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    • 2013
  • This study investigated the concentrations of odourous compounds in air, leachate, stream and well in and around Taju-Bello dumpsite. Meteorological parameters (temperature, relative humidity, wind velocity) and six odour families comprising sulphur ($H_2S$), ammonia ($NH_3$), aromatic (benzene, toluene, ethylbenzene, styrene, p-xylene, m-xylene), aliphatic (hexane), oxygenated (formaldehyde, acetaldehyde) and halogenated (tetrachloroethene, trichloroethene, carbontetrachloride) compounds were measured. Meteorological parameters suggested low dispersal of pollutants at L1 with possible perspiration and suffocation from exposure to high temperature, relative humidity and low wind velocity. The trend of abundance of odourous compounds at studied locations is of the order dumpsite (L1) > leachate (L4) > 100 m away from dumpsite (L2) > 200 m away from dumpsite (L3) > stream (L5) > well (L6). $H_2S$, Oxygenated and aromatic compounds were the major contributors to odour strength in these locations. Correlation, factor and cluster analyses of the data revealed similarities of sources as biogenics and xenobiotics inherent in the wastes as the main sources of these odourous compounds.

Liquid chromatographic enantioseparation of several amino acids as nitrobenzoxadiazole derivatives on polysaccharide trisphenylcarbamate derived chiral stationary phases

  • Suraj Adhikari;Alisha Bhandari;Wonjae Lee
    • 분석과학
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    • 제36권4호
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    • pp.143-151
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    • 2023
  • Considering the greater role of α-amino acids in our daily lives, the enantiomer resolution of seven α-amino acids derivatized with fluorogenic reagent (4-fluoro-7-nitro-2,1,3-benzoxadiazole, NBD-F) by chiral HPLC on amylose or cellulose trisphenylcarbamate derived chiral stationary phases (CSPs) under simultaneous ultraviolet (UV) and fluorescence (FL) detection was performed. The degree of enantioseparation and resolution was affected by nature and selector backbones of the CSPs as well as the kind of amino acids. Baseline enantiomer separation and resolutions were observed for the enantiomers of all analytes as NBD derivatives especially on coated type amylose tris(3,5-dimethylphenylcarbamate) derived CSPs (Chiralpak AD-H and Lux Amylose-1). The other CSPs also showed good enantioselectivity except for the CSPs (Chiralpak IB, Chiralcel OD-H and Lux Cellulose-1) having cellulose tris(3,5-dimethylphenylcarbamate) as chiral selectors. The developed analytical chiral method was applied to determine the enantiomeric purity of seven commercially available L-α-amino acids and the impurities as D-forms were found to be in the range 0.08-0.87 %, respectively. The intra- and interday accuracy and precision assays showed high accuracy and precision of the developed analytical method. This chiral HPLC method for the enantiomer resolution of amino acids using fluorescent derivatization could be useful for the determination of enantiomeric purity of pharmaceuticals and biological study for amino acid type compounds among chiral drugs.

고강도 H말뚝의 연직 지지력 특성 (The Characteristics of Axial Bearing Capacity for the High Strength H-pile)

  • 신방웅;여병철
    • 한국지반공학회논문집
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    • 제16권2호
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    • pp.135-143
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    • 2000
  • 고강도 H말뚝은 다른 말뚝에 비해 관입성이 우수하며, 경제적으로 시공이 가능하여 도로공사 및 건축공사의 기초말뚝으로 광범위하게 전세계적으로 사용되어지고 있다. 따라서 본 논문에서는 고강도 H말뚝, 강관말뚝 및 PHC 말뚝에 정재하시험과 동재하시험을 실시하여 허용지지력을 비교 분석하였으며, 각각의 말뚝에 대한 동재하시험을 통해 시간경과효과를 평가하였다. 정재하시험과 동재하시험을 비교 분석한 결과 하중-침하곡선이 유사한 것으로 조사되었다. 또한 고강도 H말뚝, 강관 말뚝, PHC 말뚝이 지반내에 향타되었을 때의 허용지지력은 시간이 경과함에 따라 증가하는 것으로 평가되었다. 재하시험 결과 시간경과효과로 인해 지반의 허용지지력이 상승됨을 알 수 있어 앞으로 기초말뚝 설계시 참고자료로 활용할 수 있을 것으로 사료된다.

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