DOI QR코드

DOI QR Code

Heterogeneous Electron Transfer at Polyoxometalate-modified Electrode Surfaces

  • Choi, Su-Hee (Department of Chemistry, Chungbuk National University) ;
  • Seo, Bo-Ra (Department of Chemistry, Chungbuk National University) ;
  • Kim, Jong-Won (Department of Chemistry, Chungbuk National University)
  • Published : 2010.01.20

Abstract

The heterogeneous electron transfer at $SiMo_{12}O_{40}^{4-}$ monolayers on GC, HOPG, and Au electrode surfaces are investigated using cyclic voltammetric and electrochemical impedance spectroscopic (EIS) methods. The electron transfer of negatively charged $Fe(CN)_6^{3-}$ species is retarded at $SiMo_{12}O_{40}^{4-}$-modified electrode surfaces, while that of positively charged $Ru(NH_3)_6^{3+}$species is accelerated at the modified surfaces. This is due to the electrostatic interactions between $SiMo_{12}O_{40}^{4-}$ layers on surfaces and charged redox species. The electron transfer kinetics of a neutral redox species, 1,1‘-ferrocenedimethanol (FDM), is not affected by the modification of electrode surfaces with $SiMo_{12}O_{40}^{4-}$, indicating the $SiMo_{12}O_{40}^{4-}$ monolayers do not impart barriers to electron transfer of neutral redox species. This is different from the case of thiolate SAMs which always add barriers to electron transfer. The effect of $SiMo_{12}O_{40}^{4-}$ layers on the electron transfer of charged redox species is dependent on the kind of electrodes, where HOPG surfaces exhibit marked effects. Possible mechanisms responsible for different electron transfer behaviors at $SiMo_{12}O_{40}^{4-}$ layers are proposed.

