• Fire Science and Engineering
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• v.21 no.1 s.65
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• pp.90-97
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• 2007

Combustion characteristics and toxicity of combustion gas of wallpaper samples were analyzed to evaluate the fire risk of wallpaper furnished in living space. In this study ash residue ratio was measured with high temperature electric furnace, and thermal analysis was carried out with TGA. Combustion time and smoke concentration were measured with cone heater and combustion gas analyzer. Smoke density of samples was measured using smoke chamber of ASTM E 662. The experimental results were showed as followings. Pyrolysis of silk wallpaper started at lower temperature compared to the other samples. It means that the silk wallpaper can be ignited at low heat flux and will have more fire risk than the others. Ignition time by radiation heat flux of silk wallpaper is shorter compared to the other samples, so evacuation time must be reduced. In the case of vinyl coated silk wall paper, carbon mono oxide concentration is the highest and the toxicity and damage effect to consciousness was stronger compared to the other samples. Smoke density of silk wall paper and fire retardant mixed coated silk wall paper were very high due to vinyl coating.

• Applied Chemistry for Engineering
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• v.23 no.3
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• pp.333-338
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• 2012

To verify the utilization of fluff refuse derived fuel (RDF) as energy source, the combustion charateristic has been studied by an experimental combustion furnace under various temperatures. The characteristics of flue gas, dust and residue from fluff RDF combustion has been analyzed and compared with those of pelletized RDF. From this work, it was found that the incomplete combustion of fluff RDF was greater than that of pelletized RDF because the combustion reaction rate of fluff RDF was faster than that of pelletized RDF, and oxgen concentration in fluff RDF combustion decreased rapidly. It was also found that carbon monoxide concentration of flue gas from fluff RDF combustion increased with combustion temperature because the oxygen consumption and the incomplete combustion increased. Therefore, it is felt that the combustion operation conditions of fluff RDF should be carefully determined.

• Journal of Hydrogen and New Energy
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• v.16 no.4
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• pp.391-399
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• 2005

This paper deals with the survey of domestic hydrogen production, consumption, and distribution. The amount of domestic hydrogen production and consumption has not been identified, and we survey the amount of domestic hydrogen production and consumption by industries. The hydrogen production industries are classified into the oil industry, the petrochemical industry, the chemical industry, and the other industry. In 2004, the amount of domestic hydrogen production was 972,601 ton, which corresponded to 1.9% of the global hydrogen production. The oil industry produced 635,683 ton(65.4%), the petrochemical industry produced 241,970 ton(24.9%), the chemical industry produced 66,250 ton(6.8%), the other industry produced 28,698 ton(2.9%). The hydrogen consumptions of corresponding industries were close to the hydrogen productions of industries except that of the other industry. Most hydrogen was used as non-energy for raw materials and hydrogen additions to the process. Only 122,743 ton(12.6%) of domestic hydrogen was used as energy for heating boilers. In 2004, 47,948 ton of domestic hydrogen was distributed. The market shares of pipeline, tube trailers and cylinders were 84.4% and 15.6%, respectively. The purity of 31,848 ton(66.4%) of the distributed hydrogen was 99.99%, and 16,100 ton(33.6%) was greater than or equal to 99.999%. Besides domestic hydrogen, we also identify the byproduct gases which contain hydrogen. The iron industry produces COG( coke oven gas), BFG(blast furnace gas), and LDG(Lintz Donawitz converter gas) that contain hydrogen. In 2004, byproduct gases of the iron industry contained 355,000 ton of hydrogen.

• Journal of the Korean Institute of Gas
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• v.12 no.2
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• pp.1-6
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• 2008

For the safety design and operation of many gas process, it is necessary to know certain explosion limit, flash point, autoignition temperature (AIT) and minimum oxygen concentration of handling substances. Also it is necessary to know explosion limit at high temperature and pressure. In this study for the safe handling of hydrogen, explosion limit and AIT of combustion properties for hydrogen were investigated. By using the literatures data, the lower and upper explosion limits of hydrogen recommended 4.0 vol% and 77.0 vol%. Also the AIT of hydrogen with ignition sources recommended $400^{\circ}C$ at the electrically heated crucible furnace (the whole surface heating) and recommended $640^{\circ}C$ at the local hot surface. The new equations for predicting the temperature and the pressure dependence of the explosion limits of hydrogen are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.12
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• pp.991-997
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• 2014

This study investigated the swirling flow fields of a gun-type gas burner (GTGB) without a combustion chamber under cold flow conditions. Three velocity components and the static pressure were measured with a straight-type five-hole pressure probe (GHPP) using a non-nulling calibration method and compared with the results of an X-type hot-wire probe (X-probe) and computational fluid dynamics (CFD). The GHPP measured the velocity and static pressure for the swirling flow of the central region of the GTGB better than the X-probe but produced slightly worse results than the CFD.

