• Title/Summary/Keyword: Grain Size Analysis

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Characterization of Ga-doped ZnO thin films prepared by RF magnetron sputtering method (RF 마그네트론 스퍼터링법으로 합성된 Ga-doped ZnO 박막의 특성평가)

  • Yun, Young-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.2
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    • pp.73-77
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    • 2021
  • Ga-doped ZnO thin films by RF magnetron sputtering process were synthesized according to the deposition conditions of O2 and Ar atmosphere gases, and rapid heat treatment (RTA) was performed at 600℃ in an N2 atmosphere. The thickness of the deposited ZnO : Ga thin film was measured, the crystal phase was investigated by XRD pattern analysis, and the microstructure of the thin film was observed by FE-SEM and AFM images. The intensity of the (002) plane of the X-ray diffraction pattern showed a significant difference depending on the deposition conditions of the thin films formed by O2 and Ar atmosphere gas types. In the case of a single thin f ilm doped with Ga under O2 conditions, a strong diffraction peak was observed. Under O2 and Ar conditions, in the case of a multilayer thin film with Ga doping, only a peak on the (002) plane with a somewhat weak intensity was shown. In the FE-SEM image, it was observed that the grain size of the surface of the thin film slightly increased as the thickness increased. In the case of a multilayer thin film with Ga doping under O2 and Ar atmosphere conditions, the specific resistance was 6.4 × 10-4 Ω·cm. In the case of a single thin film with Ga doping under O2 atmosphere conditions, the resistance of the thin film decreased. The resistance decreased as the thickness of the Ga-doped ZnO thin film increased to 2 ㎛, showing relatively a low specific resistance of 1.0 × 10-3 Ω·cm.

A Study on the Microstructure and Magnetic Properties of Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8 Nanocrystalline Soft Magnetic Alloys with varying P Content (Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8 나노결정질 연자성 합금의 P함량에 따른 미세구조 및 자기적 특성 변화 관찰에 관한 연구)

  • Im, Hyun Ah;Bae, Kyoung-Hoon;Nam, Yeong gyun;An, Subong;Yang, Sangsun;Kim, Yong-Jin;Lee, Jung Woo;Jeong, Jae Won
    • Journal of Powder Materials
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    • v.28 no.4
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    • pp.293-300
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    • 2021
  • We investigate the effect of phosphorous content on the microstructure and magnetic properties of Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8 (x = 1-4 at.%) nanocrystalline soft magnetic alloys. The simultaneous addition of Cu and P to nanocrystalline alloys reportedly decreases the nanocrystalline size significantly, to 10-20 nm. In the P-containing nanocrystalline alloy, P atoms are distributed in an amorphous residual matrix, which suppresses grain growth, increases permeability, and decreases coercivity. In this study, nanocrystalline ribbons with a composition of Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8 (x = 1-4 at.%) are fabricated by rapid quenching melt-spinning and thermal annealing. It is demonstrated that the addition of a small amount of P to the alloy improves the glass-forming ability and increases the resistance to undesirable Fex(B,P) crystallization. Among the alloys investigated in this work, an Fe83.2Si5B10P1Cu0.8 nanocrystalline ribbon annealed at 460℃ exhibits excellent soft-magnetic properties including low coercivity, low core loss, and high saturation magnetization. The uniform nanocrystallization of the Fe83.2Si5B10P1Cu0.8 alloy is confirmed by high-resolution transmission electron microscopy analysis.

Analysis on Characteristics of Pigments Manufactured with Various Neorok Produced from Mt. Gwangjeongsan, Pohang (포항 광정산 일대 산출 뇌록으로 제조한 안료의 특성 분석)

  • Mun, Seong Woo;Kang, Young Seok;Kim, Ji Sun;Hwang, Ga-Hyun;Park, Ju Hyun;Lee, Sun Myung;Jeong, Hye Young
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.533-540
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    • 2020
  • Mt. Neoseongsan (NSS) is the only natural Neorok source in Korea. The geological, historical, and cultural values of NSS were recognized in 2013, and NSS has since been designated and maintained as a natural monument (No. 547), which has restricted the research and utilization of NSS Neorok. The limited NSS Neorok supply has hindered the restoration research of traditional pigments. Recently, a large amount of Neorok has been mined from Mt. Gwangeongsan (GJS) and is expected to be the main supply source of Neorok for restoring traditional pigments. Therefore, this study analyzed the characteristics of NSS- and GJS-Neorok-based pigments to evaluate the feasibility of substituting GJS Neorok for NSS Neorok in pigments. The NSS Neorok was mostly comprised of celadonite, whereas the GJS Neorok included minerals containing glassy phases such as celadonite, cristobalite, tridymite, etc. Because both Neorok samples were vitrified under identical conditions, the GJS Neorok grains were larger than the NSS Neorok ones. The GJS Neorok pigment showed that the chromaticity, grain size, oil absorption, and stability varied depending on the mineral types and contents. In particular, GJS-2 and NSS Neorok showed similar mineral compositions, physical properties, and stabilities, suggesting that GJS-2 can be substituted for NSS Neorok, which has been difficult to source and utilize ever since NSS was designated as a natural monument.

