• Title/Summary/Keyword: Green Hydrogen

검색결과 400건 처리시간 0.019초

액체추력기 촉매베드 크기 결정을 위한 실험적 방법 (Experimental approach for catalyst bed sizing of liquid propellant thruster)

  • 안성용;권세진
    • 한국추진공학회지
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    • 제12권3호
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    • pp.24-33
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    • 2008
  • 진공 작동 조건에서 50 Newton 추력 레벨을 가지는 과산화수소 단일추진제 추력기를 개발하였다. 축소형 추력기를 제작하여 제조한 촉매의 추진제 분해 성능을 평가하였다. 축소형 추력기의 성능 평가 결과로부터 50 Newton 추력을 위한 추진제 유량을 완전히 촉매 분해시키기 위해 필요한 반응기를 설계하였다. 스케일 업을 통해 제작된 추력기는 34.8 g/s의 추진제 유량에서 98%의 특성속도 효율을, 대기압 조건에서 42 Newton의 추력, 123 sec의 비추력 결과를 보임으로써 반응기 스케일 업 과정이 적절함을 확인하였다.

시금치와 마테 분말을 이용한 클로로필 추출과 직물 염색 (Extractions of Chlorophyll from Spinach and Mate Powders and Their Dyeability on Fabrics)

  • 유혜자;안춘순
    • 한국의류학회지
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    • 제37권3호
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    • pp.413-423
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    • 2013
  • Chlorophyll is an abundant pigment found in all green plants, algae, and cyanobacteria. This study uses methanol, acetone and water to extract spinach and mate powders in order to examine the possibility of dyeing animal fibers with chlorophyll without chemical alteration. It was shown that methanol extracts of spinach and mate powders can be effectively used to dye wool and silk fabrics if the extract is mixed with water by methanol:water 65:35 v/v. Compared to methanol extract, the acetone extract showed lower chlorophyll yield and lower dye uptake. Water was not an appropriate solvent for chlorophyll extraction and dyeing. Spinach powder showed a higher dye uptake than mate powder due to the higher chlorophyll content than mate powder. It is possible that the chlorophyll dyeing of wool and silk fabrics is due to the hydrogen bonding between the hydroxy amino acids in fiber and the carbonyl groups of chlorophyll. These carbonyl groups are on the heterocyclic ring and the methyl and ethyl side chains of chlorophyll.

환경적 footprint 분석을 통한 토양경작법과 화학적산화법의 비교 (Comparison of Land Farming and Chemical Oxidation based on Environmental Footprint Analysis)

  • 김윤수;임형석;박재우
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제20권3호
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    • pp.7-14
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    • 2015
  • In this study, land farming and chemical oxidation of a diesel-contaminated site is compared to evaluate the environmental impact during soil remediation using the Spreadsheet for Environmental Footprint Analysis by U.S. EPA. Each remediation process is divided into four phases, consisting of soil excavation, backfill and transportation (Phase 0), construction of remediation facility (Phase 1), remediation operation (Phase 2), and restoration of site and waste disposal (Phase 3). Environmental footprints, such as material use, energy consumption, air emission, water use and waste generation, are analyzed to find the way to minimize the environmental impact. In material use and waste generation, land farming has more environmental effect than chemical oxidation due to the concrete and backfill material used to construct land farming facility in Phase 1. Also, in energy use, land farming use about six times more energy than chemical oxidation because of cement production and fuel use of heavy machinery, such as backhoe and truck. However, carbon dioxide, commonly considered as important factor of environmental impact due to global warming effect, is emitted more in chemical oxidation because of hydrogen peroxide production. Water use of chemical oxidation is also 2.1 times higher than land farming.

CuO가 코팅된 Cu 분말을 혼합한 Camphene 슬러리의 동결건조에 의한 Cu 다공체 제조 (Fabrication of Porous Cu by Freeze-drying Process of Camphene Slurry with CuO-coated Cu Powders)

