• Title/Summary/Keyword: Green emission

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Polymer Phosphorescence Device using a New Green Emitting Ir(III) Complex

  • Lee, Chang-Lyoul;Das, Rupasree Ragini;Noh, Yong-Young;Kim, Jang-Joo
    • Journal of Information Display
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    • v.3 no.1
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    • pp.6-10
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    • 2002
  • We have synthesized a new green Ir(III) complex fac-tris-(3-methyl-2-phenyl pyridine)iridium(III) $Ir(mpp)_3$ and fabricated phosphorescent polymer light-emitting device using it as a triplet emissive dopant in PVK. $Ir(mpp)_3$ showed absorption centered at 388 nm corresponding to the $^1MLCT$ transition as .evidenced by its extinction coefficient of the order of $10^3{\cdot}$ From the PL and EL spectra of the $Ir(mpp)_3$ doped PVK film, the emission maximum was observed at 523 nm, due to the radiative decay from the $^3MLCT$ state to the ground state, confirming a complete energy transfer from PVK to $Ir(mpp)_3$. The methyl substitution has probably caused a red shift in the absorption and emission spectrum compared to $Ir(mpp)_3$. The device consisting of a 2 % doped PVK furnished 4.5 % external quantum efficiency at 72 $cd/m^2$ (current density of 0.45 $mA/cm^2$ and drive voltage of 13.9 V) and a peak luminance of 25,000 $cd/m^2$ at 23.4 V (494 $mA/cm^2$). This work demonstrates the impact of the presence of a methyl substituent at the 3-position of the pyridyl ring of 2-phenylpyridine on the photophysical and electroluminescence properties.

Methods to Reduce Greenhouse Gas for University Buildings to Make a Low-Carbon Green Campus - With Case Study on the 'E' University -

  • Song, Su Min;Peom, Sung Woo;Park, Hyo Soon;Song, Kyoo Dong
    • KIEAE Journal
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    • v.14 no.2
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    • pp.37-46
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    • 2014
  • University buildings are energy-guzzling facility that consume more than 10,000TOE within a campus annually. Even the consumption is on an upswing trend. Behind such high consumption are there cheap power rates for education facility, lack of high-efficiency equipment and ever-increasing use of various information equipment. Being keenly aware that greenhouse gas emission increases due to such rise of energy consumption, the present study carried out a case study. In the case study, the study chose the buildings of E university from top 10 universities that consume energy most in Seoul and examined the current status of their energy consumption and greenhouse gas emission. And then it set the reduction target of greenhouse gas by year. Putting aside a middle and long-termed strategy for later endeavor, it first established the 1st year's implementation plan (2014) for energy saving and greenhouse gas reduction with limited budget and according to greenhouse gas reduction target. The plan is specified as follows. Targets for energy saving are mainly divided into two sectors: machine equipment and electric equipment. 7 ideas were proposed. Three ideas to improve machine equipment are to replace with high-efficiency boilers and chillers and to adjust the position of the cooling tower. By doing so, it was estimated that energy could be saved by 176.34TOE in total and greenhouse gas could be reduced by 370.771t$CO_2$-eq. Four ideas to improve electric equipment include the replacement with LED lights, LED emergency lights and high-efficiency motors and the installation of motion sensors. It was calculated that such replacement could conserve 1,076.08TOE (electric energy) and reduce 2,181.420t$CO_2$-eq (greenhouse gas).

The Study on Analysis of the effect of introducing Bimodal Tram - Comparing with BRT - (바이모달 트램 도입 효과 분석에 관한 연구 - BRT와의 비교분석을 중심으로-)

  • Jang, Jun-Seok;Lee, Jun;Eom, Jin-Ki
    • Proceedings of the KSR Conference
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    • 2010.06a
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    • pp.739-744
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    • 2010
  • As recent traffic policy focuses on reduction of congestion and environmental contamination, with a catch phrase, 'Green Traffic', Low Carbon Green Growth' and 'Sustainable Development', introducing the new eco-friendly transport means including railway has been emerging as critical issue. Included in the new transport means are BRT, Bimodal Tram and LRT, and this study was intended to evaluate and analyze Bimodal, among others, which generates less emission, noise and vibration thanks to hybrid type traction system employed by Bimodal Tram, which is considered a future-oriented system because of eco-friendly features and cost efficiency as well as punctuality and convenient accessibility to bus. Thus in this study, appropriateness of Bimodal Tram comparing to other system(BRT) was suggested, using conversion traffic from the road, traffic speed and CO2 emission at the metropolitan area and large provincial areas as the barometer in evaluation, and furthermore, the measures applicable to introduction strategy that will meet various functional aspects in urban area in the coming days were developed.

