• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.2 s.245
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• pp.170-176
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• 2006

A spark discharge aerosol generator using air as a carrier gas has successfully been applied to silver nanoparticle production. The spark discharge between two silver electrodes, which was periodically obtained by discharging the capacitor, produced sufficient high temperatures to evaporate a small fraction of the silver electrodes. The silver vapor was subsequently supersaturated by rapid cooling and condensed to silver nanoparticles by nucleation and condensation. The morphology of the generated particles observed by transmission electron microscope was spherical. The element composition of the nanoparticles was silver, which was determined by energy dispersive X-ray spectroscopy. The crystal phase of the particles spark-generated under air atmosphere was composed of silver and silver oxides phase, which was determined by Xray diffraction analysis. While the nanoparticles generated under nitrogen atmosphere had only silver phase. This XRD data indicates that some fraction of the evaporated silver vapor could be oxidized in air atmosphere by the reaction with oxygen. A stable operation of the spark discharge generator has been achieved. The size and concentration of the particles can be easily controlled by altering the repetition frequency, capacitance, gap distance and flow rate of the spark discharge system.

• Journal of the Korean Society of Combustion
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• v.16 no.3
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• pp.12-20
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• 2011

Oxy-coal combustion for $CO_2$ capture in coal power plants entails a mode switching from air-firing to oxyfiring. In this study, procedure of the mode switching was investigated and discussed through experiments in pilot scale facilities: (1) a 0.3 $MW_{th}$ furnace with a vertical single burner and a FGR(Flue Gas Recirculation) system (2) a 1 $MW_{th}$ furnace with horizontal 4 burners and a FGR system. Principle of the mode switching was established and performed with control of FD fan, FGR fan, ID fan and oxygen flow rates. We have found that equivalence ratio in the oxy-firing mode should be increased more than that in the air-firing to achieve stable mode switching. Control of FD, ID and FGR fans should be performed carefully in the mode switching, in the sense of complete combustion and flame attachment. Moisture contents in the ash and the flue gas recycled to the primary oxidizer stream should be removed to prevent condensation, corrosion and duct clogging.

• Journal of Hydrogen and New Energy
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• v.25 no.2
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• pp.200-208
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• 2014

This paper presents thermodynamic performance analysis of organic Rankine cycle (ORC) using low temperature heat source in the form of sensible energy and using liquefied natural gas (LNG) as heat sink to recover the cryogenic energy of LNG. LNG is able to condense the working fluid at a very low condensing temperature in a heat exchanger, which leads to an increased power output. Based on the mathematical model, a parametric analysis is conducted to examine the effects of eight different working fluids, the turbine inlet pressure and the condensation temperature on the system performance. The results indicate that the thermodynamic performance of ORC such as net work production or thermal efficiency can be significantly improved by the LNG cold energy.

• Journal of Powder Materials
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• v.14 no.3 s.62
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• pp.165-172
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• 2007

The purpose of this study was to analyze the sintering characteristics of gold and silver nanoparticles. In this study, gold and silver nanoparticles were prepared by using Inert Gas Cndensation (IGC). The sintering temperatures for gold and silver nanoparticles were $100{\sim}1000^{\circ}C\;and\'100{\sim}500^{\circ}C$, respectively. The sintering characteristics of gold and silver nanoparticles prepared by IGC were evaluated by X-ray diffraction(XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). Gold and silver nanoparticles with the size of $1{\sim}100\;nm\;and\;10{\sim}100\;nm$, respectively, were obtained. The size of sintered gold and silver nanoparticles increased with an increase in the sintering temperature. XRD data showed that silver nanoparticles were similar with polycrystal single-phase.

• Korean Journal of Materials Research
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• v.13 no.8
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• pp.550-554
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• 2003

Current nanogold cluster synthesized by chemical routine with 11 or 55 atoms of gold has been widely used for immuno chemistry probe as a form of nanocluster conjugated with biomolecules. It would be an undeveloped region that the 1 nm size of nanogold could be made by materials engineering processing. Therefore, objective of this study is to minimize the size of gold nanocluster as a function of operating temperature and chamber pressure in inert gas condensation (IGC) processing. Evaporation temperature was controlled by input current from 50 A to 65 A. Chamber pressure was controlled by argon gas with a range of 0.05 to 2 torr. The gold nanocluster by IGC was evaluated by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The gold nanocluster for TEM analysis was directly sampled with special in-situ method during the processing. Atomic force microscopy (AFM) was used to observe 3-D nanogold layer surfaces on a slide glass for the following biomolecule conjugation step. The size of gold nanoclusters had a close relationship with the processing condition such as evaporation temperature and chamber pressure. The approximately 1 nm size of nanogold was obtained at the processing condition for 1 torr at $1124 ^{\circ}C$.

• Journal of the Korean Society of Safety
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• v.8 no.4
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• pp.175-182
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• 1993

Volatilization of toxic heavy metals, especially, metal chlorides at elevated temperatures in oxidation conditions was observed using a thermogravimetric furnace since such metal chlorides used to be a cause for the disease of industrial workers by their toxicity and high volatile extent. Most of tested metal chloride compounds were evaporated or decomposed into gas phase at elevated temperatures ranged from 200~90$0^{\circ}C$, while CrCl$_3$ and NiC1$_2$became stable with converting into oxide forms. A kinetic model for evaporation/condensation could predict maximum evaporation flux and the calculated values were compared with real evaporation flux. The ratio of two fluxes could be explained as the fraction of impinging gas molecules to the condensing surface( $\alpha$ ) and obtained in the range of 10$^{-3}$ ~10$^{-9}$ for the experimented toxic heavy metal chlorides. This ratio might be used to define the volatile extent or toxicity of such toxic metal compounds. The schemes to avoid volatilization of toxic heavy metals Into the atmosphere were suggested as follows ; 1 ) controlling the compositions of metals and Chlorine produced substances( such as PVC ) in the treated materials using a reverse estimation from regulatory limit and characteristics of a processing facility, 2) Installation of wet type devices such as a scrubber for condensing the metal compounds.

