• 분석과학
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• 제6권1호
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• pp.39-45
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• 1993

시스-펩티드 모델 화합물인 디케토페라진을 수용액과 $D_2O$에서 320~218nm 사이의 여기 파장을 이용하여 라만 스펙트럼을 측정하였다. 본 연구는 공명 증폭되는 아미드 밴드를 명명하고, 그 증폭 메카니즘을 규명하는 데 목적이 있다. 3개의 공명 증폭된 시스-펩티드 표본밴드가 수용액 상태에서 1676, 1533, $806cm^{-1}$에서 관찰되었고, 이것을 각각 아미드, I, II, S 밴드로 명명하였다. $1533cm^{-1}$ 아미드 II 밴드는 수용액 상태의 공명 라만 스펙트럼에서 가장 큰 밴드였으며, 순수한 C-N 신축운동이며, N-H를 N-D로 치환한 결과 $1520cm^{-1}$로 이동되었다. 이 밴드는 아마도 단백질내에 존재하는 시스형 펩티드를 관찰할 수 있는 표본 밴드가 될 것으로 예상된다. 여기 주파수를 바꾸어 가며 얻은 라만 밴드 크기 변화와, Albrecht A-항 모델로부터 시스 펩티드 라만 밴드가 188nm 근방의 펩티드 ${\pi}-{\pi}^*$ 전자 전이에 의하여 공명 증폭됨을 증명하였다. 이러한 자료를 바탕으로 시스 펩티드 ${\pi}^*$ 들뜬 상태의 기하구조는 전자 바닥 상태와 비교하여 C-N 결합이 늘어난 형태일 것으로 제안하였다.

• 터널과지하공간
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• 제4권2호
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• pp.132-143
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• 1994

Many methods and techniques to reduce ground vibrations are well known. Some of them are to adopt electric millisecond detonators with a sequential blasting machine or an initiating system with an adequate number of delay intervals. The types of electric detonators manufactured in korea include instantaneous, decisecond and millisecond delays but numbers of delay intervals are only limited from No.1 to No.20 respectively. It is not sufficient to control accurately millisecond time with these detonators in tunnel excavation. Sequential fire time refers to adding an external time delay to a detonators norminal firing time to obtain sequential initiation and it is determined by sequential timer setting. To reduce the vibration level, sequential blasting machine(S.B.M) with decisecond detonators was adopted. A total of 134 blasts was recorede at various sites. Blast-to-structure distances ranged from 20.3 to 42.0 meter, where charge weight varied from 0.24 to 0.75 kg per delay. The results can be summarized as follow: 1. The effects of sequential blasting machine on the vibration level are discussed. The vibration level by S.B.M are decreased approximately 14.38~18.05% compare to level of conventional blasting and cycle time per round can be saved. 2. The empirical equations of particle velocity were obtained in S.B.M and conventional blasting. V=K(D/W1/3)-n, where the values for n and k are estimated to be 1.665 to 1.710 and 93.59 to 137 respectively. 3. The growth of cracks due to vibrations are found but the level fall to within allowable value.

• Smart Structures and Systems
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• 제19권1호
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• pp.1-10
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• 2017

The operation of subway trains induces secondary structure-borne vibrations in the nearby underground spaces. The vibration, along with the associated noise, can cause annoyance and adverse physical, physiological, and psychological effects on humans in dense urban environments. Traditional tethered instruments restrict the rapid measurement and assessment on such vibration effect. This paper presents a novel approach for Wireless Smart Sensor (WSS)-based autonomous evaluation system for the subway train-induced vibrations. The system was implemented on a MEMSIC's Imote2 platform, using a SHM-H high-sensitivity accelerometer board stacked on top. A new embedded application VibrationLevelCalculation, which determines the International Organization for Standardization defined weighted acceleration level, was added into the Illinois Structural Health Monitoring Project Service Toolsuite. The system was verified in a large underground space, where a nearby subway station is a good source of ground excitation caused by the running subway trains. Using an on-board processor, each sensor calculated the distribution of vibration levels within the testing zone, and sent the distribution of vibration level by radio to display it on the central server. Also, the raw time-histories and frequency spectrum were retrieved from the WSS leaf nodes. Subsequently, spectral vibration levels in the one-third octave band, characterizing the vibrating influence of different frequency components on human bodies, was also calculated from each sensor node. Experimental validation demonstrates that the proposed system is efficient for autonomously evaluating the subway train-induced ambient vibration of underground spaces, and the system holds the potential of greatly reducing the laboring of dynamic field testing.

