• Title/Summary/Keyword: Gas-Phase

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A Study on the Rupture Disk Design and Application at the Two Phase Flow by Runaway Reaction at Batch Reactor (회분식 반응기에서 반응폭주에 의한 2-Phase 흐름 파열판 설계 및 적용에 관한 연구)

  • Lee, Hyung-Sub;Yun, Hee-Chang
    • Journal of the Korean Institute of Gas
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    • v.21 no.3
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    • pp.1-8
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    • 2017
  • The purpose of this study is to suggest the rupture disk design(size) and application at the two phase(gas-liquid) flow by runaway reaction at batch reactor. The definition of runaway reaction is abnormally exothermic reaction by the uncontrolled cooling water or deviated operating condition. As a result, the temperature of reactor is rapidly increasing. The causes of runaway reaction are either self-heating reaction or sleeper reaction. General methods of rupture disk size or safety valve are not suitable in the runaway reaction, because of temperature and pressure increasing rapidly in the reactor and the phases of relieving fluid is 2-phase flow. This study case of the reactor incident, the depressurization system such as safety valve and vent installed, however, the system did not relieved the pressure of reactor suitably. The orifice size of the safety valve were designed too small because the size had not been considered the phenomena and character of reaction. The batch reactor design should be considered by referring to the possibility of runaway reaction proposed in this study and the size of rupture disk design method considering 2-phase flow.

Effect of Moisture Content of Biocatalyst on the Gas Phase Continuous Bioreaction (생촉매의 수분함유량이 기상의 연속반응에 미치는 영향)

  • ;Deb
    • KSBB Journal
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    • v.8 no.5
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    • pp.417-423
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    • 1993
  • The effect of moisture content of biocatalyst on the performance of a gas phase continuous bioreactor was investigated along with study on the mass transfer limitation. The biocatalysts whose moisture contents are 46.2% and 37.2%, respectively were prepared by immobilization of alcohol oxidase on Amberlite IRA-400, following by slow dehydration method, and packed into a column. Relative production rate (RPR), acetaldehyde composition ($X_p$) and conversion (X) of biocatalysts (37.2%) are better than those of biocatalysls (46.2%), and it was considered that these are attributed to the mass transfer enhancement in the gas phase compared with the aqueous phase.

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Calculation of Temperature Rise in Gas Insulated Busbar by Coupled Magneto-Thermal-Fluid Analysis

  • Kim, Hong-Kyu;Oh, Yeon-Ho;Lee, Se-Hee
    • Journal of Electrical Engineering and Technology
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    • v.4 no.4
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    • pp.510-514
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    • 2009
  • This paper presents the coupled analysis method to calculate the temperature rise in a gas insulated busbar (GIB). Harmonic eddy current analysis is carried out and the power losses are calculated in the conductor and enclosure tank. Two methods are presented to analyze the temperature distribution in the conductor and tank. One is to solve the thermal conduction problem with the equivalent natural convection coefficient and is applied to a single phase GIB. The other is to employ the computational fluid dynamics (CFD) tool which directly solves the thermal-fluid equations and is applied to a three-phase GIB. The accuracy of both methods is verified by the comparison of the measured and calculated temperature in a single phase and three-phase GIB.

Review on Gas-Voiding Models for HCDA(Hypothetical Core Disruptive Accident) Initiating Phase in LMR Analysis (I)

  • Chang, W.P.;Kwon, Y.M.;Hahn, D.H.;Suk, S.D.
    • Nuclear Engineering and Technology
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    • v.31 no.6
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    • pp.51-65
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    • 1999
  • The present review report introduces the existing analysis codes and physical modeling of two-phase flow associated with initiating event of HCDA in Liquid Metal Reactors for the effective study in the future, because the related research has not been systematically carried out in Korea compared with other areas. The description in this report is specifically addressed to the results yielded from careful review of the technical concepts on the two-phase flow modeling in the SAS2A code which was developed in ANL. The report is prepared in 2 parts based on the definite physical phenomena. The liquid slug and gas behavior models are main representations in the part (I) and (II), respectively. In this regard, it is expected that this report provide a fundamental knowledge on the two-phase flow model in LMR and, thus, contribute to establishment of the necessary HCDA analysis technology concerned with the LMR development in Korea.

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Characterization of Synthesized WS$_2$ Solid Lubricant (합성 WS$_2$ 고체윤활제의 특성 분석)

  • 신동우;윤대현;최인혁;김인섭
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1997.10a
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    • pp.211-216
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    • 1997
  • The tungsten disulfide (WS$_2$) solid lubricant was synthesized by two different reaction processes, and the chemical and physical characteristics of synthesized WS$_2$ powder were analyzed in terms of the average particle size, morphology, crystalline phase. The solid WO$_3$ powder with the average size of 0.2 $\mu$m was reacted with CS$_2$ gas flowed with N$_2$ or 96% N$_2$ + 4% H$_2$ forming gas for 36 h and 24 h at 900$\circ$C respectively. In the case of vapour phase transport method, the 3.5 wt% iodine was added as a vapour transport reagent into the composition of tungsten and sulfur powders maintaining a constant molar ratio of W : S = 1 : 2.2. The mixture was then heat treated at 850$\circ$C for 2 weeks in vacuum The reaction product obtained showed the average size of 12 $\mu$m and the hexagonal plate shape of typical solid lubricant with 2H-WS$_2$ crystalline phase.