Characteristics of Macro Benthic Community in the Subtidal Zone of Muan Bay on Summer and Health Assessment by using AZTI Marine Biotic Index (AMBI) and Water Quality Index (WQI) (하계 무안만 조하대 저서동물군집 특성 및 AZTI의 해양생물지수(AMBI)와 수질평가지수(WQI)를 이용한 건강성 평가)

  • Oh, Jun Ho;Lee, Kyoung Seon
    • Journal of Marine Life Science
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    • v.7 no.1
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    • pp.21-28
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    • 2022
  • Benthic animals are important indicators in benthic environmental quality assessment. This study investigated the environmental characteristics and the distribution pattern of benthic animals, and assessed the benthic ecosystem using AMBI (AZTI's marine biotic index) and WQI (water quality index) in the subtidal zone of Muan bay. Samplings were collected from 10 stations in the subtidal zone of Muan bay on summer. In the upper area of Muan bay, grain size was finer and organic content was higher than those of in the lower area. The pollution indicator organism such as Musculista senhousia, Theora fragilis and Lumbrineris longifolia were dominant at some stations. The benthic community was distinguished into three groups of upper, center and lower area of Muan bay, and which were coincided with the results by correlation analysis between organic matter content and benthic health assessment (WQI and AMBI). As a result of this study, the health condition of the subtidal zone in Muan bay were good. However, from the results that benthic animals were not evenly distributed, and also the opportunistic species appeared, the load of organic matter in Muan bay seems to be increasing.

Physical and Mineralogical Properties of Pottery-Making Soils in Korea (국내 도자기용 태토의 토질 및 광물 특성)

  • Kim, Hak Joon;Lee, Yong Cheon;Lee, Yu Jin;Lee, Ho Jeong;Jeong, Chan Ho
    • The Journal of Engineering Geology
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    • v.32 no.4
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    • pp.685-696
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    • 2022
  • Although the use of pottery-making soils has a long history, its use in the pottery industry requires that physical and geotechnical properties of the materials be established to define the suitability for various purposes. The main purpose of this study is to identify the different types of clays and mineral composition and to perform the geotechnical evaluation of the clays for making pottery products. Soils investigated in this study include raw materials used for making Baekja (white porcelains), Chungja (celadons), Buncheong, Sancheong, and Johyung. Pottery-making soils are manufactured by using different types of soils and sold by individual ceramic clay company. This study includes physical tests of soil and chemical analysis of major elements using XRF and XRD instrumentation. Grain size distributions, mineralogical composition, and a range of plasticities of soils for making different types of potteries are presented. Correlations between specific type of pottery clays and geotechnical and mineralogical characteristics are determined by comparing the test results. Since quantitative research using laboratory tests for pottery-making soils are rarely performed in Korea, further research should be done in the future to improve the Korean pottery industry.

Distribution and Origin of Carbonate Sediments near Dok Island: Preliminary Study (독도주변 탄산염퇴적물의 분포와 성인: 예비조사 결과)

  • Woo, Kyug-Sik;Ji, Hyo-Seon;Kim, Lyoun;Jeon, Jin-A;Park, Jae-Suk;Park, Heung-Sik;Kim, Dong-Seon;Park, Chan-Hong
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.14 no.3
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    • pp.171-180
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    • 2009
  • Based on the constituent analysis of sediments near Dok Island, the origin and sedimentary facies were Investigated. The sediments are mainly from originated from volcanic and volcaniclastic rock fragments derived from Dok Island and carbonate sediments formed by a variety of shallow-dwelling organisms that secreted calcareous skeletons. Carbonate producers include mollusks (bivalves and gastropods), encrusting & branching bryozoans, encrusting & segmented red algae, worm tubes, barnacles, diatoms, sponge spicules and echinoderm fragments. The distribution and relative amount of these constituents are basically dependent upon water depth and grain size even though local variations can be observed within the same depth interval. Five sedimentary facies can be divided: nearshore facies (<20 m), neritic facies ($20{\sim}100m$), upper transitional facies ($100{\sim}200m$), lower transitional facies ($200{\sim}700m$), and hemipelagic facies (>700 m). The sediments that were sampled below the water depth of 2,000 m still contain a significant amount of carbonates (ca. $10{\sim}20%$), implying that the carbonate compensation depth in the East Sea may well exceed this water depth.

High-Frequency Bottom Loss Measured at Near-Normal Incidence Grazing Angle in Jinhae Bay (진해만에서 측정된 높은 수평입사각에서의 고주파 해저면 반사손실)

  • La, Hyoung-Sul;Park, Chi-Hyung;Cho, Sung-Ho;Choi, Jee-Woong;Na, Jung-Yul;Yoon, Kwan-Seob;Park, Kyung-ju;Park, Joung-Soo
    • The Journal of the Acoustical Society of Korea
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    • v.29 no.4
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    • pp.223-228
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    • 2010
  • High-frequency bottom loss measurements for grazing angle of $82^{\circ}$ in frequency range 17-40 kHz were made in Jinhae bay in the southern part of Korea. Observations of bottom loss showed the strong variation as a function of frequency, which were compared to the predicted values using two-layered sediment reflection model. The geoacoustic parameters including sound speed, density and attenuation coefficient for the second sediment layer were predicted from the empirical relations with the mean grain size obtained from sediment core analysis. The geoacoustic parameters for the surficial sediment layer were inverted using Monte Carlo inversion algorithm. A sensitivity study for the geoacoustic parameters showed that the thickness of surficial sediment layer was most sensitive to the variation of the bottom loss.