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HYBRID LIGHT DUTY VEHICLES EVALUATION PROGRAM

  • Trigui, R.;Badin, F.;Jeanneret, B.;Harel, F.;Coquery, G.;Lallemand, R.;Ousten, JP.;Castagne, M.;Debest, M.;Gittard, E.;Vangraefshepe, F.;Morel, V.;Baghli, L.;Rezzoug, A.;Labbe, J.;Biscalia, S.
    • International Journal of Automotive Technology
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    • v.4 no.2
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    • pp.65-75
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    • 2003
  • A HEV evaluation program, funded by ADEME, was carried out by a group of Laboratories of different specialties in order to evaluate and compare consumption, emission and component technologies of the three first HEVs put on the market (Toyota Prius, Nissan Tino and Honda Insight). This paper presents the results obtained until now. These results show good consumption and emission performance of the tested vehicles compared to conventional ones. The energy management seems to be globally the same for the three vehicles excepting for cold stans where the Insight allows a very earlier stop of the engine compared to the Tino and especially to the Prius. A mapping of the engine consumption of the Prius and the Insight was performed in order to furnish data for the simulation models. The Permanent Magnet motors of the Prius and Tino have different number of pair poles and then different emf at a given speed. The low emf values of the Prius allow operation at high speed with less field weakening control than for the Tino. The inverters of the Prius and the Tino, controlled by a PWM at respectively 5 kHz and 7 kHz switching frequency, are made of IGBTs with high commutation performances.

A Comparative Study on Low-Carbon Port Management of Busan and LA/LB - On the Basis of Port Management Cost - (LA/LB항과 부산항의 저탄소 항만운영에 관한 비교연구 - 비용부담을 중심으로 -)

  • Cho, Dong-Oh
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.16 no.2
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    • pp.223-228
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    • 2010
  • In the midst of worldwide response to climate change, the advanced ports including LA/LB(Los Angeles/Long Beach) has started to reduce carbon emission from port area which has not been targets of interests in the worldwide cooperation. Recently, the Port of Busan has started to reduce carbon emission from the port area under the Green Port Strategy in Korea. However, the low-carbon port management increases the cost of port management and negatively impacts the port competitiveness in the short term. Therefore, the Busan Port Authority is carrying out the low-carbon projects directly and has not transfer the cost to the port users, such as shipowers, cargo owners and terminal operators. However, the Port Authority of LA/LB has transferred the cost at low-carbon port management to customers of port. In this study, comparative analysis on cost of low-carbon port management at Busan and LA/LB is carried out for sustainable port management.

Estimation of CO2 Emission from a Eutrophic Reservoir in Temperate Region (온대지역 부영양 저수지의 이산화탄소 배출량 산정)

  • Chung, Se-Woong;Yoo, Ji-Su;Park, Hyung-Seok;Schladow, S. Geoffrey
    • Journal of Korean Society on Water Environment
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    • v.32 no.5
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    • pp.433-441
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    • 2016
  • Many large dams have been constructed for water supply, irrigation, flood control and hydropower in Korea for the last century. Meanwhile, recent studies indicated that the artificial reservoirs impounded by these dams are major sources of carbon dioxide (CO2) to the atmosphere and relevant to global budget of green house gases. However, limited information is available on the seasonal variations of CO2 evasion from the reservoirs located in the temperate monsoon regions including Korea. The objectives of this study were to estimate daily Net Atmospheric Flux (NAF) of CO2 in Daecheong Reservoir located in Geum River basin of Korea, and analyze the influencing parameters that characterize the variation of NAF. Daily pH and alkalinity (Alk) data collected in wet year (2012) and dry year (2013) were used for estimating the NAFs in the reservoir. The dissolved inorganic carbon (DIC) was computed using the pH and Alk measurements supposing an equilibrium state among the carbonate species. The results showed seasonal variations of NAF; negative NAFs from May to October when the primary production of the reservoir increased with water temperature increase, while positive NAF for the rest of the period. Overall the reservoir acted as sources of CO2 to the atmosphere. The estimated NAFs were 2,590 and 771 mg CO2 m-2d-1 in 2012 and 2013, respectively, indicating that the NAFs vary a large extent for different hydrological years. Statistical analysis indicated that the NAFs are negatively correlated to pH, water temperature, and Chl-a concentration of the reservoir.

A Study on the IMO Regulations regarding GHG Emission from Ships and its Implementation (선박기인 온실가스 배출에 대한 IMO의 규제와 이행방향)

  • Lee, Yun-Cheol;Doo, Hyun-Wook
    • Journal of Navigation and Port Research
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    • v.35 no.5
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    • pp.371-380
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    • 2011
  • Traditionally, UNCLOS stipulates that States have the obligation and responsibility to protect and preserve the marine environment and exercise their rights in Principle of Non-Discrimination with respect to foreign ships visiting to port states. UNFCCC and Kyoto protocol established Common but Differentiated Responsibility as the basis which is established on the historic responsibility. The principle in which IMO is presently developing the regulations of Green House Gas emitted from ships is contradict with the principle of UNFCCC regime. In this paper, the development and the principle of UNFCCC and Kyoto protocol is surveyed and it provides the tendency of the IMO activities regarding GHG emission from ships. Also, through consideration of the problems and restrictions drawn from comparison between two principles, the conclusion suggests the fundamental theory and implementation means in order to carry out the purpose of IMO regulations in accordance with the principles of UNCLOS and IMO Convention.