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A Phase-space View of Environmentally Driven Processes in the Virgo Cluster

  • Yoon, Hyein;Chung, Aeree;Smith, Rory;Jaffe, Yara L.
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.69.3-70
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    • 2016
  • We study the orbital histories of Virgo galaxies undergoing different HI gas stripping stages using phase-space diagrams. Based on the HI properties of galaxies, we find that location of galaxies is in good agreement with ram-pressure stripping predicted by numerical simulations with different infall time. For example, galaxies experiencing active gas stripping are mostly found in the first infall region showing high velocity with respect to the cluster center. Meanwhile, most galaxies that are likely to have lost gas a while ago are found in the cluster outskirts with low orbital velocities. We also discuss the cases where observational properties of galaxies and their locations in the phase-space do not well agree. In addition, we probe the phase-space of filaments and subgroups around or within Virgo. Our results strongly suggest that substructures can play important roles in galaxy evolution while galaxies are falling to the cluster.

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Study on the two phase turbulent heat transfer of gas-solid supension flow in pipes (固體粉末이 浮上된 二相亂流 管流動의 熱傳達에 관한 硏究)

  • 김재웅;김봉기;최영돈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.3
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    • pp.528-537
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    • 1989
  • The objective of this paper is to investigate effects of the specific heat and the diameter of suspending particles on the heat transfer coefficient of two phase turbulent flow with suspension of solid particles in a circular tube with constant heat flux. Heat transfer coefficients of two phase turbulent flow in pipe with suspension of graphite powder were measured with variations of particle sizes and solid-gas loading ratio. Measured data were compared with predictions by numerical analysis in which the turbulece models are closed on the first order level. Results show that heat transfer coefficient increases with increasing the solid-gas loading ratio and the specific heat of suspending material, however, it decreases as the average diameter of particles decreases below $24{\mu}m$.

A Study on Economics of Air Stripping Towers and Activated Carbon Adsorption(Multicomponent System) (충전탑 공기 스트리핑과 활성탄 흡착의 경제성에 관한 연구(다중성분계))

  • Yoo, Ho Sik
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.4
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    • pp.33-42
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    • 1998
  • The optimum design and preliminary cost estimations of air stripping towers ASTs with granular activated carbon adsorption (GAC) systems as the off-gas treatment were done and compared to liquid-phase GAC system. The optimum design and preliminary cost estimations were done for either single or multicomponent systems. A computer program was developed for this study. 15 single compounds and their multicomponent systems were studies. Even with off-gas treatment, AST was generally a less expensive process for treatment of volatile organics than liquid-phase GAC system. Treatment costs of small systems were sensitive to system capacity. Accumulative effect of treatment costs was found in multicomponent systems. The cost of a multicomponent system was highly dependent on the least strippable component in ASTs even with gas-phase GAC or the least adsorbable component in liquid-phase GAC system.

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Electrostatic Charging and Substrate Seeding in Gas Phase Synthesis of Nanocrystalline Diamond Powder

  • Cho, Jung-Min;Lee, Hak-Joo;Choi, Heon-Jin;Lee, Wook-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.418-418
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    • 2012
  • Synthesis of nanocrystalline diamond powder was investigated via a gas-to-particle scheme using the hot filament chemical vapor deposition. Effect of substrate surface seeding by nano diamond powder, and that of the electrical conductance of the substrate were studied. The substrate temperature, methane content in the precursor gas, filament-substrate distance and filament temperature were $670^{\circ}C$, 5% methane in hydrogen, 10 mm and $2400^{\circ}C$, respectively. The powder formation by gas-to-particle mechanism were greatly enhanced by the substrate seeding by the nano diamond powder. It was attributed to the removal of the electrostatic force between the substrate and the seeded nano diamond particle by the thermal electron shower from the hot filament, via the depolarization of the substrate surface or the attached diamond powder and subsequent levitation into the gas phase to serve as the gas-phase nucleation site. The powder formation was greatly favoured by the conducting substrate relative to the insulating substrate, which proved the actual effect of the electric static force in the powder formation.

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Estimation of Air Concentrations of PCBs using Passive Air Samplers (PAS) and a Gas/particle Partition Model (Passive Air Sampler (PAS)와 기체/입자 분배모델을 이용한 대기 중 PCB 농도 산정)

  • Baek, Song-Yee;Choi, Sung-Deuk;Chang, Yoon-Seok
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.6
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    • pp.734-743
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    • 2007
  • Polyurethane foam-disk passive air samplers (PAS) were deployed in a southern area of Korea for three months. The target compounds were 12 coplanar polychlorinated biphenyls (PCBs). The congener profiles measured in this study were the same as those in ambient air and emission gas from the incinerator. A gradient of the total PCBs in different regions (industrial>residential>rural) was observed, suggesting the industrial complex may be an important source of coplanar PCBs. In general, only gas-phase compounds are mainly sequestrated by PAS. In order to estimate the concentration of particle-phase PCBs, a gas/particle partition model was used. A combined result (gas+particle-phase PCBs) was compared with previous results, indicating that the level of coplanar PCBs in our study area is comparable to those in other urban sites in the world. The validation of this method for estimating the total concentration is required through additional backup studies.