• Bulletin of the Korean Chemical Society
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• v.22 no.2
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• pp.154-158
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• 2001

The steps for the generation of very thin GaN films on ultrathin AlN/6H-SiC surface by alternating a pulsative supply (APS) of trimethyl gallium and NH3 gases have been examined by ASED-MO calculations. We postulate that the gallium cul ster was formed with the evaporation of CH4 gases via the decomposition of trimethyl gallium (TMG), dimethyl gallium (DMG), and monomethyl galluim (MMG). During the injection of NH3 gas into the reactor, the atomic hydrogens were produced from the thermal decomposition of NH3 molecule. These hydrogen gases activated the Ga-C bond cleavage. An energetically stable GaN nucleation site was formed via nitrogen incorporation into the layer of gallium cluster. The nitrogen atoms produced from the thermal degradation of NH3 were expected to incorporate into the edge of the gallium cluster since the galliums bind weakly to each other (0.19 eV). The structure was stabilized by 2.08 eV, as an adsorbed N atom incorporated into a tetrahedral site of the Ga cluster. This suggests that the adhesion of the initial layer can be reinforced by the incorporation of nitrogen atom through the formation of large grain boundary GaN crystals at the early stage of GaN film growth.

• Journal of Ceramic Processing Research
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• v.19 no.5
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• pp.388-393
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• 2018

Sublimation of $Bi_2O_3$-based materials is an important degradation issue for the long-term applications of many electronic devices. A series of $SnO_2$-doped $Bi_2O_3$ materials (SBO), was synthesized, densified, and then tested in air or strong reducing atmosphere. The $SnO_2$-doping effects and sublimation kinetics of the SBO materials were studied by X-ray diffraction (XRD), scanning electron microscope (SEM) and precise mass loss measurement. The results show that formation of $Bi_2Sn_2O_7$ phase greatly retards the mass loss of SBO. The SBO samples show a surface sublimation in an energy of $52.6kJ{\cdot}mol^{-1}$. However, the sublimation is also controlled by surface microstructure as the amount of vaporizing species (the Bi or gaseous Bi-oxides) is more than 0.1 mass%. The evaporation is retarded on the rough surface and the mechanism of surface evaporation is changed to diffusional control.

• Korean Journal of Metals and Materials
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• v.46 no.11
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• pp.708-712
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• 2008

The influence of high temperature gas nitriding (HTGN) in STS347 and STS310S steels was experimentally investigated. The HTGN was carried out at $1,050^{\circ}C{\sim}1,150^{\circ}C$ for 10 hrs in a gaseous atmosphere containing $1kg/mm^2$ of nitrogen. After HTGN, fine precipitates of $Cr_2N$ and NbN appeared in austenite on the surface of STS 347, while nitrogen pearlite, which was layeredof $Cr_2N$ and austenite alternatively, appeared in austenite on the surface of STS 310S. The surface hardness of HTGN-treated, STS 347 and STS 310S specimens was 250~360 Hv and 270~400 Hv, respectively, depending on the temperature of HTGN. The nitrogen content was analyzed 1.4 wt% and 1.6 wt% at the surface layer of STS 347 and STS 310S steels, respectively. In addition, an improvement in the corrosion resistance of HTGN treated specimens was observed.

• Journal of the Korean Society of Propulsion Engineers
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• v.24 no.6
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• pp.85-92
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• 2020

Ground hot-firing tests were conducted to analyze the combustion performance according to the characteristic lengths 1.37 m, 1.71 m, and 2.06 m of the combustion chamber in 200 N-class GCH4-LOx small rocket engine. Thrust, specific impulse, and characteristic velocity at the steady-state could be obtained as the key performance parameters of the rocket engine. The performance characteristics acquired through the test were compared and analyzed with the theoretical performance calculated from CEA analysis. Observation of the influence of characteristic length on the combustion performance indicates that an optimal characteristic length shall remain between 1.71 m and 2.06 m.

• Elastomers and Composites
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• v.55 no.4
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• pp.270-276
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• 2020

The long-term durability of an FKM O-ring used as parts of a hydrogen station was investigated by exposing it to high-pressure gaseous hydrogen for 1, 3, and 7 days at room temperature. Changes in its sealing force were subsequently measured at 150℃ using intermittent compression stress relaxation (CSR). No changes in the tensile properties of FKM O-ring were observed, but its initial and overall sealing forces at 150℃ significantly decreased with increasing exposure time to hydrogen gas. Microvoid formation in the FKM O-ring upon exposure to high-pressure hydrogen was minimized over time after the ring was exposed to atmospheric pressure at room temperature, which prevented changes in its tensile properties. However, applying heat accelerated FKM O-ring oxidation, which decreased its sealing force. These results indicated that identifying changes in the sealing force of rubber materials using intermittent CSR is not sufficient for monitoring changes in mechanical properties under high-pressure hydrogen atmospheres; however, it is suitable for evaluating the long-term durability of sealing materials for hydrogen station applications under similar conditions.

