• Title/Summary/Keyword: Glycol Ether

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Synthesis of O/W Emulsion of Alkyd Resin for Reducing of VOC (VOC 절감을 위한 알키드 수지의 O/W 에멀젼 제조)

  • Lee, Young Sang;Lee, Euy Soo;Ha, Jin Kuk
    • Journal of Adhesion and Interface
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    • v.11 no.1
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    • pp.9-14
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    • 2010
  • O/W emulsions were prepared with the phase inversion emulsification methods. The emulsifiers were used the UNIQ-1 (isopropylamine alkyl aryl sulphonate) and UNIQ-2 (alkoxylated glycol ether). Investigated effect that HLB value, agitator velocity and manufacture temperature get in mean particle size of emulsions. Mean particle size receives much effect of HLB value. Also, estimated stability about storage temperature and light. Emulsion's mean particle size was 193 nm lastly, reduced VOC amount used 90% than existing alkyd resin.

The Toughness of Polyurethane and Epoxy Resins IPNs (폴리우레탄-에폭시 IPNs의 강인성)

  • Kim, Jong Seok;Hong, Suk Pyo
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.445-450
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    • 1998
  • Interpenetrating polymer networks(IPNs) were prepared from castor oil-type polyurethanes(PUs) and epoxy resin. Two types of PU were prepared by using polypropylene ether glycol(PPG) as a chain extending agent and caster oil(CO) as a crosslinking agent. COPU/epoxy simultaneous interpenetrating polymer networks(SINs) based on CO had a better compatibility over the all composition than PPGPU/epoxy SINs based on PPG. The flexural strength of all PPGPU/epoxy SINs was decreased with decreasing entanglement of networks. COPU/epoxy SINs showed the higher fracture toughness and mechanial properties than the PPGPU/epoxy SINs. Fracture surfaces of all of the SINs showed the localized shear deformation and crack deflection rather than generation of stress whitening associated with the cavitation.

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Synthesis and Emulsification of Polyurethane Anionomer (음이온성 폴리우레탄의 합성 및 에멀젼화에 관한 연구)

  • Ann, Choun-Kee;Jin, Je-Yong;Lee, Gyung-Won;Choi, Sei-Young
    • Elastomers and Composites
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    • v.34 no.5
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    • pp.399-406
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    • 1999
  • Polyurethane (PU) prepolymers were synthesized from polytetramethylene ether glycol (PTMG), 4,4'-diphenylmethane diisocyanate (MDI), toluene 2,4-diisocyanate (TDI) and isophoron diisocyanate (IPDI). After chain extention using dimethyol propionic acid (DMPA), aqueous polyurethane anionomers were prepared from triethyl amine (TEA) as a neutralizer. The effect of the content of chain extender and the degree of neutralization on the state of emulsification, adhesive strength, viscosity, glass transition temperature and physical properties of emulsion cast film were investigated using UTM, Viscometer and DSC.

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A Study on Characteristics for Performance and Exhaust Emissions on Changes of Fuel Properties and Application of EGR Method in Diesel Engines (연료성상 변화와 배기가스재순환 방법 적용에 의한 디젤기관의 성능 및 배기배출물 특성 연구)

  • Oh Young-Taig;Choi Seung-Hun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.4 s.247
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    • pp.358-363
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    • 2006
  • In this study, the effects of oxygenated fuel such as ethylene glycol mono-normal butyl ether(EGBE) was investigated both DI and IDI diesel engine. Because EGBE includes oxygen content approximately 27.1 %, it is a kind of oxygenated fuel that the smoke emission of EGBE blending fuel is reduced remarkably compared with commercial diesel fuel. The focus of this study was to investigate the effects of the addition of oxygenated fuel to diesel fuel on the engine-out emissions and the performance. Smoke emissions of all EGBE blends were reduced substantially in comparison with conventional diesel fuel. This study showed that remarkable reduction of smoke with oxygenate blending fuels in diesel engines including DI and IDI combustion method. Besides, this study showed that simultaneous reduction of smoke and NOx emissions could be achieved by oxygenated fuel and EGR method that was applied to decrease NOx emissions increasing with smoke emissions reduction.

Study on the Synthesis of Polyurethane Cationomers and Their Mechanical Properties (양이온성 폴리우레탄의 합성 및 기계적 특성에 관한 연구)

  • Ann, Choun-Kee;Jin, Je-Yong;Choi, Sei-Yong
    • Elastomers and Composites
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    • v.33 no.3
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    • pp.177-184
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    • 1998
  • Polyurethane(PU) prepolymers were synthesized from polytetramethylene ether glycol(PTMG), with 4,4'-diphenylmethane diisocyanate(MDI), toluene 2,4-diisocyanate (TDI) and isophoron diisocyanate(IPDI). After chain extention using n-methyl-diethanol amine(n-MDEA), aqueous polyurethane cationomers were prepared by addition of glycolic acid(GA) as a quaternizer. The effect of the content of chain extender and the degree of neutralization on the stability of emulsion, adhesive strength, viscosity, glass transition temperature and physical properties of emulsion cast film were investigated using UTM, viscometer and DSC.

