• Title/Summary/Keyword: Functional resin

검색결과 231건 처리시간 0.029초

Sputtering에 의한 polyester 직물의 박막내구성 개선을 위한 수지처리 효과 (The Effect of Resin Treatment for Improving of the Metal Thin Membrane Fastness on Polyester Fabrics by Sputtering)

  • 구강;전상민;송병갑;박영미
    • 한국염색가공학회지
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    • 제18권3호
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    • pp.31-41
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    • 2006
  • Functional properties are available with sputtering. But sputtering treatment alone cannot got a good fastness performance to washing, rubbing and light. This research was objected to investigate optimum condition by sputtering on polyester through various processing conditions such as ion current and treatment time, and then various resin treated onto metal coated polyester fabrics in order to increase washing fastness of metal membrane. As the results, the optimum conditions revealed 1500 mA of ion current, 2 min of treatment time in sputter, and suitable resin concentrations were 2% of o.w.s (on the weight of solution) in resin treatment. Therefore, we could get enhanced anti-static effect and flex stiffness as well as washing fastness in sputtered polyester fabric with various resin treatment, for example, melamine and polyurethane.

Preparation of polyaniline/cyanoethyl resin blends

  • Kim, Tae-Kyun;Kim, Seong-Hun;Oh, Kyung-Wha
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.93-93
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    • 2003
  • Electrically conducting polyaniline/cyanoethyl resin (PANI/Cyan) blends were prepared by in situ polymerization. The mechanical properties of the blend films increased with increasing cyanoethyl resin and the blend films have moderate conductivity.

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Synthesis of Epoxy Functional Siloxane and its Effect on Thermal Stress

  • Hyun, Dae-Sup;Jeong, Noh-Hee
    • 한국응용과학기술학회지
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    • 제26권4호
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    • pp.379-384
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    • 2009
  • Epoxy resin based encapsulants are widely used in semiconductor packaging applications. Epoxy resin based encapsulants are often subject to crack or delamination during the reliability test due to the thermal stress caused by high modulus nature of epoxy resins. Epoxy functional siloxanes are often added into epoxy resin to reduce the modulus so that the thermal stress can be reduced. Epoxy functional siloxanes, additives for reduced modulus, were synthesized and added into the curable epoxy resins. The modulus and the coefficient of thermal expansion (CTE) were also measured to investigate the thermal stress and to see whether the epoxy functional siloxane adversely affects the CTE or not. As a result, around 26% to 72% of thermal stress reduction was observed with no adverse effect on CTE.

이온교환법에 의한 탈질소 공정개발의 기초연구(V) -질산성 질소 선택적인 이온교환수지의 합성- (Basic Study for Development of Denitrogenation Process by Ion Exchange(V) -Synthesis of Nitrate-Selective Ion Exchange Resines-)

  • 이동환;김승일;전진희;박찬영;이민규
    • 한국환경과학회지
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    • 제9권4호
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    • pp.319-323
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    • 2000
  • Nitrate-selective ion exchange resin which have bulky tertiary amine as functional group have been synthesized by the reaction of chloromethylated polystyrene-divinylbenzene copolymer and the corresponding tertiary amine [$NR_3=NE_{t3} 1, N{(C_2 H_4 H_3)}_32]$in ethanol, while commercial resin has $NMe_3$ as functional group. The fundamental properties such as bulk density, water content, appearance index, exchange capacity, effective size, uniformity coefficient of synthesized anion exchange resin (1) have been measured. The ion exchange resin (1) and (2) exhibited the better selectivity for nitrate than sulfate in both batch and continuous column experiments.

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다목적 기능 합성수지 거푸집 성능평가에 관한 연구 (A Study on Performance Evaluation of Multipurpose Functional Synthetic Resin Formworks)

  • 김태희;안성진;최석;남경용
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2018년도 춘계 학술논문 발표대회
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    • pp.245-246
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    • 2018
  • This paper is a multipurpose functional synthetic resin formwork which can replace existing euro form. We tried to improve the disadvantages such as work noise, stenosis, recyclability, and workability of Euroform system. As a result of the test, Euroform showed an average of 106.7dB and synthetic resin formwork showed an average of 100.4dB. Therefore, it is considered that the synthetic resin formwork has a great effect of noise reduction compared to the euro form.

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다른 pH의 전해질에서 polyvinylidene chloride-resin와 polyvinylidene fluoride로부터 합성된 다공성 탄소의 전하 저장 거동 (Charge Storage Behavior of the Carbons Derived from Polyvinylidene Chloride-resin and Polyvinylidene Fluoride in Different pH Electrolytes)

  • 전상은
    • Composites Research
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    • 제35권6호
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    • pp.394-401
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    • 2022
  • Polyvinylidene chloride-resin(PVDC-resin)와 polyvinylidene fluoride(PVDF)의 두 폴리머 전구체는 열분해 과정을 통해 마이크로 다공성 탄소로 변환되어 되므로 이온 흡/탈착으로 전하를 저장하는 슈퍼커패시터용 전극재료로 유리하다. 더욱이, 두 전구체를 구성하는 여러가지 이종원소들은 탄화 후 작용기를 형성하여 추가적인 전하저장에 기여할 수 있으므로, 탄화 시 생성되는 작용기에 대한 분석은 에너지 저장용 탄소소재를 개발하는데 중요하다. 본 연구에서는 두 폴리머 전구체를 탄화시킨 후 생성된 작용기를 X-선 광전자 분광법(X-ray photoelectron spectroscopy)과 다양한 pH의 전해질에서 탄소 전극의 전기화학 거동 관찰을 통하여 확인하였다. 산성(1 M H2SO4) 전해질에서 측정된 두 탄소 전극의 비전기용량은 생성된 quinone 작용기의 패러데익 충/방전 반응 덕분에 중성 전해질(0.5 M Na2SO4)에서보다 증가하였다. 특히, PVDC-resin으로부터 합성된 탄소는 매우 작은 마이크로 기공이 표면에 형성되어 있어 전해질 이온의 흡착을 어렵게 하므로, PVDF로부터 합성된 탄소 전극에 비해 낮은 용량을 보인다. 염기성 전해질(6 M KOH)에서 두 탄소 전극 모두 3가지 전해질 중 가장 높은 비전기용량이 측정되었는데, 이는 구성하는 전해질 이온들(K+, OH-)이 두 탄소에 형성된 마이크로 기공으로 흡/탈착이 용이하게 일어나는 동시에 패러데익 충/방전 반응으로 추가적인 전하가 저장되었기 때문이다.

