• Korean Chemical Engineering Research
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• 제49권4호
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• pp.460-464
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• 2011

Poly(ether-block-amide)(PEBA, $PEBAX^{TM}$)는 열가소성 탄성체(thermoplastic elastomer, TCU)로서 hard-rigid amide block과 soft-flexible ether block으로 구성되어 있으며, 분자량과 두 block간의 구성비에 따라 여러 종류가 있다. $PEBAX^{TM}$는 분리막소재로 이용할 경우, $PEBAX^{TM}$의 hard amide block은 우수한 기계적 특성과 선택도를, 그리고 soft ether block은 높은 투과도를 제공할 수 있다. 따라서 본 연구에서는 2종류의 $PEBAX^{TM}$를 사용하여 기체분리막을 제조하고, 종류에 따른 이산화탄소와 메탄의 투과특성 변화를 연구하였다. 또한 순수 $PEBAX^{TM}$ 분리막의 투과특성을 향상시키기 위해 무기전구체로서 TEOS(tetraethoxysilane)를 사용하여 $PEBAX^{TM}$/TEOS 하이브리드막을 제조하고, 그 투과특성을 순수 $PEBAX^{TM}$ 분리막의 결과와 비교하였다. 순수 $PEBAX^{TM}$-1657과 $PEBAX^{TM}$-2533 분리막의 투과도 측정 결과, ether block의 비율이 상대적으로 높은 $PEBAX^{TM}$-2533 분리막의 투과도 계수가 보다 높은 투과도 계수값을 가졌다. 이는 $PEBAX^{TM}$-2533의 경우, 상대적으로 높은 ether block 함량 때문에 고분자 사슬의 유연성이 보다 크기 때문으로 볼 수 있다. $PEBAX^{TM}$/TEOS 하이브리드 분리막의 투과특성을 순수 $PEBAX^{TM}$ 분리막의 결과와 비교할 때, 하이브리드 분리막의 기체 투과도 계수가 보다 높음을 알 수 있다. 이는 TEOS의 축합반응으로 생성된 silica domain에 의해 결정성이 감소하고 또한 이산화탄소와 silanol group과의 친화도(affinity) 증가에 따른 용해도가 증가하기 때문으로 볼 수 있다. 하이브리드 분리막의 투과도 계수 증가에도 불구하고 이상분리인자는 거의 비슷하거나 약간 감소하였음을 알 수 있다. 이는 이산화탄소와 silanol group의 친화도 증가로 인한 용해선택도의 증가에 기인한 것으로 볼 수 있다.

• 한국진공학회지
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• 제14권2호
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• pp.69-77
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• 2005

중성입자빔 가열장치의 이온원과 빔라인 부품들을 개발하고 시험하기 위해 제작한 부피 $60m^3$의 시험설비에는 특성 비교를 위해 몇 가지 다른 방식으로 제작된 대용량 크라이오 흡착펌프를 장착하여 사용하고 있다. 크라이오 펌프의 활성탄 패널을 냉각시키면서 수소를 적절한 간격으로 도입하여 수소 분압을 측정하고 그 시간적인 변화를 통해 온도에 따른 수소흡착과 방출특성을 분석해 보았으며 관련 파라미터 사이의 상호 영향에 대해 알아보기 위해 시뮬레이션을 수행했다.

• 한국자동차공학회논문집
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• 제18권5호
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• pp.1-8
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• 2010

The introduction of mixture heterogeneity has been considered to be one of the ways to avoid knocking, as it reduces the pressure rise rate in HCCI Combustion. The purpose of this research was to investigate the effects of heterogeneity, in particular thermal stratification and fuel strength stratification, on HCCI Combustion fueled with DME and n-Butane. Thermal stratification is formed in the Combustion Chamber of a Rapid Compression Machine with three kinds of pre-mixture, each with different properties. The stratified charge mixture was adiabatically compressed, throughout which cylinder gas pressure and two-dimensional chemiluminescence images were measured and analyzed.

• Mass Spectrometry Letters
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• 제8권4호
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• pp.79-89
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• 2017

Ion mobility mass spectrometry (IM-MS) combines the advantages of ion mobility spectrometry (IMS) and MS for effective gas-phase ion analysis. Separation of ions based on their mobilities prior to MS can be performed without a great loss in other analytical figures of merit, and the extra dimension of analysis offered by IM can be beneficial for isomer and complex sample analyses. In this review, basic principles of IMS and IM-MS are described in addition to an introduction to various IMS techniques and commercial IM-MS instruments. The nature of collision cross-section (${\Omega}_D$), an important parameter determining the transport properties of ions in IMS, is also explained in detail.

