• 제목/요약/키워드: Gas release

검색결과 660건 처리시간 0.032초

금강 수계 주요지류인 갑천과 미호천에서 잠정유해물질 오염원 확인 연구 (Contamination Sources of Several Potentially Hazardous Compounds Found at the Gap Stream and the Miho Stream, Two Major Tributaries of the Geum River)

  • 이준배;이재정;조윤해;윤조희;홍선화;이대희;이수형;조영환;신호상
    • 한국환경농학회지
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    • 제35권1호
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    • pp.15-23
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    • 2016
  • BACKGROUND: Water quality is of concern to water utility operators, public health officials, and populations using the water. If any contaminant is released from a point of entry, it could be spread rapidly throughout the water stream. So the identification of the location of the points of entry and its release history are critical informations to establish the management strategy.METHODS AND RESULTS: Aniline, nonylphenol, pentachlorophenol and formaldehyde in 39 surface water samples were analysed using Gas chromatography-mass spectrometry (GC-MS) methods. Formaldehyde, aniline and nonylphenol were mainly detected in the near sites where industrial waste water and domestic sewage were discharged into stream. But pentachlorophenol was detected in the downstream samples where pulp manufacturing plants were operated.CONCLUSION: Results indicate that pentachlorophenol found in main stream of Guem river was mainly introduced from pulp manufacture industries. Otherwise, formaldehyde, aniline and nonylphenol were mainly contaminated from the industrial waste water and domestic sewage.

제어를 위한 Lean NOx Trap의 흡장 및 환원 모델링 (Control Oriented Storage and Reduction Modeling of the Lean NOx Trap Catalyst)

  • 이병수;한만배
    • 한국자동차공학회논문집
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    • 제22권2호
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    • pp.60-66
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    • 2014
  • A control oriented model of the Lean $NO_x$ trap (LNT) was developed to determine the timing of $NO_x$ regeneration. The LNT model consists of $NO_x$ storage and reduction model. Once $NO_x$ is stored ($NO_x$ storage model), at the right timing $NO_x$ should be released and then reduced ($NO_x$ reduction model) with reductants on the catalyst active sites, called regeneration. The $NO_x$ storage model simulates the degree of stored $NO_x$ in the LNT. It is structured by an instantaneous $NO_x$ storage efficiency and the $NO_x$ storage capacity model. The $NO_x$ storge capacity model was modeled to have a Gaussian distribution with a function of exhaust gas temperature. $NO_x$ release and reduction reactions for the $NO_x$ reduction model were modeled as Arrhenius equations. The parameter identification was optimally performed by the data of the bench flow reactor test results at space velocity 50,000/hr, 80,000/hr, and temperature of $250-500^{\circ}C$. The LNT model state, storage fraction indicates the degree of stored $NO_x$ in the LNT and thus, the timing of the regeneration can be determined based on it. For practical purpose, this model will be verified more completely by engine test data which simulate the NEDC transient mode.

전력부문 온실가스 감축정책 평가를 위한 상향식 모형화 방안 (A Study on Constructing Bottom-up Model for Electric Sector)

  • 김후곤;백천현;정용주;안영환
    • 에너지공학
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    • 제25권3호
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    • pp.114-129
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    • 2016
  • 국가온실가스 감축 로드맵을 통해 2020년 BAU 대비 약 30%의 온실가스감축을 목표로 하고 있는데, 전력부문의 경우 가장 많은 온실가스 배출을 하고 있어서 감축잠재량 산정에 매우 중요한 부문이다. 전력부문의 경우 온실가스 감축을 위해 수요관리, 전원믹스개선, 연료전환 등과 신재생에너지 비중 확대 등의 정책 및 기술확산 등을 통해 2020년 온실가스 감축 목표달성을 하게 된다. 이처럼 매우 복잡한 전력부문 온실가스 감축 정책 수립 및 평가를 위해 대부분의 국가에서는 상향식 모형 또는 하향식 모형을 이용하고 있다. 본 연구에서는 전력부문 상향식 모형의 일반적인 현황 및 적용방안에 대해서 알아보고, 이를 위해 전력부문의 가장 큰 특징인 구간부하(load region)을 분석하고, 이를 이용하여 수력 및 양수 등을 모형화하는 방안을 제시한다. 또한 전력부문에 대한 상향식 기반의 BAU 모형을 제안하고, 이 모형을 이용하는데 필요한 데이터 및 이슈들을 정리한다.

