• 분석과학
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• 제7권2호
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• pp.181-186
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• 1994

Poly(3-methylthiophene) 전도성 막전극을 이용해서 벗김 전압-전류법으로 Ag의 분석 가능성을 연구하였다. 막전극 표면에 존재하는 18-crown-6은 수용액에서 Ag(I)을 착화에 의해서 흡수하고 이 Ag(I)은 제한된 전위 범위의 순환 전압-전류법에 의해서 막전극 속으로 이동하여 유리질 탄소전극에서 산화-환원된다. 따라서 막전극은 Ag(I)의 침투를 용이하게 하기 위해서 적당한 두께의 다공성으로 제조되어야 한다. 이러한 실험 결과를 바탕으로 수용액에서 $5.0{\times}10^{-6}M$의 Ag(I)을 검출할 수 있었다.

• Korean Chemical Engineering Research
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• 제54권6호
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• pp.817-821
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• 2016

Levodopa or L-3,4-dihydroxyphenylalanine (L-DOPA) is the direct precursor of the neurotransmitter dopamine. L-DOPA is a well-known neuroprotective agent for the treatment of Parkinson's disease symptoms. L-DOPA was synthesized using the enzyme, tyrosinase, as a biocatalyst for the conversion of L-tyrosine to L-DOPA and an electrochemical method for reducing L-DOPAquinone, the product resulting from enzymatic synthesis, to L-DOPA. In this study, three electrode systems were used: A glassy carbon electrode (GCE) as working electrode, a platinum, and a Ag/AgCl electrode as auxiliary and reference electrodes, respectively. GCE has been modified using electropolymerization of pyrrole to facilitate the electron transfer process and immobilize tyrosinase. Optimum conditions for the electropolymerization modified electrode were a temperature of $30^{\circ}C$ and a pH of 7 producing L-DOPA concentration 0.315 mM. After 40 days, the relative activity of an enzyme for electropolymerization remained 38.6%, respectively.

• Journal of Electrochemical Science and Technology
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• 제11권3호
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• pp.238-247
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• 2020

Some nano structured bimetallic NiPd electrocatalysts were electrodeposited on glassy carbon electrodes using a double potential step chronoamperometry. The morphology of the electrodeposited samples was investigated by field emission-scanning electron microscopy, while their compositions were evaluated using energy dispersive X-ray spectroscopy. It was observed that the electrodeposited samples contained a low Ni content, in the range of 0.80 - 7.10%. The electrodeposited samples were employed as the anode electro-catalysts for the oxidation of sodium borohydride in NaOH solution (1.0 M) using cyclic voltammetry, chronoamperometry, rotating disk electrode, and impedance spectroscopy. The number of exchanged electrons, charge transfer resistances, apparent rate constants, and double layer capacitances were calculated for the oxidation of borohydride on the prepared catalysts. According to the results obtained, the NiPd-2 sample with the lowest Ni content (0.80%), presented the highest catalytic activity for borohydride oxidation compared with the other NiPd samples as well as the pure Pd sample. The anodic peak current density was obtained to be about 1.3 times higher on the NiPd-2 sample compared with that for the Pd sample.

• 대한기계학회논문집A
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• 제30권8호
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• pp.976-984
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• 2006

Time-temperature superposition has been studied to determine the long-term fatigue life over millions of cycles for glassy polymers. π le superposition is supposed to make an accelerated lifetime testing (ALT) technique possible. Dog-bone shaped specimens made of carbon filled Polycarbonate (PC) were tested under fatigue, based on the stress-lifetime approach (S-N curve). Fatigue-induced localized yield-like deformation is considered as the defect leading to fatigue and its evolution behavior is characterized by a modified energy activation model in which temperature is considered as fatigue acceleration factor. This model allows the reduced time concept to account for effects of different temperature in short-term fatigue data to determine long-term fatigue life through the use of time-temperature superposition that is applicable under a low frequency and isothermal conditions. The experimental results validated that the proposed technique could be a possible method for accelerated lifetime testing (ALT) of time-dependent polymeric materials.

• 센서학회지
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• 제26권6호
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• pp.379-385
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• 2017

In this study, an amperometric non-enzymatic glucose sensor was developed on the surface of a glassy carbon electrode by simply drop-casting the synthesized homogeneous suspension of hexagonal boron nitride (h-BN) nanosheets with a copper metal-organic framework (Cu-MOF) composite. Comprehensive analytical methods, including field-emission scanning electron microscopy (FE-SEM), Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), cyclic voltammetry, electrochemical impedance spectroscopy, and amperometry, were used to investigate the surface and electrochemical characteristics of the h-BN-Cu-MOF composite. The FE-SEM, FT-IR, and XRD results showed that the h-BN-Cu-MOF composite was formed successfully and exhibited a good porous structure. The electrochemical results showed a sensor sensitivity of $18.1{\mu}A{\mu}M^{-1}cm^{-2}$ with a dynamic linearity range of $10-900{\mu}M$ glucose and a detection limit of $5.5{\mu}M$ glucose with a rapid turnaround time (less than 2 min). Additionally, the developed sensor exhibited satisfactory anti-interference ability against dopamine, ascorbic acid, uric acid, urea, and nitrate, and thus, can be applied to the design and development of non-enzymatic glucose sensors.