• Proceedings of the Korean Nuclear Society Conference
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• 1995.10a
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• pp.403-410
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• 1995

A loss of the residual heat removal (RHR) accident during mid-loop operation of Yong-gwang Nuclear Units 3/4 was analyzed using the RELAP5/MOD3.1.2 code. In this work the following assumptions are used; (i) initially the reactor coolant system (RCS) above the hot leg center line is filled with nitrogen gas, (ii) two 3/4-inch diameter vent valves on the reactor vessel head and the top of pressurizer in the reactor coolant system are always open, and a level indicator is connected to the RMR suction line, (iii) the two steam generators are in wet layup status and the steam generator atmospheric dump valve assemblies are removed so that the secondary side pressure remains at nearly atmospheric condition throughout the accident, and (iv) the loss of RHR is presumed to occur at 48 hours after reactor shutdown. Findings from the RELAP5 calculations are (i) the core boiling begins at ∼5 min, (ii) the peak RCS pressure is ∼3.0 bar, which implies a possibility of temporary seal break, (iii) ∼94 % of the decay heat is removed by reflux condensation in the steam generator U-tubes in spite of the presence of noncondensable gas, (iv) the core uncovery time is evaluated to be 7.2 hours. Significant mass errors were observed in the calculations.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.407-408
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• 2011

Natural boron consists of two stable isotopes 10B and 11B with natural abundance of 18.8 atom percent of 10B and 81.2 atom percent of 11B. The thermal neutron absorption cross-section for 10B and 11B are 3837 barn and 0.005 barn respectively. 10B enriched specific compounds are used for control rods and as a reactor coolant additives. In this work 2 methods for boron enrichment were analysed: 1) Gas irradiation in static conditions. Dissociation occurs due to multiphoton absorption by specific isotopes in appropriately tuned laser field. IR shifted laser pulses are usually used in combination with increasing the laser intensity also improves selectivity up to some degree. In order to prevent recombination of dissociated molecules BCl3 is mixed with H2S 2) SILARC method. Advantages of this method: a) Gas cooling is helpful to split and shrink boron isotopes absorption bands. In order to achieve better selectivity BCl3 gas has to be substantially rarefied (~0.01%-5%) in mixture with carrier gas. b) Laser intensity is lower than in the first method. Some preliminary calculations of dissociation and recombination with carrier gas molecules energetics for both methods will be demonstrated Boron separation in SILARC method can be represented as multistage process: 1) Mixture of BCl3 with carrier gas is putted in reservoir 2) Gas overcooling due to expansion through Laval nozzle 3) IR multiphoton absorption by gas irradiated by specifically tuned laser field with subsequent gradual gas condensation in outlet chamber It is planned to develop software which includes these stages. This software will rely on the following available software based on quantum molecular dynamics in external quantized field: 1) WavePacket: Each particle is treated semiclassicaly based on Wigner transform method 2) Turbomole: It is based on local density methods like density of functional methods (DFT) and its improvement- coupled clusters approach (CC) to take into account quantum correlation. These models will be used to extract information concerning kinetic coefficients, and their dependence on applied external field. Information on radiative corrections to equation of state induced by laser field which take into account possible phase transition (or crossover?) can be also revealed. This mixed phase equation of state with quantum corrections will be further used in hydrodynamical simulations. Moreover results of these hydrodynamical simulations can be compared with results of CFD calculations. The first reasonable question to ask before starting the CFD simulations is whether turbulent effects are significant or not, and how to model turbulence? The questions of laser beam parameters and outlet chamber geometry which are most optimal to make all gas volume irradiated is also discussed. Relationship between enrichment factor and stagnation pressure and temperature based on experimental data is also reported.

• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.1
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• pp.61-67
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• 2015

The cooling of hot exhaust gas is an important issue for the construction of combustor test facility. Water spray is an effective method for exhaust gas cooling due to its large latent heat in process of evaporation. In this study, 1-D analysis has been performed based on continuity, energy conservation, and saturated vapor property to understand water spray cooling of combustion gas. In the exhaust duct of combustor test facility, the injected water decreases combustion gas temperature, and evaporates in the combustion gas. However, some of the injected water is collected in the sump due to condensation. The evaporation of water helps combustion gas cooling, but causes pressure increase inside the exhaust duct due to increase of vapor pressure. These phenomena has been analyzed by 1-D modeling in this study. From 1-D analysis, the adequate mass flow rate of water spray to cool combustion gas and to avoid excessive pressure rise inside the exhaust duct has been decided.

• Journal of computational fluids engineering
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• v.12 no.1
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• pp.9-15
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• 2007

A three dimensional numerical model to predict the flow and transport of mixtures and also the electrochemical reactions in polymer electrolyte membrane (PEM) fuel cells is developed. The numerical computation is base on vorticity- velocity method. Governing equations for the flow and transport of mixtures are coupled with the equations for electrochemical reactions and are solved simultaneously including production and condensation of vapor. Fuel cell performance predicted by this calculation is compared with the experimental results and resonable agreements are achieved.