Ion Beam Modified ppolyimide: A Study of the Irradiation Effect

  • Lee, Y.S.;Lim, K.Y.;Chung, Y.D.;Lee, K.M.;Choi, B.S.;Whang, C.N.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1998년도 제14회 학술발표회 논문개요집
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    • pp.132-132
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    • 1998
  • Ion bombardment in the keV range is known to induce drastic chemical modifications in organic and inoranic molecular comppounds. A degrading effects in orgainc materials such as the release of ppolymer compponents and the chemistry of the iradiation pprocess have been observed. The work to be described was carried out in order to understand the irradiation effect better. The sampple(ppolyimide : Kappton ) Were irradiated by Ar+, Ne+, H+ ions and electrons (3 keV) to fluence ranging from ~1$\times$1015 to ~1$\times$1017 ions/$cm^2$ at room tempperature. The impplant was usually rastered over an area of a few $cm^2$ . These ion impplantation were carried out in an electron sppectrometer ESCA 5700 (ppHI Ltd) at a residual gas ppressure of ~5$\times$10-10 Torr. X-ray pphotoelectron sppectroscoppy(XppS) measurements were made using a monochromatized Al Ka(1486.6 eV) excitation source. The pphotoemitted electrons were detected by hemisppherical analyser with a ppass energy of 23.5 eV. Core-level binding energies were referenced to the Fermi level. To avoid the charging effect it was used the neutralizer. We studied the irradiation effects on ppolyimide with Ar+, Ne+, He+ ions and electrons by XppS which 추 pprovide detailed information concerning the bonding-induced changes.

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In vitro Biofumigation of Brassica Tissues Against Potato Stem Rot Caused by Sclerotinia sclerotiorum

  • Ojaghian, Mohammad Reza;Jiang, Heng;Xie, Guan-Lin;Cui, Zhou-Qi;Zhang, Jingze;Li, Bin
    • The Plant Pathology Journal
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    • 제28권2호
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    • pp.185-190
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    • 2012
  • Sclerotinia sclerotiorum is a serious pathogen which causes yield loss in many dicotyledonous crops including potato. The objective of this study was to assess the potential of biofumigation using three Brassica crops including Brassica napus, B. juncea and B. campestris against potato stem rot caused by S. sclerotiorum by in vitro tests. Both macerated and irradiated dried tissues were able to reduce radial growth and sclerotia formation of five pathogen isolates on PDA, but macerated live tissues were more effective. Compared with other tested crops, B. juncea showed more inhibitory effect against the pathogen. The volatile compounds produced from macerated tissues were identified using a gas chromatograph-mass spectrometer. The main identified compounds were methyl, allyl and butyl isothiocyanates. Different concentrations of these compounds inhibited mycelial growth of the pathogen in vitro when applied as the vapor of pure chemicals. A negative relationship was observed between chemicals concentrations and growth inhibition percentage. In this study, it became clear that the tissues of local Brassica crops release glucosinolates and have a good potential to be used against the pathogen in field examinations.

필로티 구조의 공동주택 화재 위험성 연구 - 의정부 대봉그린 도시형아파트 화재 사례를 중심으로 - (A Study on Fire Risk of Apartment House with Pilotis Structure - Focused on the Fire case of Uijeongbu-si Urban Livig Homes -)

  • 최승복;최돈묵
    • 한국화재소방학회논문지
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    • 제30권3호
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    • pp.48-54
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    • 2016
  • 대부분 필로티 구조 건물은 필로티를 통해야만 출입이 가능한 구조이고 주차장으로 사용할 경우 차량이 연쇄적으로 소훼되면서 짧은 시간에 필로티 전체로 확산된다. 연소 하중이 높은 차량과 천장 단열재에서 생성된 뜨거운 열기와 유독가스는 출입문을 파손시키고 건물내부로 유입되어 계단과 승강기 그리고 전선이 지나가는 피트(EPS)와 같은 경로를 통해 건물 상층으로 확대된다. 필로티에서 화재가 발생할 위험성은 다양하다. 만약 이곳에서 화재가 발생할 경우 입주민들은 건물에 갇혀 생존에 위협을 받을 수밖에 없다. 본 연구는 필로티에서 화재가 발생하여 5명이 사망하고 139명의 다친 의정부 아파트 화재 사례를 살펴보고 필로티 구조의 건물의 화재 취약성을 분석하였다.

Heterogeneous Catalysts for Hydrogen Generation Based on Ru-Incorporated Hydroxyapatite