• Journal of Electrochemical Science and Technology
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• 제11권1호
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• pp.68-83
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• 2020

A fast and simple method for synthesis of Cu_xO-ZnO/PPy/RGO nanocomposite by electrochemical manner have been reported in this paper. For testing the utility of this nanocomposite we modified a GCE with the nanocomposite to yield a sensor for simultaneous determination of four analytes namely ascorbic acid (AA), dopamine (DA), uric acid (UA), and folic acid (FA). Cyclic voltammetry (CV) and Differential pulse voltammetry (DPV) selected for the study. The modified electrode cause to enhance electron transfer rate so overcome to overlapping their peaks and consequently having the ability to the simultaneous determination of AA, DA, UA, and FA. To synthesis confirmation of the nanocomposite, Field emission scanning electron microscopy (FE-SEM), Raman spectroscopy, and electrochemical impedance spectroscopy (EIS) were applied. The linearity ranges were 0.07-485 μM, 0.05-430 μM, 0.02-250 μM and 0.022-180 μM for AA, DA, UA, and FA respectively and the detection limits were 22 nM, 10 nM, 5 nM and 6 nM for AA, DA, UA, and FA respectively Also, the obtained electrode can be used for the determination of the AA, DA, UA, and FA in human blood, and human urine real samples.

• 분석과학
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• 제11권3호
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• pp.151-155
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• 1998

100 mM NaCl+27 mM $MgCl_2$ 용액에서, 도데실황산나트륨 (SDS)의 유무에 따른 1.0 mM 메틸비올로겐 ($MV^{2+}$)의 전기화학적 거동을 연구하였다. ${\Delta}E_p$(산화와 환원 봉우리전위 값의 차이) 대 - log[SDS]로 도시한 그림에서 두 선의 교차점을 임계미셀농도 (CMC)로 결정하였다. $Mg^{2+}$가 첨가되면, 유리탄소전극에 대한 효과적인 $MV{\cdot}^+$의 접근이 가능해지고 미셀형성도 지연되었다.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3133-3138
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• 2010

The electrochemical properties of the liposoluble vitamin $K_1$ adsorbed on bare and lipid coated glassy carbon electrodes (GCEs) were studied in unbuffered and well buffered aqueous media. The reduction products of vitamin $K_1$ were characterized by employing cyclic voltammetry and the in situ UV-visible spectroelectrochemical technique. The radical species of vitamin $K_1$ cannot be observed at the bare GCEs in well buffered media. The formation of the anion radical of vitamin $K_1$ was observed in unbuffered solutions above pH 5.9 or at the lipid coated GCE in a well-buffered solution. UV-visible absorption bands of neutral vitamin $K_1$ were observed at 260 nm and 330 nm, and a band corresponding to the anion radical species was observed at 450 nm. The derivative cyclic voltabsorptometric (DCVA) curves obtained for electrochemical reduction of vitamin $K_1$ confirmed the presence of both neutral and anion radical species. The anion radical of vitamin $K_1$ formed at the hydrophobic conditions with phosphatidylcholine (PC) lipid coated electrode was stable enough to be observed in the spectroelectrochemical experiments.

• Bulletin of the Korean Chemical Society
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• 제31권1호
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• pp.104-111
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• 2010

The heterogeneous electron transfer at $SiMo_{12}O_{40}^{4-}$ monolayers on GC, HOPG, and Au electrode surfaces are investigated using cyclic voltammetric and electrochemical impedance spectroscopic (EIS) methods. The electron transfer of negatively charged $Fe(CN)_6^{3-}$ species is retarded at $SiMo_{12}O_{40}^{4-}$-modified electrode surfaces, while that of positively charged $Ru(NH_3)_6^{3+}$species is accelerated at the modified surfaces. This is due to the electrostatic interactions between $SiMo_{12}O_{40}^{4-}$ layers on surfaces and charged redox species. The electron transfer kinetics of a neutral redox species, 1,1‘-ferrocenedimethanol (FDM), is not affected by the modification of electrode surfaces with $SiMo_{12}O_{40}^{4-}$, indicating the $SiMo_{12}O_{40}^{4-}$ monolayers do not impart barriers to electron transfer of neutral redox species. This is different from the case of thiolate SAMs which always add barriers to electron transfer. The effect of $SiMo_{12}O_{40}^{4-}$ layers on the electron transfer of charged redox species is dependent on the kind of electrodes, where HOPG surfaces exhibit marked effects. Possible mechanisms responsible for different electron transfer behaviors at $SiMo_{12}O_{40}^{4-}$ layers are proposed.

• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.182-188
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• 2014

Three new transition metal complexes based on Ozagrel $[Cu(Ozagrel)]_n$ (1), $[Zn(Ozagrel)(Cl)]_n$ (2), ${[Mn_2-(Ozagrel)(1,4-ndc)_2]{\cdot}(H_2O)}_n$ (3), (Ozagrel = 3-(4-((1H-imidazol-1-yl)methyl)phenyl)acrylic acid; 1,4-ndc = 1,4-Naphthalenedicarboxylic acid) have been hydrothermally synthesized and characterized by elemental analyse, IR, TG, PXRD, electrochemical analysis and single crystal X-ray diffraction. X-ray structure analysis reveals that 1 and 3 are 3D coordination polymers, while complex 2 is a two-dimensional network polymer, the 2D layers are further packed into 3D supramolecular architectures that are connected through hydrogen bonds. The electrochemistry of 1-3 was studied by cyclic voltammetry in methanol and water using a glassy carbon working electrode. Also, thermal decomposition process and powder X-ray diffraction of complexes were investigated.