Effect of Deposition Temperature on the Properties of Eu3+-doped MgMoO4 Phosphor Thin Films (증착 온도가 Eu3+ 이온이 도핑된 MgMoO4 형광체 박막의 특성에 미치는 영향)

  • Kang, Dongkyun;Cho, Shinho
    • Journal of Surface Science and Engineering
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    • v.49 no.1
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    • pp.81-86
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    • 2016
  • $Eu^{3+}$-doped $MgMoO_4$ phosphor thin films were deposited on quartz substrates by radio frequency magnetron sputtering with changing various growth temperatures. The effects of growth temperature on the structure, transmittance, optical band gap, and luminescence of the phosphor thin films were characterized. All the phosphor thin films, irrespective of growth temperature, showed a monoclinic structure with a main (220) diffraction peak. The thin film deposited at a growth temperature of $400^{\circ}C$ indicated an average transmittance of 90% in the wavelength range of 500 ~ 1100 nm and band gap energy of 4.81 eV. The excitation spectra of the phosphor thin films consisted of a broad charge transfer band peaked at 284 nm in the range of 230 ~ 330 nm and two weak peaks located at 368 and 461 nm, respectively. The emission spectra under ultraviolet excitation at 284 nm exhibited a sharp emission peak at 614 nm and several weak bands. All the phosphor thin films showed high asymmetry ratio values, indicating that $Eu^{3+}$ ions incorporated into the host lattice occupied at the non-inversion symmetry sites. The results suggest that the growth temperature plays an important role in growing high-quality phosphor thin films.

Analysis of GHG Reduction Potential on Road Transportation Sector using the LEAP Model - Low Carbon Car Collaboration Fund, Fuel Efficiency, Improving Driving Behavior - (LEAP 모형을 이용한 도로교통부문의 온실가스 감축잠재량 분석 - 저탄소차협력금제도, 연비강화, 운전행태개선을 중심으로 -)

  • Kim, Min wook;Yoon, Young Joong;Han, Jun;Lee, Hwa Soo;Jeon, Eui Chan
    • Journal of Climate Change Research
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    • v.7 no.1
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    • pp.85-93
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    • 2016
  • This study the efficiency of greenhouse gas reduction of 'low carbon car collaboration fund' and its alternative 'control of average fuel efficiency and greenhouse gas', and 'improving driving behavior' were analyzed by using LEAP, long term energy analysis model. Total 4 scenarios were set, baseline scenario, without energy-saving activity, 'low carbon car collaboration fund' scenario, 'fuel efficiency improving scenario', and 'improving driving behavior' scenario. The contents of analysis were forecast of energy demand by scenario and application as well as reduction of greenhouse gas emission volume, and the period taken for analysis was every 1 year during 2015~2030. Baseline scenario, greenhouse gas emission volume in 2015 would be 7,935,697 M/T and 13,081,986 M/T in 2030, increased 64.8%. The analysis result was average annual increase rate of 3.4%. The expected average annual increase rate of other scenarios was, 'low carbon car collaboration fund' scenario 1.7%, 'fuel efficiency improving' scenario 3.0%. and 'improving driving behavior' scenario 3.4%. and these were each 1.7%, 0.3%. 0.3% reduce from baseline scenario. The largest reduction was 'low carbon car collaboration fund' scenario, and there after were 'fuel efficiency improving scenario', and 'improving driving behavior' scenario.

Odor emission characteristics in anaerobic high temperature burial composting of swine carcasses (돼지 사체의 혐기적 고온 매몰퇴비화법에서의 악취발생 특성)

  • Yang, Woo-Young;Lee, Jin-Young;Choi, Yeon-Ju;Ryu, Hee-Wook;Chae, Jeong-Seok;Jeon, Jun-Min
    • Journal of odor and indoor environment
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    • v.16 no.2
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    • pp.187-198
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    • 2017
  • It is very important to treat infected livestock carcasses safely and quickly. In this study, the degradation characteristics and odor generation characteristics of carcasses were investigated during the treatment of swine carcasses using the anaerobic burial composting method. While the carcasses were decomposed, the temperature remained high, at $40{\sim}55^{\circ}C$ on average, and most of the carcasses were decomposed rapidly. The major odor-contributing substances in the buried composting method are sulfuric odor substances such as $H_2S$, $CH_3SH$, dimethyl sulfide (DMS) and dimethyl disulfide (DMDS), and the odor contribution of these substances is 93~99%. Among them, $CH_3SH$, which accounts for about 56~89% of odor contribution, was the most representative indicator substance. Despite the anaerobic digestion process, the methane concentration in the digestion process was as low as 0.5~0.8% at the burial point of the carcass. The odor and methane produced during the decomposition of the carcasses decreased considerably during the discharge to the surface layer through the buried layer consisting of compost. These results suggest that anaerobic high temperature burial composting is one of the most useful methods to treat carcasses of infected livestock.