  • 방수룡;오승탁
    • 한국분말재료학회지
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    • 제21권3호
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    • pp.191-195
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    • 2014
  • This study reports a simple way of fabricating the porous Cu with unidirectional pore channels by freeze drying camphene slurry with Cu oxide coated Cu powders. The coated powders were prepared by calcination of ball-milled powder mixture of Cu and Cu-nitrate. Improved dispersion stability of camphene slurry could be achieved using the Cu oxide coated Cu powders instead of pure Cu powders. Pores in the frozen specimen at $-25^{\circ}C$ were generated by sublimation of the camphene during drying in air, and the green bodies were sintered at $750^{\circ}C$ for 1 h in $H_2$ atmosphere. XRD analysis revealed that the coated layer of Cu oxide was completely converted to Cu phase without any reaction phases by hydrogen heat treatment. The porous Cu specimen prepared from pure Cu powders showed partly large pores with unidirectional pore channels, but most of pores were randomly distributed. In contrast, large and aligned parallel pores to the camphene growth direction were clearly observed in the sample using Cu oxide coated Cu powders. Pore formation behavior depending on the initial powders was discussed based on the degree of powder rearrangement and dispersion stability in slurry.

다양한 동결제를 이용하여 동결건조 공정으로 제조한 Cu 다공체의 기공구조 특성 (Freeze Drying Process and Pore Structure Characteristics of Porous Cu with Various Sublimable Vehicles)

  • 이규휘;오승탁;석명진;정영근
    • 한국분말재료학회지
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    • 제27권3호
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    • pp.198-202
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    • 2020
  • The effect of sublimable vehicles on the pore structure of Cu fabricated by freeze drying is investigated. The 5 vol% CuO-dispersed slurries with camphene and various camphor-naphthalene compositions are frozen in a Teflon mold at -25℃, followed by sublimation at room temperature. After hydrogen reduction at 300℃ and sintering at 600 ℃, the green bodies of CuO are completely converted to Cu with various pore structures. The sintered samples prepared using CuO/camphene slurries show large pores that are aligned parallel to the sublimable vehicle growth direction. In addition, a dense microstructure is observed in the bottom section of the specimen where the solidification heat was released, owing to the difference in the solidification behavior of the camphene crystals. The porous Cu shows different pore structures, such as dendritic, rod-like, and plate shaped, depending on the composition of the camphornaphthalene system. The change in pore structure is explained by the crystal growth behavior of primary camphor and eutectic and primary naphthalene.

HFC-152a와 HFC-1523에 $CF_3 I$를 혼합한 공비혼합냉매 특성에 관한 연구 (A Study on the Refrigerant Characteristics of the HFC-l52a, and Azeotrope Mixed with $CF_3 I$)

  • 이종인;하옥남;김재열;이연신;권일욱
    • 한국공작기계학회논문집
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    • 제10권6호
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    • pp.102-108
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    • 2001
  • To prevent green house effect and destruction of an ozone layer, an ozone destruction potential(OBP) must be zero and a refrigerant for low global warming potential(GWP) is needed. HFC-l34a, in which hydrogen is mixed instead of chlorine is a refrigerant used for automobile conditioners and its destruction potential is ecologically zero. However, it is not consid- ered as a perfect substitutive refrigerant as its GWP is high. It is studied refrigerant mixtures in which HFC-l52a and $CF_3 I$ in HFC-l52a with low GWP and zero ODP are mixed by experimentally and concluded as follows: 1) With the variation of speed of compressor outside temperature and flow rate, 7he heat of evaporator and compressor and coefficient of perfor- mance was varied, and influenced the air conditioner. 2) The pressure of evaporator was decreased with increasing the speed of compressor and the pressure of evaporator with the refrigerant HFC-l52a was higher 24% than that of azotrope refrigerant mixed with $CF_3 I$

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Protective Effect of EGCG Against Reactive Oxygen Species-induced Stress

  • Ha, Jung-Sun;Kim, Jeong-Hee
    • International Journal of Oral Biology
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    • 제30권3호
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    • pp.77-84
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    • 2005
  • EGCG[(-)-epigallocatechin gallate], is a major component of green tea has been considered as a major antioxidant constituent. It has been considered as potential chemopreventive and chemotherapeutic agents. However, very little is known about the cellular actions by which EGCG mediates its therapeutic effects. Various aspects of antioxidant activity of EGCG were evaluated in this study. EGCG itself did not show significant cytotoxicity. Significant 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging activity was observed in all ranges of concentration ($0.8-100{\mu}g/ml$) used in this study. Protective effect of EGCG against hydrogen peroxide induced cell death was observed. Relatively high lipid peroxidation inhibitory activity were detected ($IC_{50}$ was about $20{\mu}g/ml$). EGCG also dose-dependently enhanced the activities of superoxide dismutase (SOD), catalase (CAT) and glutathione peroxidase (GPX) in V79-4 cells. In concentrations of $100{\mu}g/ml$ of EGCG, activities of SOD, CAT and GPX were measured as 36.9 U/mg of protein, 22.9 U/mg of protein and 17.8 U/mg of protein, respectively. When these values were compared with those of the control groups (24.9 U/mg of protein, 14.9 U/mg of protein and 11.7 U/mg of protein), the relative increases were calculated as 48, 54 and 52%, respectively. Taken together, our findings suggest that EGCG can act as an antioxidant by scavenging radicals and enhancing antioxidant enzyme activities.

