• 제목/요약/키워드: H.A.Z

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Facile Synthesis of ZnO Nanoparticles and Their Photocatalytic Activity

  • Lee, Soo-Keun;Kim, A Young;Lee, Jun Young;Ko, Sung Hyun;Kim, Sang Wook
    • Bulletin of the Korean Chemical Society
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    • 제35권7호
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    • pp.2004-2008
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    • 2014
  • This paper reports the facile synthesis methods of zinc oxide (ZnO) nanoparticles, Z1-Z10, using diethylene glycol (DEG) and polyethylene glycol (PEG400). The particle size and morphology were correlated with the PEG concentration and reaction time. With 0.75 mL of PEG400 in 150 mL of DEG and a 20 h reaction time, the ZnO nanoparticles began to disperse from a collective spherical grain shape. The ZnO nanoparticles were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and a $N_2$ adsorption-desorption studies. The Brunauer-Emmett-Teller (BET) surface areas of Z4, Z5 and Z10 were 157.083, 141.559 and 233.249 $m^2/g$, respectively. The observed pore diameters of Z4, Z5 and Z10 were 63.4, 42.0 and 134.0 ${\AA}$, respectively. The pore volumes of Z4, Z5 and Z10 were 0.249, 0.148 and 0.781 $cm^3/g$, respectively. The photocatalytic activity of the synthesized ZnO nanoparticles was evaluated by methylene blue (MB) degradation, and the activity showed a good correlation with the $N_2$ adsorption-desorption data.

합성 제올라이트를 이용한 pH에 따른 Cu와 Zn 이온의 흡착특성 (Cu and Zn Ions Adsorption Properties at Various pH with a Synthetic Zeolite)

  • 이창한
    • 한국환경과학회지
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    • 제21권7호
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    • pp.805-813
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    • 2012
  • The removal property of Cu and Zn ions by chemical precipitation and adsorption using zeolite(Z-C1) prepared from coal fly ash(CFA) were evaluated in this study. Adsorption kinetic and equilibrium mechanisms described to analyze parameters and correlation factors with Lagergen $1^{st}$ and $2^{nd}$ order model and Langmuir and Freundlich model. Analysis of adsorption kinetics data revealed that the pseudo $2^{nd}$ order kinetics mechanism was predominant. The equilibrium data in pH 3 - 5 were able to be fitted well to a Langmuir model, by which the maximum adsorption capacities($q_{max}$) were determined at 124.9 - 140.1 mg $Cu^{2+}/g$ and 153.2 - 166.9 mg $Zn^{2+}/g$, respectively. We found that Z-C1 has a potential application as absorbents in metal ion recovery with low pH.

A WEIGHTED COMPOSITION OPERATOR ON THE LOGARITHMIC BLOCH SPACE

  • Ye, Shanli
    • 대한수학회보
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    • 제47권3호
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    • pp.527-540
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    • 2010
  • We characterize the boundedness and compactness of the weighted composition operator on the logarithmic Bloch space $\mathcal{L}\ss=\{f{\in}H(D):sup_D(1-|z|^2)ln(\frac{2}{1-|z|})|f'(z)|$<+$\infty$ and the little logarithmic Bloch space ${\mathcal{L}\ss_0$. The results generalize the known corresponding results on the composition operator and the pointwise multiplier on the logarithmic Bloch space ${\mathcal{L}\ss$ and the little logarithmic Bloch space ${\mathcal{L}\ss_0$.

REAL-TIME PERSONAL DOSE MEASUREMENT AND MANAGEMENT SYSTEM RESEARCH IN CHINA

  • Zhang, Z.Y.;Cheng, C.;Liu, Z.S.;Yang, H.T.;Deng, C.M.;Zhang, X.;Guo, Z.J.
    • Journal of Radiation Protection and Research
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    • 제26권3호
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    • pp.281-286
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    • 2001
  • The composition and design of a real-time personal dose measurement and management system are described in this paper. Accordingly, some pertinent hardware circuits and software codes including their operation modes have also been presented.