Chemo-Mechanical Analysis of Bifunctional Linear DGEBA/Linear Amine (DDM, DDS) Resin Casting Systems (DGEBA/방향족 아민(DDM, DDS) 경화제의 벤젠링 사이의 관능기 변화가 물성 변화에 미치는 영향에 대한 연구)

  • 명인호;정인재;이재락
    • Composites Research
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    • v.12 no.4
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    • pp.71-78
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    • 1999
  • To determine the effect of chemical structure of linear amine curing agents on thermal and mechanical properties, standard epoxy resin DGEBA was cured with diaminodiphenyl methane (DDM), diaminodiphenyl sulphone (DDS) in a stoichiometrically equivalent ratio. From this work, the effect of aromatic amine curing agents. In contrast, the results show that the DGEBA/DDS cure system having the sulfone structure between the benzene rings had higher values in the conversion of epoxide, density, shrinkage (%), glass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBA/DDM cure system having methylene structure between the benzene rings, whereas the DGEBA/DDM cure system presented higher values in the maximum exothermic temperature, thermal expansion coefficient, and thermal stability. These results are caused by the relative effects of sulfone group having strong electronegativity and methylene group having (+) repulsive property and stem from the effect of the conversion ratio of epoxide group. The result of fractography shows that the each grain size of the DDM/DGEBA system with feather-like structure is larger than that of the DDS/DGEBA system.

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Diversification of Rice Quality for Processing. Physicochemical Characteristics and Inheritance of Floury Endosperm Mutants (특수 가공용 미질개발 : 분상질배유 돌연변이 계통의 이화학적특성과 유전)

  • Kim, Kwang-Ho;Koh, Hee-Jong;Lee, Jang-Hoon;Park, Sun-Zik;Heu, Mun-Hue
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.38 no.3
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    • pp.264-274
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    • 1993
  • This study was carried out to assess the agronomic characters and physicochemical properties of floury and chalky-endosperm mutant lines induced by chemical mutagen treatment to rice varieties, Hwacheongbyeo and IR24. Linkage analysis of a floury-endosperm gene was carried out using linkage testers. The grain size of brown rice of the mutants was smaller than that of the original varieties. The l, 000-grain and 1$\ell$ weight were lighter in the mutants compared with those in the original varieties. The compound starch granules in the endosperm cell of the mutants showed a loosely-packed crystalline structure. Amylose contents in mutants ranged from 16.9 to 28.5%. Crude protein contents of the mutants were not significantly different from the original rice variety, Hwacheongbyeo, but white core mutant(line 47106) derived from IR24 showed higher protein(l1.32%) compared with IR24(8.30%). The mutants showed slightly harder gel characteristics, and much lower viscosity in Amylograph than original varieties. Steamed rice-cakes from mutant lines showed greater volume than those from original varieties. During the process of alcohol fermentation, Brix in the mutants(especially floury mutants) decreased faster and the alcohol production after 10-day fermentation was much greater in the mutants than in the original varieties. Three different gene loci for floury endosperm characteristics were identified from the allelism test among mutant lines, and the genes were tentatively symbolized as flo-a, flo-b and flo-c, respectively. A floury gene, flo-a, was linked with lg(liguleless) gene in the linkage group N, with R.V. 5.76$\pm$1.72%.

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Distribution Characteristics of Heavy Metals for Tidal Flat Sediments in the Saemankeum Area (새만금 갯벌의 중금속 분포 특성)

  • KIM Jong-Gu;YOO Sun-Jae;CHO Eun-Il;AHN Wook-Sung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.36 no.1
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    • pp.55-61
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    • 2003
  • This study was conducted to evaluate distribution and behavior characteristics of heavy metals for tidal flat sediments in the Saemankeum area. The value of heavy metal contents in the tidal flat sediments were higher than that surveyed in 1994, but showing that it's lower when compared with the value of Shiwha lake. Enrichment factors in the tidal flat sediments showed below 1 except for Pb and Zn. Metal excesses was appeared that Cu, Cr, Fe, Mn lacked and Pb, Zn were high. The correlation analysis between heavy metals and organic matters was found high positive relationship (r=0.424$\~$0.839), especially correlation coefficient between ignition loss and oxide Al, Fe, Mn showed high positive relationship above 0.7. The correlation analysis between Brain size and hear metals was found that as grain size was small, heavy metals contents were increased. Correlation coefficient between silt and heavy metals except for Cu, Pb showed high positive relationship as 0.552$\~$0.732.