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Comparative Anatomy of the Korean Native Goat 2. Mesenteric mast cell (한국 재래 산양의 비교해부학적 연구 2. 장간막 비만세포에 대하여)

  • Lee, Heung Shik;Kim, Chang Ki
    • Korean Journal of Veterinary Research
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    • v.14 no.2
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    • pp.151-157
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    • 1974
  • This study was carried out to investigate on the morphology, distribution and stainability of the mast cells in the Korean Native goat. For the study, the experimental animals were anesthetized with pentobarbital sodium and opened the anterior abdomianl wall to remove immediately the specimens with a minimum of mechanical effects. The mesenteries were fixed in 10% neutral formalin, 4% basic lead acetate, absolute alcohol and ethlene glycol monoethyl ether. Following 24 hours of fixation, the toto preparation stained with 0.4% toluidine blue, 1% methylene blue, 1.5% bismark brown, saturated thionine and thionlne-methylene blue complex solution. The preparation were observed from 10 microscopic field with 450 magnification. The results were as follows: 1. The form of the mesenteric mast cell was found 2 types. One was spindle form in larger number around vessels, the other was ovoid or spherical form in connective tissue far from blood vessels. 2. The average size was $18.63{\pm}5.75{\mu}m$ in length, $10.61{\pm}3.39{\mu}m$ in width and number was $105.50{\pm}18.45$. 3. Ethylene glycol monoethyl ether was particularly useful in preserving the mast cell granules. 4. Thione-methylene blue complex solution might be recommended to stain of granules.

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Electrochemical Performance of Lithium Sulfur Batteries with Plasticized Polymer Electrolytes based on P(VdF-co-HFP)

  • Park, Jeong-Ho;Yeo, Sang-Yeob;Park, Jung-Ki;Lee, Yong-Min
    • Journal of the Korean Electrochemical Society
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    • v.13 no.2
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    • pp.110-115
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    • 2010
  • The plasticized polymer electrolytes based on polyvinylidene fluoride-co-hexafluoropropylene (P(VdF-co-HFP)), tetra (ethylene glycol) dimethyl ether (TEGDME), and lithium perchlorate ($LiClO_4$) are prepared for the lithium sulfur batteries by solution casting with a doctor-blade. The polymer electrolyte with EO : Li ratio of 16 : 1 shows the maximum ionic conductivity, $6.5\;{\times}\;10^{-4}\;S/cm$ at room temperature. To understand the effect of the salt concentration on the electrochemical performance, the polymer electrolytes are characterized using electrochemical impedance spectroscopy (EIS), infrared spectroscopy (IR), viscometer, and differential scanning calorimeter (DSC). The optimum concentration and mobility of the charge carriers could lead to enhance the utilization of sulfur active materials and the cyclability of the Li/S unit cell.

CHARACTERISTICS OF PERFORMANCE AND EXHAUST EMISSION OF DIESEL ENGINES BY CHANGES IN FUEL PROPERTIES AND APPLICATION OF EGR

  • Choi, S.H.;Oh, Y.T.
    • International Journal of Automotive Technology
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    • v.8 no.2
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    • pp.179-184
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    • 2007
  • In this study, the potential use of oxygenated fuels such as ethylene glycol mono-normal butyl ether (EGBE) was investigated in an attempt to reduce the emission of exhaust smoke from diesel engines. Effects of the combustion method on exhaust emission of DI and IDI diesel engines were also examined. Since EGBE is composed of approximately 27.1% oxygen, this is one of several potential oxygenated fuels that could reduce the smoke content of exhaust gas. EGBE blended fuels have been proven to reduce smoke emission remarkably compared to the conventional commercial fuels. The test was conducted with single and four cylinder, four stroke, DI and IDI diesel engines. The study showed that a simultaneous reduction of smoke and NOx emission could be achieved by the combination of oxygenated blend fuels and the cooled EGR method in both DI and IDI diesel engines. It was also found that a reduction rate of exhaust emission in a DI engine was larger than an IDI diesel engine.

Physico-Chemical Characteristics of $\alpha$-D-Glucosidase Inhibitor from Streptomyces sp (Streptomyces속 균주가 생성하는 $\alpha$-D-Glucosidase 저해물질의 물리학적 성질)

  • 도재호;주현규
    • Microbiology and Biotechnology Letters
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    • v.18 no.1
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    • pp.35-38
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    • 1990
  • $\alpha$-D-Glucosidase inhibitor purified in a pure form was amorphous powder which gave a single spot at Rf value 0.12-0.71 with various developing solvent systems on silica gel thin layer chromatography, and melting point was 154.3-155.3$^{\circ}C$. It was disolved in water, formic acid and ethylene glycol monoethyl ether, and was very high hygroscopic substance. Biochemical reaction of the substance was positive to phenol sulfuric acid, ninhydrin, silver nitrate-sodium hydroxide, but negative to DNS reagent. Acid hydrolysis gave fructose and acid as sole sugar and amino acid constituents respectively. Moelcular weight of the inhibitor was estimated to be 1,050 by Shphadex G-25 column chromatography.

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