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EXISTENCE OF SIX SOLUTIONS OF THE NONLINEAR HAMILTONIAN SYSTEM

  • Jung, Tack-Sun;Choi, Q-Heung
    • 호남수학학술지
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    • 제30권3호
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    • pp.443-468
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    • 2008
  • We give a theorem of existence of six nontrivial solutions of the nonlinear Hamiltonian system $\.{z}$ = $J(H_z(t,z))$. For the proof of the theorem we use the critical point theory induced from the limit relative category of the torus with three holes and the finite dimensional reduction method.

Saccharomyces uvarum과 Zymomonas mobilis간의 경쟁적 상호작용 (Possible Competition between S. uvarum and Z. mobilis)

  • 이재흥
    • 한국식품과학회지
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    • 제14권4호
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    • pp.394-396
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    • 1982
  • 발효로부터 생성되는 에타놀에 의해서 균체성장속도가 제한되는 연속식 배양 시스템에서, 에타놀 생성균주인 Saccharomyces uvarum과 Zymomonas mobilisrks의 경쟁적 상호 작용을 연구한 결과 Zymomonas mobilis가 Saccharomyces uvarum에 비하여 에타놀에 대한 내성(耐性)이 크기 때문에 Zymomonas mobilis 만이 생존할 수 있다.

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Palladium(II) Schiff Base Complexes Derived from Allylamine and Vinylaniline

  • Uh, Yoon-Seo;Zhang, Hai-Wen;Vogels, Christopher M.;Decken, Andreae;Westcott, Stephen A.
    • Bulletin of the Korean Chemical Society
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    • 제25권7호
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    • pp.986-990
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    • 2004
  • Condensation of salicylaldehyde $(2-HOC_6H_4C(O)H)$ with allylamine afforded the unsaturated salicylaldimine, $2-HOC_6H_4C(H)=NCH_2CH=CH_2$. Similar reactivity was observed with substituted salicylaldehydes. Further reaction of these Schiff bases with palladium acetate or $Na_2PdCl_4$ afforded complexes of the type $PdL_2$, where L = deprotonated Schiff base. The molecular structure of the parent salicylaldimine palladium complex $[trans-(2-OC_6H_4C(H)=NCH_2CH=CH_2)_2Pd]$ (1) was characterized by an X-ray diffraction study. Crystals of 1 were monoclinic, space group $P2_1/n,\;a\;=\;14.0005(9)\;{\AA},\;b\;=7.2964(5)\;{\AA},\;c\;=\;17.5103(12)\;{\AA},\;{\beta}\;=\;100.189(1)^{\circ}$, Z = 4. Analogous chemistry with 4-vinylaniline also gave novel palladium complexes containing a pendant styryl group. Crystals of $[trans-(2-HOC_6H_4C(H)=N-4-C_6H_4CH=CH_2)_2Pd]$ (4) were monoclinic, space group $P2_1/c$, a = 13.7710(14) ${\AA}$, b = 11.0348(11) ${\AA}$, c = 7.8192(8) ${\AA}$, ${\beta}\;=\;98.817(2)^{\circ}$, Z = 2.