• 한국포장학회지
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• 제29권3호
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• pp.175-179
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• 2023

This paper analyzes the vibration characteristics within the cargo compartment of a three-wheeled cargo bike when used on both regular roads and dedicated bicycle lanes. When cargo is loaded into the cargo compartment of a cargo bike and driven on the road, the shocks and vibrations transmitted from the ground can potentially affect the transported goods and even lead to product damage. As the vibration characteristics applied to the cargo compartment may vary depending on the condition of the road, vibration sensors were attached to the cargo bike's cargo compartment for data collection during operation on different road types. According to KS T ISO 13355 standards, the cargo bike can withstand vibrations within the range of 10 Hz to 60 Hz when operating on both bicycle lanes and regular roads. However, it is observed that there are peaks exceeding the profile in the frequency range of 3-6 Hz. In the 70-200 Hz range, the profile is exceeded on both regular roads and bicycle lanes, with a tendency for higher exceedance on bicycle lanes. The Grms value within the frequency range of KS T ISO 13355 is 5.926 m/s² (0.604 Grms). When operating on bicycle lanes with cargo, the Peak envelope optimization PSD value is 6.553 Grms, while on bicycle lanes, it is 7.708 Grms, indicating a difference of at least tenfold.

• 화약ㆍ발파
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• 제33권3호
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• pp.29-50
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• 2015

측정된 지반진동의 최대입자속도 자료에 대한 통계분석을 통해 환산거리 개념에 기초한 안전발파 설계조건식을 구할 수 있다. 국내에서 널리 사용되는 환산거리에는 자승근 환산거리(SRSD)와 삼승근 환산거리(CRSD)의 두 가지가 있다. 하지만 SRSD와는 대조적으로, CRSD의 장약량 함수는 두 회귀식의 유사한 적합도에도 불구하고 두 함수의 교점을 지나면 기하급수적으로 증가하게 된다. 따라서 CRSD의 지나치게 많은 장약량으로 인해 발생할 지도 모를 구조물의 피해를 방지하기 위해 본 논문에서는 CRSD는 어떤 특정한 거리 이내에서만 사용하도록 제한한다. 한편, 진동의 주파수 스펙트럼에 대한 충분한 고려도 없이 PPV로부터 진동레벨(vibration level; VL)을 예측하거나 환산거리에 따라 VL을 추정하려는 시도들이 있다. 이 시도들은 발파공사 과정에서 소음진동관리법을 충족시키려는 목적으로 이루어지는 것으로 보인다. 소음진동관리법은 생활소음과 생활진동을 주로 취급하고 있다. 그러나 원칙적으로 전체 주파수 스펙트럼 상에서는 속도나 가속도 피크치 사이에는 아무런 상관관계도 존재할 수 없다. 따라서 이러한 상관관계나 추정식의 유도작업은 반드시 동일하거나 매우 유사한 주파수 스펙트럼을 지니는 파동들에 한해서 수행되어야 한다. 끝으로, 구조물의 손상은 PPV 수준과 관련이 있는 것으로 알려져 있으므로 구조물에 대한 지반진동 규제기준에서는 주파수대역별 PPV를 사용하는 것이 바람직하다고 본다.

• 센서학회지
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• 제26권2호
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• pp.107-113
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• 2017

Energy source of a piezo-electric harvester is vibration. Sources of vibration are machineries operated with high frequencies, constructions and people operated with low frequencies and etc. In this study, we tried to figure out power generation properties over vibrations upon angles of a piezo-cantilever for applying them to movements of the construction and/or people, which are vibration sources at low frequencies. A uni-morph cantilever with a $59mm{\times}29mm{\times}0.2mm$ piezo-electric element attached on a $71mm{\times}46mm{\times}0.25mm$ copperplate was used. A spring was attached to the lower side of the cantilever and a mass was attached on the opposite side. Also, a structure with a specific angle which is an angle in between the ground and the cantilever was prepared and then, connected to a spring or the cantilever. Then, this structure was divided into the A-type and B-type and excited in the direction of z- axis. After that, the angle between the ground and the cantilever was changed and excited by 1 to 10 Hz upon the existence of a spring and/or a mass to compare power generation properties.

