• Title/Summary/Keyword: Furan resin

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A Study on the Reclamation of the Furan Sand by the Fluidized Bed (유동층을 이용한 주물사의 재생에 관한 연구)

  • Baek, Ko-Kil;Choi, Yang-Jin
    • Journal of Korea Foundry Society
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    • v.12 no.6
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    • pp.471-479
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    • 1992
  • For the last 2 decades, the bonding materials for the foundry sand and the foundry equipments with high performance have been developed and employed in the foundry shops. In those periods, the furan resins hardened in higher temperature have been replaced with the self-hardened ones in the room temperature. Simultaneously the various reclamation methods of the self-hardened furan resin sand have been developed in order to get the clean working environments, the reduction of solid wastes and the lower of production cost in the foundry. In this experimental study, the combustion reclamation method using the fluidized bed among the various methods was studied in order to reduce the L.O.I. and /or $N_2$ gas due to the deposition of the furan resins and the hardeners. Comparing the results of this experimental combustion reclamation method with those of the employed pneumatic method, the Surface Stability Index of the specimen made by combustion method is 30% higher than that of the latter one and L.O.I. decreases about 30%. The reclamation temperature of 650$^{\circ}C$ in this experimental fluidized bed would be recommended in the viewpoints of the reclamation period, the fuel consumption and the residual quantity of the furan resin. The formula determining the minimum fluidizing velocities according to the temperatures in the fluidized bed has been obtained.

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Study on the Application of Domestic Artificial Sands for the Self-hardening Molding Process by Using Furan Resin (후란자경성(自硬性) 주형용(鑄型用) 국산인조규사(國産人造硅砂)의 활용(活用)에 관(關)한 연구(硏究))

  • Choi, Chang-Ock;Lee, Sang-Yun
    • Journal of Korea Foundry Society
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    • v.1 no.3
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    • pp.19-29
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    • 1981
  • An emphasis has been placed on the importance of selecting a sand for furan sand process, which ie affected by the properties of sand. Investigations have been carried out to use the domestic artificial sands for the furan sand process. For laboratory investigations, the sands have been prepared and tested for chemical analysis, loss on ignition, sieve analysis, AFS grain fineness number, grain shape, PH value, acid demand, surface shape, theoretical surface area, moisture absorption, crushing durability and compressive strength and S. S. I. of molding sands. Most commercial sands have been found to be able to be used. The main requirement of the sands has been shown to be that 3 or 4 screen sands, AFS no.40-70 (or 100), of low acid demand, good surface area and good grain shape require less resin and catalyst to give an adequate strength.

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The Role of Inorganic Compounds Additions on the Matrix Microtexture Control of C/C Composite (무기화합물 첨가에 의한 C/C복합재료의 매트릭스 조직제어)

  • ;安田榮
    • Journal of the Korean Ceramic Society
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    • v.34 no.11
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    • pp.1151-1158
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    • 1997
  • Fracture of uni-directional carbon fiber reinforced carbon matrix composite is strongly dependent on the orientation of basal plane in graphite matrix when it is limited within matrix. The orientation of basal planes are vertically stacked to carbon fiber which results in the weakness for applied tensile or shear force in thermosetting resin derived-carbon matrix composite. Microtextural control of the matrix was tried through chemical interaction between metal carbides and furan resin derived-carbon matrix. SiC and TiO2 addition made the orientation disordered. However, porosity increased due to decomposition of SiC. Interfacial bonding could be controlled by TiO2 addition, but carbon fiber was considerably reacted with TiC during thermal treatment higher than 2$600^{\circ}C$. Therefore, it is desirable to control the thermal treatment temperature at which decomposition of SiC was not serious and TiC/C was not formed eutectoid.

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Fabrication of Glassy Carbon from Furan Resin (퓨란수지를 이용한 유리질 탄소의 제조)

  • 임연수;김희석;정윤중;김명수;김지현
    • Journal of the Korean Ceramic Society
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    • v.38 no.7
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    • pp.643-647
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    • 2001
  • 퓨란수지로부터 유리질 탄소를 제조하였다. 유리질 탄소의 제조시, 사용된 수지가 경화 및 탄화 단계에서 많은 양의 가스를 방출하면서 큰 수축이 발생하여 크랙을 형성하고 휨 현상을 일으킨다. 이런 현상을 감소시키기 위하여 본 실험에서는 경화단계에서 압력을 가하고, 가열속도를 매우 느리게 하였다. 또한, 경화단계에서 무게감소와 수축율을 억제하고, 발생하는 가스의 배출을 용이하게 하여 궁극적으로는 시편의 크랙 및 휨 현상을 방지하고자 필러와 알콜을 첨가하였다. 그 결과, 무게감소와 수축을 억제하고 밀도의 증가를 가져왔고 유리질 탄소를 용이하게 제조할 수 있었으나 알코올을 첨가한 경우 필러의 양이 증가할수록 높은 비저항 값과 낮은 강도값을 나타내었다. 이런 현상은 알코올이 경화단계에서 분해 증발하면서 미세한 기포를 형성하고 이것들이 기공으로 전이하여 최종 제품에까지 영향을 주었기 때문이다.