FLY-BY ENCOUNTERS BETWEEN DARK MATTER HALOS IN COSMOLOGICAL SIMULATIONS

  • AN, SUNG-HO;KIM, JEONGHWAN H.;YUN, KIYUN;KIM, JUHAN;YOON, SUK-JIN
    • 천문학논총
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    • 제30권2호
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    • pp.331-333
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    • 2015
  • Gravitational interactions - mergers and fly-by encounters - between galaxies play a key role as the drivers of their evolution. Here we perform a cosmological N-body simulation using the tree-particle-mesh code GOTPM, and attempt to separate out the effects of mergers and fly-bys between dark matter halos. Once close pair halos are identified by the halo finding algorithm PSB, they are classified into mergers ($E_{12}$ < 0) and fly-by encounters ($E_{12}$ > 0) based on the total energy ($E_{12}$) between two halos. The fly-by and merger fractions as functions of redshift, halo masses, and ambient environments are calculated and the result shows the following.(1) Among Milky-way sized halos ($0.33-2.0{\times}10^{12}h^{-1}M{\odot}$), $5.37{\pm}0.03%$ have experienced major fly-bys and $7.98{\pm}0.04%$ have undergone major mergers since z ~ 1; (2) Among dwarf halos ($0.1-0.33{\times}10^{12}h^{-1}M{\odot}$), $6.42{\pm}0.02%$ went through major fly-bys and $9.51{\pm}0.03%$ experienced major mergers since z ~ 1; (3) Milky-way sized halos in the cluster environment experienced fly-bys (mergers) 4-11(1.5-1.7) times more frequently than those in the field since z ~ 1; and (4) Approaching z = 0, the fly-by fraction decreases sharply with the merger fraction remaining constant, implying that the empirical pair/merger fractions (that decrease from z ~ 1) are in fact driven by the fly-bys, not by the mergers themselves.

Umbilicaria vellea 중 페놀성 화합물의 구조 및 항균활성 (The Structure of Phenolic Compounds and Their Antibiotic Activities in Umbilicaria vellea)

  • 민태진;배강규
    • 대한화학회지
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    • 제40권9호
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    • pp.623-629
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    • 1996
  • 지의류에 속하는 Umbiliciaria vellea 중 에탄올 분획의 항균활성 물질을 규명하기 위하여 silica겔 컬럼 크로마토그래피 및 재결정법으로 화합물 I과 II를 순수히 분리정제하여 그 구조와 항균활성을 측정하였다. 정제된 화합물I은 Cryptococcus neoformance 등의 균에 대한 항진균활성과, Pseudomonas aeruginosa등의 균에 대한 항세균 활성이 있었다. 이 물질의 녹는점은 129~132$^{\circ}C$였고, 217, 265 및 330 nm의 UV 최대흡광을 보였다. 그리고 EI-mass에서 측정된 분자이온은 m/z 196이었고, 원소분석 결과 분자식은 $C_{10}H_{12}O_4$였으며 IR 및 NMR 스펙트라로부터 이 물질이 ethyl 2,4-dihydroxy-6-methyl benzoate임을 확인하였다. 화합물 II의 녹는점은 58~59$^{\circ}C$였고, 212, 276 및 282 nm의 UV 최대흡광을 보였다. 이 물질의 분자이온은 m/z 124였고, $C_7H_8O_2$의 분자식을 갖는 5-methyl-1,3-benzenediol임을 확인하였다.

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CERTAIN CLASSES OF INFINITE SERIES DEDUCIBLE FROM MELLIN-BARNES TYPE OF CONTOUR INTEGRALS

  • Choi, Junesang;Agarwal, Praveen
    • 한국수학교육학회지시리즈B:순수및응용수학
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    • 제20권4호
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    • pp.233-242
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    • 2013
  • Certain interesting single (or double) infinite series associated with hypergeometric functions have been expressed in terms of Psi (or Digamma) function ${\psi}(z)$, for example, see Nishimoto and Srivastava [8], Srivastava and Nishimoto [13], Saxena [10], and Chen and Srivastava [5], and so on. In this sequel, with a view to unifying and extending those earlier results, we first establish two relations which some double infinite series involving hypergeometric functions are expressed in a single infinite series involving ${\psi}(z)$. With the help of those series relations we derived, we next present two functional relations which some double infinite series involving $\bar{H}$-functions, which are defined by a generalized Mellin-Barnes type of contour integral, are expressed in a single infinite series involving ${\psi}(z)$. The results obtained here are of general character and only two of their special cases, among numerous ones, are pointed out to reduce to some known results.