• 대한의용생체공학회:의공학회지
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• 제32권1호
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• pp.61-73
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• 2011

The purpose of this study was to investigate changes in the center of pressure (COP), ground reaction force (GRF) and joint angles of elderly people and young people while stair-descent. The participants in this experiment were 5 elderly people and 5 young people, each of which was asked to descend stairs of three different heights (8 cm, 16 cm, and 32 cm). As they climbed down the stairs, they received vibration stimulation on the lower limb. The change of COP, GRF and joint angles were analyzed during the standing phase. COP decreased as the Achilles tendon and tibialis anterior tendon were vibrated. Vertical GRF increased as the Achilles tendon was vibrated, and the joint angle differed according to vibration stimulation conditions. These results mean that ankle joint, knee joint and hip joint were influenced by the vibrations on the lower limb as the participants descended the stairs. It was concluded that the vibration stimulation on the lower limb allowed the participants to efficiently climb down the stairs.

• Bulletin of the Korean Chemical Society
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• 제34권12호
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• pp.3641-3648
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• 2013

Energy transfer and bond dissociation of $C-H_{methyl}$ and $C-H_{ring}$ in excited toluene in the collision with $H_2$ and $D_2$ have been studied by use of classical trajectory procedures at 300 K. Energy lost by the vibrationally excited toluene to the ground-state $H_2/D_2$ is not large, but the amount increases with increasing vibrational excitation from 5000 and $40,000cm^{-1}$. The principal energy transfer pathway is vibration to translation (V-T) in both systems. The vibration to vibration (V-V) step is important in toluene + $D_2$, but plays a minor role in toluene + $H_2$. When the incident molecule is also vibrationally excited, toluene loses energy to $D_2$, whereas it gains energy from $H_2$ instead. The overall extent of energy loss is greater in toluene + $D_2$ than that in toluene + $H_2$. The different efficiency of the energy transfer pathways in two collisions is mainly due to the near-resonant condition between $D_2$ and C-H vibrations. Collision-induced dissociation of $C-H_{methyl}$ and $C-H_{ring}$ bonds occurs when highly excited toluene ($55,000-70,400cm^{-1}$) interacts with the ground-state $H_2/D_2$. Dissociation probabilities are low ($10^{-5}{\sim}10^{-2}$) but increase exponentially with rising vibrational excitation. Intramolecular energy flow between the excited C-H bonds occurring on a subpicosecond timescale is responsible for the bond dissociation.

• 화약ㆍ발파
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• 제34권2호
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• pp.1-9
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• 2016

본 논문에서는 PLHBM의 환산 거리별 공수에 따른 터널 심발공의 진동감쇠효과를 비교하기 위해 편마암지역에서 V-cut, PLHBM 1공, PLHBM 2공에 대한 현장실험을 수행하였다. 시험결과 얻어진 발파진동추정식을 근거로 하였을 때 진동 감쇠율은 V-cut의 PPV를 기준으로 환산거리 $10{\sim}100m/kg^{1/2}$의 범위에서 PLHBM 1공 적용 시 21.8~61.1%, 2공 적용시 35.7~79.3%로 나타났다. 진동감쇠효과는 환산거리가 증가할수록 작아지는 경향을 보였으며, PLHBM 1~2공은 심발공의 진동감쇠효과가 높은 것으로 나타났다.

• Nuclear Engineering and Technology
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• 제54권11호
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• pp.4146-4158
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• 2022

Ultra-high performance concrete (UHPC) has been widely utilized in military and civil protective structures to resist intensive loadings attributed to its excellent properties, e.g., high tensile/compressive strength, high dynamic toughness and impact resistance. At present, aiming to improve the defects of the traditional vertical concrete cask (VCC), i.e., the external storage facility of spent fuel, with normal strength concrete (NSC) shield, e.g., heavy weight and difficult to fabricate/transform, the feasibility of UHPC applied in the shield of VCC is numerically examined considering its high radiation and corrosion resistance. Firstly, the finite element (FE) analyses approach and material model parameters of NSC and UHPC are verified based on the 1/3 scaled VCC tip-over test and drop hammer test on UHPC members, respectively. Then, the refined FE model of prototypical VCC is established and utilized to examine its dynamic behaviors and damage distribution in accidental tip-over and end-drop events, in which the various influential factors, e.g., UHPC shield thickness, concrete ground thickness, and sealing methods of steel container are considered. In conclusion, by quantitatively evaluating the safety of VCC in terms of the shield damage and vibrations, it is found that adopting the 300 mm-thick UHPC shield instead of the conventional 650 mm-thick NSC shield can reduce about 1/3 of the total weight of VCC, i.e., about 50 t, and 37% floor space, as well as guarantee the structural integrity of VCC during the accidental drop simultaneously. Besides, based on the parametric analyses, the thickness of concrete ground in the VCC storage site is recommended as less than 500 mm, and the welded connection is recommended for the sealing method of steel containers.