• Korean Journal of Remote Sensing
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• v.38 no.1
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• pp.1-20
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• 2022

As unmanned aerial vehicle (UAV) technology grew in popularity over the years, it was introduced for air quality monitoring. This can easily be used to estimate the sidewalk emission concentration by calculating road traffic emission factors of different vehicle types. These calculations require a simulation of the spread of pollutants from one or more sources given for estimation. For this purpose, a Gaussian plume dispersion model was developed based on the US EPA Motor Vehicle Emissions Simulator (MOVES), which provides an accurate estimate of fuel consumption and pollutant emissions from vehicles under a wide range of user-defined conditions. This paper describes a methodology for estimating emission concentration on the sidewalk emitted by different types of vehicles. This line source considers vehicle parameters, wind speed and direction, and pollutant concentration using a UAV equipped with a monocular camera. All were sampled over an hourly interval. In this article, the YOLOv5 deep learning model is developed, vehicle tracking is used through Deep SORT (Simple Online and Realtime Tracking), vehicle localization using a homography transformation matrix to locate each vehicle and calculate the parameters of speed and acceleration, and ultimately a Gaussian plume dispersion model was developed to estimate the CO, NOx concentrations at a sidewalk point. The results demonstrate that these estimated pollutants values are good to give a fast and reasonable indication for any near road receptor point using a cheap UAV without installing air monitoring stations along the road.

• Journal of Electrochemical Science and Technology
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• v.13 no.4
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• pp.417-423
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• 2022

With the emerging importance of catalysts for water electrolysis, developing efficient and inexpensive electrocatalysts for water electrolysis plays a vital role in renewable hydrogen energy technology. In this study, a 1nm thickness of TiC-supported Ru catalyst for hydrogen evolution reaction (HER) has been successfully fabricated using an electron (E)-beam evaporator and thermal decomposition of gaseous CH₄ in a furnace. The prepared Ru/TiC catalyst exhibited an outstanding performance for alkaline hydrogen evolution reaction with an overpotential of 55 mV at 10 mA cm^-2. Furthermore, we demonstrated that the outstanding HER performance of Ru/TiC was attributed to the high surface area of the support and the metal-support interaction.

• Journal of Ocean Engineering and Technology
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• v.36 no.4
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• pp.211-216
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• 2022

Since liquefied natural gas (LNG) is imported in a liquid state of about -162℃ to increase transportation efficiency in Korea, it must be vaporized in a gaseous state to supply it to consumers. Among them, ambient air vaporizer (AAV) has caught attention due to eco-friendly and low costs characteristics. However, there is a disadvantage that the performance of the heat exchanger is deteriorated due to frost due to mist and icing when used for a long time. In this paper, frost generation model in AAV vaporizer was investigated with numerically to examine utilizing the vaporizer performance with the frost generation behavior. The frost generation behavior of AAV vaporizers was examined with humidity, fin characteristic, and temperature effects. As for the LNG discharge temperature, the 12 fin vaporizer showed the highest discharge temperature when the atmospheric temperature was 25℃, and the 8 fin vaporizer had the lowest LNG discharge temperature when the atmospheric temperature was 0℃. In the case of frost formation, in the case of the 12 fin vaporizer, it was formed the most at the atmospheric temperature of 25℃, and the least was formed in the vaporizer at the 0℃ condition of the atmospheric temperature of 8 fins.

• Journal of the Korean Vacuum Society
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• v.4 no.S2
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• pp.131-138
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• 1995

The broad beam ion sources of hot filament plasma type have widely used for modifications of materials and thin films, and the new type intensive current broad beam metal ion source including reactive gaseous ion beams is needed for preparing the hard coating films such as DLC, $\beta-C_3N_4$ Carbides, Nitrides, Borides etc. Now a electorn beam evaporation(EBE) broad beam metal ion source has been developed for this purpose in our lab. CN film has been formed by the EBE ion source. Study of the CN film shows that it has high hardness(HK=5800kgf/$\textrm {mm}^2$)and good adhesion. This method can widely changes the ratio of C/N atom's concentrations from 0.14 to 0.6 and has high coating rate. The low energy pocket ion source which was specially designed for surface texturing of medical silicon rubber was also developed. It has high efficiency and large uniform working zone. Both nature texturing and mesh masked texturing of silicon rubbers were performed. The biocompatibility was tested by culture of monocytes, and the results showed improved biocompatibility for the treated silicon rubbers. In addition, the TiB2 film synthesized by IBED is being studied recently in our lab. In this paper, the results which include the hardness, thickness of the films and the AES, XRD analysis as well as the tests of the oxidation of high temperature and erosion will be presented.

• Journal of Korean Society for Atmospheric Environment
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• v.4 no.2
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• pp.1-10
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• 1988

Brookhaven 의학연구용 원자로에서 방출되는 기체분출물에 관하여 연구 되었다. 모든 기체시료는 $\gamma$-선 분광계측에 의하여 분석되었다. 시료 중에 존재하는 것으로 확인된 핵종으로서, $^{82}Cl(T_{1/2}$ = 35.30 시간) 이 가장 뚜렷하였다. 그 외의 확인된 핵종은 $^{38}Cl(T_{1/2}$ = 37.24분), $^{41}Ar(T_{1/2}$ = 1.82시간), $^{106}Rh(T_{1/2}$ = 29.80묘), $^{133}Te(T_{1/2}$ = 12.45분)이었다. 3MW 원자로 출력에서 pre-filter bank를 통과한 기체분출물 중에서 $$^{41}Ar$의 농도는 2.436Bq/cc로 계산됨으로써 $^{41}Ar$의 방사능 방출율은 8.51 ${\times}10^9$Bq/MW - h로 산정되었다. filter bank의 방사능 원거효율(%)은 $^{38}Cl$의 경우 97.84%, $^{41}Ar$은 14.15%, ^{82}Br$은 98.70% 그리고 $^{106}Rh$은 98.81% 각각 산정되었다. 한편, charcoal trap과 millipore filter 에서 확인된 기타 핵종들로서 $^{24}Na$, $^{72}Ga$, $^{92}Sr$, $^{97}Zr$, $^{132}I$, $^{133}Te$, $^{141}Ce$, $^{153}Sm$과 $^{154}Pm$은 filter bank에 의해서 완전히 제거되었다.