• Environmental Engineering Research
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• 제20권4호
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• pp.307-328
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• 2015

The increasing demand for materials, energy and products drives chemical engineers to propose new solutions everyday able to promote development while supporting sustainable industrial growth. Membrane engineering can offer significant assets to this development. Here, they are identified the most interesting aspects of membrane engineering in strategic industrial sectors such as water treatment, energy production and depletion and reuse of raw materials. The opportunity to integrate membrane units with innovative systems to exploit the potential advantages derived from their synergic uses is also emphasized. The analysis of the potentialities of these new technologies is supported by the introduction of process intensification metrics which provide an alternative and innovative point of view regarding the unit performance, highlighting important aspects characterizing the technology and not identified by the conventional analysis of the unit performance.

• 기술사
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• 제43권1호
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• pp.26-31
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• 2010

The changes of climate and earth environment caused by Global Warming has seriously occurred recently. For instance, the water in the Chad Lake in Africa has continuously disappeared and Tuvalu in the South Pacific is facing a serious natural disaster with that the entire country is sinking under the sea. These natural disasters become a serious risk threatening the existence of the human-race. Therefore, we needs a fundamental measure to prevent Global Warming. That is a natural phenomenon that makes the earth warmer by 6 types a greenhouse gas including $CO_2So$ we look for an answer from the 'Green Growth' movement.

• 한국막학회:학술대회논문집
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• 한국막학회 1997년도 추계 총회 및 학술발표회
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• pp.5-8
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• 1997

Introduction : Membranes made from inorganic materials are generally superior to organo-polymeric materials in thermal and mechanical stability, and chemical resistance. Among inorganic materials zeolite is a promising candidate for a high performance membrane because of the unique characteristics of zeolite crystals such as molecular sieving, ion exchange, selective adsorption and catalysis. Although there are many recent reportsl on the preparation of zeolitc membranes and the gas permeation through the membranes, only a limited number of publications deal with pervaporation studies. Recently, we have reported a high pervaporation performance of NaA zeolite membrane for the separation of water/organic liquid mixtures. and of NaY zeolite menlbrane for the separation of methanol/MTBE. Here, preparation of zeolite (LTA, ZSM-5 and FAU) membranes and their permeation properties are discussed.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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• pp.1539-1540
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• 2008

The field degradation of carbon nanotube field emitters in diode emission at constant current was demonstrated to be highly dependent upon the presence of residual gases at partial pressures. Upon exposure to a higher pressure of oxygen containing gases, for example, $O_2$ and CO increased the voltage. Those gases give rise to chemical etching to CNTs emitters. On the contrary, $CH_4$ affected the emission properties in the opposite direction as decreasing the voltage which was probably attributed to the introduction of adsorbate tunneling states. The mixed gas may cause a combined effect of both adsorbate tunneling states and CNT etching.

• 한국세라믹학회지
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• 제33권8호
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• pp.935-941
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• 1996

Two-dimensional carbon/carbon preforms made of PAN-based carbon yarn and phenolic resin were densified with pyrolysis of propane by pulse chemical vapor infiltration where repeated the cycle of gas introduction residence and evacuation. Maximim density increment was 14% when infiltration temperature and time were 100$0^{\circ}C$ and 21.25 hrs respectively. The distribution of deposits of pyrocarbon by this process has been occurred uniformly in the bottom middle and top of carbon/carbon composite preform Pulse CVI with residence is most effective in increasing density and shortening infiltration time among isothermal CVI and pulse CVI with and without residence.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2004년도 춘계학술발표회
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• pp.475-482
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• 2004

The purpose of this paper is to study on the investigation of abandoned waste landfill for rehabilitation. The geotechnical and environmental field and laboratory tests for wastes dumped at municipal site were carried out. Testing wastes were sampled at the illegal landfill site The various samples such as waste. soil, groundwater, gas, leachate were taken in the landfill site. As a result of this study, the engineering properties and concentration of samples were investigated The result of this study was used for introduction the rehabilitation method and treatment of unregulated closed landfill.