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Synthesis and Applications of Spherical Active Carbon Materials (구형 활성탄소의 합성 및 응용)

  • Kim, Hongkyeong
    • Journal of Institute of Convergence Technology
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    • v.3 no.1
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    • pp.45-49
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    • 2013
  • Spherical active carbon materials have been used for the removal of pollutants in the area of food processing, water treatment, air purification, oral administration. Moreover, they are now expected to make an epoch in the areas of electronics, life science, environmental technology, and so on due to their superior physical properties. Carbon particles should be requested for the edgeless spherical shapes in order to minimize the loss due to the abrasion during the process and/or practical use, but the carbon particles manufactured from petroleum-based pitch do not meet these needs. Nowadays, thus, the spherical active carbon particles carbonized from various spherical polymer beads are studied with thermoplastic and/or thermosetting polymers. In this paper, the synthesis of spherical phenolic beads and furan beads, which are thermosetting polymers, and their carbonization techniques are examined.

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Chemical Modification of Wood with Alkylene Oxides, Vinylpirrolidinone and Furans:Effects on Dimensional Stabilization

  • Guevara, R.;Moslemi, A.A.
    • Journal of the Korean Wood Science and Technology
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    • v.10 no.4
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    • pp.38-52
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    • 1982
  • The effect of propylene oxide, butylene oxide, furan resin, and vinylpyrrolidinone in controlling wood dimensional stability have been examined. Wood in the green or ovendry condition was treated with various chemical treatments using a vacuum-pressure procedure, and treated specimens were tested for tangential sweelling, moisture gain, and changes in sorption hysteresis. Results' indicate that propylene oxide, and butylene oxide enhanced with the crosslin king agent trimethylol propane trimethacrylate and applied to ovendry wood were the most efficient chemical treatments in controlling tangential sweeling caused by liquid water or water vapor, and in reducing water vapor adsorption. The sorption behavior of treated wood as depicted by the ratios of sorption was "very favorable" in most instances. In the particular case of furan resin treatments, ratios of sorption were improved from 25 to 100 percent as compared to those of untreated wood.

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Development of Eco-friendly Basalt Fiber-reinforced Furan-based Composite Material with Improved Fire and Flame Retardants for Shipbuilding and Offshore Pipe Insulation Cover (조선해양 파이프 단열재 커버 적용을 위한 내화/난연 성능을 갖는 친환경 바잘트섬유 강화 퓨란계 복합재료 개발 연구)

  • Kwon, Dong-Jun;Seo, Hyoung-Seock
    • Composites Research
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    • v.34 no.1
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    • pp.57-62
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    • 2021
  • As interest in the eco-friendly ships and lightweight equipment is increasing in the shipbuilding and marine industry, composite materials are applied to equipment such as pipes. In this study, a basalt fiber reinforced furan composite (BFC), an eco-friendly material, was manufactured to apply the pipe insulation cover that requires environment-friendly and heat/flame retardant performance. An optimization study of post-curing conditions of BFC was conducted, and experiments and analysis were performed on mechanical strength, heat/flame retardant properties, and affinity properties. Finally, as a result of the study BFC material is proved to be a good candidate to apply pipe insulation cover.

Preparation of Glass-like High-density Carbon by Polymerization of Thermosetting Resin (열경화성 수지의 축중합에 의한 고밀도 유리상 탄소의 제조)

  • Kim, Ji-Hyun;Kim, Hee-Seok;Lim, Yun-Soo;Park, Hong-Soo;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.2
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    • pp.153-159
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    • 2001
  • Due to its low density, good mechanical properties and chemical inertness, glassy carbon(GC) has been studied for appications in several fields. A raw thermosetting resin of furanic resin was polymerized with a curing agent of p-toluenesulfonic acid monohydrate. The maximum yield of GC was obtained at the curing agent content of 1.0 wt% in furanic resin. In order to make thick GC, the affect of graphite filler addition to the furanic resin was investigated. The density and electrical resitivity of GC after graphitization were 1.45 $g/cm^{3}$ and 47 ${\times}10^{-4}$ ${\Omega}$ ${\cdot}$ cm respectively and the amorphous structure of GC was confirmed by XRD profiles with very broad peaks comparable to those of graphite at $206^{\circ}$ and $45^{\circ}$.

Structural and Property Changes in Glass-like Carbons Formed by Heat Treatment and Addition of Filler

  • Kim, Jangsoon;Kim, Myung-Soo;Hahm, Hyun-Sik;Lim, Yun-Soo
    • Macromolecular Research
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    • v.12 no.4
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    • pp.399-406
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    • 2004
  • Glass-like carbon precursors shrink significantly during curing and carbonization, which leads to crack formation and bending. Cured furan resin powder and ethanol were added to furan resin to diminish the weight loss, to suppress the shrinkage and bending, and to readily release the gases evolved during polymerization and curing. Curing and carbonization were controlled by pressure and slow heating to avoid damage to the samples. The effect of the filler and ethanol on the fabrication process was examined by measuring the properties of the glass-like carbon, such as the specific gravity, bending strength, electrical resistivity, and microstructural change. The specific gravities of the filler-added glass-like carbons were higher than those of the ethanol-added samples because of the formation of macropores from the vaporization of ethanol during the curing and polymerization processes. Although the ethanol-added glass-like carbons exhibited lower bending strengths after carbonization than did the filler-added samples, the opposite result was observed after aging at 2,600$^{\circ}C$. We found that the macropores created from ethanol were contracted and removed upon heat treatment. The electrical resistivity of the glass-like carbon aged at 2,600$^{\circ}C$ was lower than those of the samples carbonized at 1,000$^{\circ}C$. We attribute this phenomenon to the fact that aging at high temperature led to well-developed microstructures, the removal of macropores, and the reduction of the surface area.