Keywords

References

  1. Bowling, R. J.; Packard, R. T.; McCreery, R. L. J. Am. Chem. Soc. 1989, 111, 1217. https://doi.org/10.1021/ja00186a008
  2. Rice, R. J.; Pontikos, N. M.; McCreery, R. L. J. Am. Chem. Soc. 1990, 112, 4617. https://doi.org/10.1021/ja00168a001
  3. Kneten, K. R.; McCreery, R. L. Anal. Chem. 1992, 64, 2518. https://doi.org/10.1021/ac00045a011
  4. McDermott, C. A.; Kneten, K. R.; McCreery, R. L. J. Electrochem. Soc. 1993, 140, 2593. https://doi.org/10.1149/1.2220868
  5. Cline, K. K.; McDermott, M. T.; McCreery, R. L. J. Phys. Chem. 1994, 98, 5314. https://doi.org/10.1021/j100071a023
  6. Finklea, H. O. In Electroanalytical Chemistry: a Series of Advances; 1996; Vol. 19, pp 109.
  7. Chidsey, C. E. D. Science 1991, 251, 919. https://doi.org/10.1126/science.251.4996.919
  8. Ganesh, V.; Pal, S. K.; Kumar, S.; Lakshminarayanan, V. J. Colloid Interface Sci. 2006, 296, 195. https://doi.org/10.1016/j.jcis.2005.08.051
  9. Xing, Y. F.; O'Shea, S. J.; Li, S. F. Y. J. Electroanal. Chem. 2003, 542, 7. https://doi.org/10.1016/S0022-0728(02)01440-7
  10. Porter, M. D.; Bright, T. B.; Allara, D. L.; Chidsey, C. E. D. J. Am. Chem. Soc. 1987, 109, 3559. https://doi.org/10.1021/ja00246a011
  11. Chidsey, C. E. D.; Loiacono, D. N. Langmuir 1990, 6, 682. https://doi.org/10.1021/la00093a026
  12. Takehara, K.; Takemura, H.; Ide, Y. Electrochim. Acta 1994, 39, 817. https://doi.org/10.1016/0013-4686(93)E0018-H
  13. Pope, M. T. Heteropoly and Isopoly Oxometalates; Springer-Verlag: Berlin, 1983.
  14. Rong, C. Y.; Anson, F. C. Anal. Chem. 1994, 66, 3124. https://doi.org/10.1021/ac00091a021
  15. Kuhn, A.; Anson, F. C. Langmuir 1996, 12, 5481. https://doi.org/10.1021/la960461r
  16. Rong, C. Y.; Anson, F. C. Inorg. Chim. Acta 1996, 242, 11. https://doi.org/10.1016/0020-1693(95)04843-X
  17. Ge, M.; Niece, B. K.; Wall, C. G.; Klemperer, W. G.; Gewirth, A. A. Mater. Res. Soc. Symp. Proc. 1997, 451, 99.
  18. Lee, L.; Wang, J. X.; Adzic, R. R.; Robinson, I. K.; Gewirth, A. A. J. Am. Chem. Soc. 2001, 123, 8838. https://doi.org/10.1021/ja0161352
  19. Kim, J.; Gewirth, A. A. Langmuir 2003, 19, 8934. https://doi.org/10.1021/la034708d
  20. Ge, M. H.; Zhong, B. X.; Klemperer, W. G.; Gewirth, A. A. J. Am. Chem. Soc. 1996, 118, 5812. https://doi.org/10.1021/ja960498y
  21. Sadakane, M.; Steckhan, E. Chem. Rev. 1998, 98, 219. https://doi.org/10.1021/cr960403a
  22. Mizuno, N.; Misono, M. Chem. Rev. 1998, 98, 199. https://doi.org/10.1021/cr960401q
  23. Choi, S.; Kim, J. Bull. Korean Chem. Soc. 2009, 30, 810. https://doi.org/10.5012/bkcs.2009.30.4.810
  24. Tang, Z. Y.; Liu, S. Q.; Wang, E. K.; Dong, S. J.; Wang, E. B. Langmuir 2000, 16, 5806. https://doi.org/10.1021/la991348e
  25. Tang, Z. Y.; Liu, S. Q.; Wang, E. K.; Dong, S. J. Langmuir 2000, 16, 4946. https://doi.org/10.1021/la9907127
  26. Lee, L.; Gewirth, A. A. J. Electroanal. Chem. 2002, 522, 11. https://doi.org/10.1016/S0022-0728(01)00742-2
  27. Xu, J. S.; Chen, Q. Y.; Swain, G. M. Anal. Chem. 1998, 70, 3146. https://doi.org/10.1021/ac9800661
  28. Nicholson, R. S. Anal. Chem. 1965, 37, 1351. https://doi.org/10.1021/ac60230a016
  29. Bard, A. J.; Faulkner, L. R. Electrochemical Methods, 2nd ed.; John Wiley & Sons: New York, 2001.
  30. Mahe, E.; Devilliers, D.; Comninellis, C. Electrochim. Acta 2005, 50, 2263. https://doi.org/10.1016/j.electacta.2004.10.060
  31. Park, S. M.; Yoo, J. S. Anal. Chem. 2003, 75, 455A.
  32. Hwang, S.; Chi, Y. S.; Lee, B. S.; Lee, S. G.; Choi, I. S.; Kwak, J. Chem. Commun. 2006, 183.
  33. Kim, J.; Lee, L.; Niece, B. K.; Wang, J. X.; Gewirth, A. A. J. Phys. Chem. B 2004, 108, 7927. https://doi.org/10.1021/jp0494436
  34. Love, J. C.; Estroff, L. A.; Kriebel, J. K.; Nuzzo, R. G.; Whitesides, G. M. Chem. Rev. 2005, 105, 1103. https://doi.org/10.1021/cr0300789
  35. Hong, H. G.; Park, W. Langmuir 2001, 17, 2485. https://doi.org/10.1021/la001466y
  36. Janek, R. P.; Fawcett, W. R.; Ulman, A. Langmuir 1998, 14, 3011. https://doi.org/10.1021/la970980+
  37. Wakabayashi, N.; Kitamura, F.; Ohsaka, T.; Tokuda, K. J. Electroanal. Chem. 2001, 499, 161. https://doi.org/10.1016/S0022-0728(00)00508-8
  38. Choi, S.; Seo, B.; Kim, J. unpublished result.
  39. Kim, K.; Kwak, J. J. Electroanal. Chem. 2001, 512, 83. https://doi.org/10.1016/S0022-0728(01)00588-5
  40. Hwang, S.; Lee, B. S.; Chi, Y. S.; Kwak, J.; Choi, I. S.; Lee, S. G. Electrochim. Acta 2008, 53, 2630. https://doi.org/10.1016/j.electacta.2007.10.043
  41. Bastl, Z.; Franc, J.; Janda, P.; Pelouchova, H.; Samec, Z. J. Electroanal. Chem. 2007, 605, 31. https://doi.org/10.1016/j.jelechem.2007.03.003

Cited by

  1. Speciation in strongly acidic metastable solutions of oxotungstate(vi) compounds vol.62, pp.6, 2013, https://doi.org/10.1007/s11172-013-0185-z