  • Jaworski, Justyn Wayne;Kim, Dae-Hyun;Jung, Kyeong-Mun;Kim, So-Hue;Jeong, Jong-Ok;Jeon, Hyo-Sang;Min, Byoung-Koun;Kwon, Ki-Young
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.319-319
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    • 2011
  • Hydrolysis of sodium borohydride provides a safe and clean approach to hydrogen generation. Having the proper catalytic support for controlling this reaction is therefore a valuable technology. Here we demonstrate the capability of hydroxyapatite as a novel catalytic support material for hydrogen generation. Aside from being inexpensive and durable, we reveal that Ru ion exchange on the HAP surface provides a highly active support for sodium borohydride hydrolysis, exemplifying a high total turnover number of nearly 24,000 mol $H_2$/ mol Ru. Moreover, we observe that the RuHAP support exhibits a high catalytic lifetime of approximately one month upon repeated exposure to $NaBH_4$ solutions. In addition to examining surface area effects, we also identified the role of complex surface morphology in enhancing hydrolysis by the catalytic transition metal covered surface. Particularly, we found that a polycrystalline RuHAP catalytic support exhibits shorter induction times for the initial bubble formation as well as increased hydrogen generation rates as compared to a single crystal supports. The independent factor of a complex surface morphology is believed to provide enhanced sites for gas release during the initial stages of the reaction. By demonstrating the ability to shorten induction time and enhance catalytic activity through changes in surface morphology and Ru content, we find it feasible to further explore this catalyst support in the construction of a practical hydrogen generator.

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삼중수소취급계통의 설계(II): 주입계통, 재생계통 (Design of Tritium Handling System(II): Injection System, Regeneration System)

  • 김광신;김경숙;정은수;손순환;김위수
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2003년도 가을 학술논문집
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    • pp.117-123
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    • 2003
  • 지난 논문에 이어서 삼중수소 취급시설의 일부인 삼중수소 주입계통과 재생계통을 소개하였다. 두 계통은 모두 삼중수소의 유출이 가능한 계통들로서 GB안에 설치되어야 하는 계통들이다. 삼중수소 주입계통은 삼중수소 취급시설을 사용하여 목적하는 제품을 생산하게 되는 주 계통으로서 삼중수소의 관리를 위하여 정확히 삼중수소의 주입/분배량을 계량할 수 있어야 하고, 주입 후 계통내 잔여 삼중수소를 최대한 회수할 수 있도록 하여 방사성 물질의 환경방출을 최소화 할 뿐만 아니라 귀한 자원의 손실을 최소화하도록 설계되었다. MS, Ni catalyst bed, metal getter 등 재생이 필요한 TRS 내부의 장치들은 별도의 재생계통을 사용하여 재생한다. 다른 장치들의 재생은 장치를 가열하면서 적절한 purge gas를 흘려주는 비교적 간단한 방법으로 재생이 가능하나 삼중수소를 흡착한 metal getter의 삼중수소를 회수해야 하기 때문에 복잡한 공정을 거쳐야 한다.

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화염묘사함수 모델링 결과를 이용한 한계 진폭 예측 (Limit Cycle Amplitude Prediction Using Results of Flame Describing Function Modeling)

  • 김지환;김진아;김대식
    • 한국추진공학회지
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    • 제20권6호
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    • pp.46-53
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    • 2016
  • 희박 예혼합 가스터빈의 연소 불안정 현상을 이해하기 위해서는, 선형 과정에 의하여 얻어지는 고유주파수 및 초기 성장률뿐만 아니라, 연소기 비선형 특성에 의존하는 한계진폭의 예측이 필요하다. 특히 현재의 연구에서는 비선형 거동에 의한 한계 진폭을 예측하기 위해서 유동 섭동과 열발생의 비율이 주파수와 속도 진폭을 정의할 수 있는 화염묘사함수를 적용하였다. 본 연구에서는 화염묘사함수를 얻기 위하여 CFD 기법이 적용되었으며, 이를 통하여 비선형 열음향 해석으로부터 불안정 한계 진폭을 예측할 수 있었다.

커먼레일식 디젤기관의 EGR율과 바이오디젤 혼합율에 따른 연소 및 배기 특성 (Effects of Bio-diesel blending rate on the Combustion and Emission Characteristics in a Common Rail Diesel Engine with EGR rate)

  • 윤삼기;최낙정
    • 동력기계공학회지
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    • 제18권2호
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    • pp.5-11
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    • 2014
  • The purpose of this study is to investigate the specific characteristics of combustion and exhaust emissions on a 4-cylinder common rail diesel engine as EGR rate and the rate of blended bio-diesel was altered. Bio-diesel fuel which is a sort of alternative fuels can be adapted to diesel engine directly without modifying. This study was performed to 2000rpm of engine speed with torque 30Nm while EGR rate and the rate of blended bio-diesel was changed. Decreasing combustion pressure and increasing the rate of heat were occurred when we had changed the EGR rate on the 20% of bio-diesel blended diesel fuel. The maximum pressure of combustion and the IMEP became higher as the EGR rate and the rate of blended bio-diesel were changed. Exhaust gas temperature was increased the higher rate of the blended bio-diesel under the fixed EGR rate. However, it went down as the EGR rate increased. The amounts of CO and Soot were reduced with increasing the rate of the blended bio-diesel without changing EGR rate and raised with increasing of the EGR rate. On the fixed EGR rate, NOx was increased along with growing the rate of the bio-diesel. On the other hand, it was decreased while EGR rate were going up.