Effect of Noble Metals on Hydrogen Sensing Properties of Metal Oxide-based Gas Sensors

  • Mirzaei, Ali;Bang, Jae Hoon;Kim, Sang Sub;Kim, Hyoun Woo
    • 센서학회지
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    • 제29권6호
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    • pp.365-368
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    • 2020
  • As a green and abundant source of energy, H2 has attracted the attention of researchers for use in different applications. Nevertheless, it is highly flammable, and because of its significantly small size, extreme attention is needed to detect its leakage. In this review, we discuss different effects of noble metals on the H2 gas response and performance of metal oxide-based gas sensors. In this regard, we discuss the effects of noble metals, in combination with metal oxides, on H2 gas detection. The catalytic activity towards H2 gas and the formation of heterojunctions with metal oxides are the main contributions of noble metals to the sensing improvement of H2 gas sensors. Furthermore, in the special case of Pd and somewhat Pt, the formation of PdHx and PtHx also affects the H2 sensing performance. This review paper provides useful information for researchers working in the field of H2 gas detection.

개질기용 Anode Off Gas의 연소특성에 관한 연구 (Combustion Characteristic of Anode Off Gas for Fuel Cell Reformer)

  • 이필형;황상순
    • 한국연소학회지
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    • 제17권4호
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    • pp.5-10
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    • 2012
  • The reformer system is a chemical device that drives the conversion of hydrocarbon to hydrogen rich gas under high temperature environment($600-1,000^{\circ}C$). Generally, NG(Natural Gas) or AOG(Anode Off Gas) is used as fuel of fuel cell reformer combustion system. The experimental study to analyze the combustion characteristics of a premixed ceramic burner used for 0.5-1.0 kW fuel cell reformer was performed. Ceramic burner experiments using NG and AOG were carried out to investigate the flame stability characteristics by heating capacity, equivalence ratio and different fuels respectively. The results show that surface flames can be classified into green, red, blue and lift-off flames as the equivalence ratio of methane-air mixture decreases. And the stable flames can be established using NG and AOG as reformer fuel in the perforated ceramic burner. In particular, the blue flame is found to be stable at a lean equivalence ratio under different mixture conditions of NG and AOG for the 0.5 to 1.0 kW fuel cell system power range. NOx emission is under 60 ppm between 0.70 to 0.78 of equivalence ratio and CO emission is under 50 ppm between 0.70 to 0.84 of equivalence ratio.

Advanced estimation and mitigation strategies: a cumulative approach to enteric methane abatement from ruminants

  • Islam, Mahfuzul;Lee, Sang-Suk
    • Journal of Animal Science and Technology
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    • 제61권3호
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    • pp.122-137
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    • 2019
  • Methane, one of the important greenhouse gas, has a higher global warming potential than that of carbon dioxide. Agriculture, especially livestock, is considered as the biggest sector in producing anthropogenic methane. Among livestock, ruminants are the highest emitters of enteric methane. Methanogenesis, a continuous process in the rumen, carried out by archaea either with a hydrogenotrophic pathway that converts hydrogen and carbon dioxide to methane or with methylotrophic pathway, which the substrate for methanogenesis is methyl groups. For accurate estimation of methane from ruminants, three methods have been successfully used in various experiments under different environmental conditions such as respiration chamber, sulfur hexafluoride tracer technique, and the automated head-chamber or GreenFeed system. Methane production and emission from ruminants are increasing day by day with an increase of ruminants which help to meet up the nutrient demands of the increasing human population throughout the world. Several mitigation strategies have been taken separately for methane abatement from ruminant productions such as animal intervention, diet selection, dietary feed additives, probiotics, defaunation, supplementation of fats, oils, organic acids, plant secondary metabolites, etc. However, sustainable mitigation strategies are not established yet. A cumulative approach of accurate enteric methane measurement and existing mitigation strategies with more focusing on the biological reduction of methane emission by direct-fed microbials could be the sustainable methane mitigation approaches.