• Resources Recycling
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• v.20 no.4
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• pp.71-77
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• 2011

$MoO_3$ powders were reduced to $MoO_2$ under Ar+$H_2$ gas mixture in a tubular furnace at temperature range 723~873 K. Reaction rate was quantitatively deduced by measuring relative humidity of off gas. Observed reaction rate increased significantly with hydrogen partial pressure and reaction temperature and the rate of $H_2O$ evolution increased drastically during the initial period of reduction. As reduction proceeded, however, $H_2O$ partial pressure decreased noticeably. During the initial period of the reduction, a linear relationship for time dependence of the reduction fraction was observed. The activation energy for the reduction of $MoO_3$ to $MoO_2$was 73.56 kJ/mol during the initial period of reduction.

• Resources Recycling
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• v.27 no.6
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• pp.38-43
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• 2018

In this study, using electro-refining process and methane gas reduction, we performed studying the recovery of tin with high purity from waste tin oxide had used as a electrode rod of ceramic furnace which occurred during glass production process. We recovered the crude tin of 99% purity from a methane gas reduction process and controlled a little amount of impurities. When the electrolytic refining condition was a current density of $60A/dm^2$ and the sulfuric acid concentration of 0.75 mol, 96.8% of recovered tin (99.979% of purity) were recovered during the electrolytic refining. We confirmed that toxic impurities such as Pb, Sb included in electrode rod. could be controlled.

• Journal of the Korea Institute of Building Construction
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• v.17 no.6
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• pp.507-515
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• 2017

This study is to develop a high quality lightweight foamed concrete that can be applied in the field using EXFG by cracking reducing agent combined with FGD and ALS. First, to increase the volume of foam, the flow and density of the mixture was increased and decreased, respectively. At this time, the effect of substitution ratio of EXFG on fluidity was negligible. The fraction of foam was the highest at EXFG 1%, and the settlement was found to be prevented by the expansion reaction at EXFG 1%. At this time, the ratio of foam was 65%. In the compressive strength, the strengths were similar or decreased when the substitution ratio of EXFG was more than 1%. The apparent density satisfied the KS 0.5 type at the bubble contents was 65%. In case of EXFG substitution, dry shrinkage was decreased by about 10%. As the substitution ratio of EXFG increased, the thermal conductivity increased proportionally.

• Journal of the Korean Society of Combustion
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• v.10 no.2
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• pp.26-34
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• 2005

The performance of oxygen combustion with $CO_2$ feeding was investigated in a pyrex tube furnace. The inverse type multi-hole burner was used for improving mixing and wide operating range. It introduced oxygen, fuel, and oxygen, respectively, from center tube to outer tubes. Oxygen combustion characteristics with excess oxygen ratio, oxygen feeding ratio, and $CO_2$ feeding flow rate were studied to optimize the operating condition and to apply the oxygen combustion with recirculation of flue gas to a real furnace. This paper presents results on the effect of $CO_2$ feeding flow rate on the structure of the flames and concentrations of NO and CO emissions. The visible flame length was shortest due to well mixing between fuel and oxygen when the oxygen feeding ratio was 0.25. The NO emission was reduced drastically regardless of excess oxygen ratio when the $CO_2$ feeding flow rate was larger than 15 lpm. The CO emission is varied by changing the $CO_2$ feeding flow rate but the CO emission characteristics is highly affected by excess oxygen ratio. When the excess oxygen ratio is below $\lambda=1.1$, the CO emission increased as the $CO_2$ feeding flow rate increased.

• 한국연소학회:학술대회논문집
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• 2005.10a
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• pp.162-169
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• 2005

The performance of oxygen combustion with $CO_2$ feeding was investigated in a pyrex tube furnace. The inverse type multi-hole burner was used for improving mixing and wide operating range. It introduced oxygen, fuel, and oxygen, respectively, from center tube to outer tubes. Oxygen combustion characteristics with excess oxygen ratio, oxygen feeding ratio, and $CO_2$ feeding flow rate were studied to optimize the operating condition and to apply the oxygen combustion with recirculation of flue gas to a real furnace. This paper presents results on the effect of $CO_2$ feeding flow rate on the structure of the flames and concentrations of NO and CO emissions. The visible flame length was shortest due to well mixing between fuel and oxygen when the oxygen feeding ratio was 0.25. The NO emission was reduced drastically regardless of excess oxygen ratio when the $CO_2$ feeding flow rate was larger than 15 lpm. The CO emission is varied by changing the $CO_2$ feeding flow rate but the CO emission characteristics is highly affected by excess oxygen ratio. When the excess oxygen ratio is below ${\lamda}=1.1$, the CO emission increased as the $CO_2$ feeding flow rate increased.