A Chelating Resin Containing 2-(2-Thiazolylazo)-5-dimethylaminophenol as the Functional Group: Synthesis and Sorption Behavior for Some Trace Metal Ions

  • Lee, Won;Lee, Si-Eun;Kim, Mi-Kyoung;Lee, Chang-Heon;Kim, Young-Sang
    • Bulletin of the Korean Chemical Society
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    • 제23권8호
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    • pp.1067-1072
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    • 2002
  • A new polystyrene-divinylbenzene resin containing 2-(2-thiazolylazo)-5-dimethylamino-phenol (TAM) functional groups has been synthesized and its sorption behavior for nineteen metal ions, including Zr(Ⅳ),Hf(Ⅳ) and U(Ⅵ) has been investigated by batch and column methods. The chelating resin showed high sorption affinity for Zr(Ⅳ) at pH 1-5 and U(Ⅵ) at pH 4. Some parameters affecting the sorption of the metal ions have been detailed. The breakthrough and overall capacities were measured under optimized conditions. The overall capacities of Zr(Ⅳ), Th(Ⅳ) and U(Ⅵ), which showed higher than the other metal ions, were 0.90,0.84 and 0.80 mmol/g, respectively. The elution order of metal ions at pH 4 was evaluated as Zr(Ⅳ) > Th(Ⅳ) > U(Ⅵ) > Cu(Ⅱ) > Hf(Ⅳ) > W(Ⅵ) > Mo(Ⅵ) > In(Ⅲ) > Sn(Ⅳ) > Cr(Ⅲ) > V(Ⅴ) > Fe(Ⅲ). Quantitative recovery of most metal ions except Zr(Ⅳ) was achieved using 2M HNO3. Desorption and recovery of Zr(Ⅳ) was successfully performed with 2 M HClO4 and 2 M HCl.

1-Aza-18-Crown-6를 이용한 우라늄(VI) 이온 흡착제 수지 합성 (Resin Synthesis of Adsorbent Uranium(VI) Ion using 1-Aza-18-Crown-6)

  • 김선화;김해진
    • 환경위생공학
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    • 제21권4호
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    • pp.49-60
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    • 2006
  • The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 - divinylbenzene(DVB) with 1%, 2%, 4% and 8%-crosslinking and 1-aza-18-crown-6 macrocyclic ligand by copolymerization method. Content of chlorine in styrene-DVB copolymer was decreased as crosslink increased and it is because as crosslink increased 1%, 2%, 4% and 8% DVB content increased and crosslink density increased and cavity was reduced. Functional group of resin almost disappeared as C-C1 peak around $700cm^{-1}$ was substituted with 1-aza-18-C-6 macrocyclic ligand and new peak of C-N around $1020cm^{-1}$ appeared, so it was confirmed that styrene-DVB copolymer and ligand were compounded. As crosslink increased in the analysis of element contents, it resulted in the reduction of nitrogen content and it is because as crosslink increased, it led to the reduction of chlorine content in the process of substitution reaction and it affected macrocyclic ligand substituted. Thermo analysis curve of functional synthetic resin decomposed three part of 1-aza-18-C-6, styrene, and DVB. Form of functional synthetic resin showed distortion of its particles as macrocyclic ligand was introduced to styrene-DVB copolymer and hydrogen of ligand caused substitution with chlorine element of styrene molecule.

ZnO 나노 입자 분산 레진의 thermal imprinting 공정을 통한 기능성 패턴 제작 (Fabrication of Functional ZnO Nano-particles Dispersion Resin Pattern Through Thermal Imprinting Process)

  • 권무현;이헌
    • 한국정밀공학회지
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    • 제28권12호
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    • pp.1419-1424
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    • 2011
  • Nanoimprint lithography is a next generation lithography technology, which enables to fabricate nano to micron-scale patterns through simple and low cost process. Nanoimprint lithography has been applied in various industry fields such as light emitting diodes, solar cells and display. Functional patterns, including anti-reflection moth-eye pattern, photonic crystal pattern, fabricated by nanoimprint lithography are used to improve overall efficiency of devices in that fields. For these reasons, in this study, sub-micron-scaled functional patterns were directly fabricated on Si and glass substrates by thermal imprinting process using ZnO nano-particles dispersion resin. Through the thermal imprinting process, arrays of sub-micron-scaled pillar and hole patterns were successfully fabricated on the Si and glass substrates. And then, the topography, components and optical property of the imprinted ZnO nano-particles/resin patterns are characterized by Scanning Electron Microscope, Energy-dispersive X-ray spectroscopy and UV-vis spectrometer, respectively.

인조스웨드의 견뢰도 향상에 관한 연구 (3) (Enhancement of Dyeing Fastness of Artificial Suede (3))

  • 김경필;김혜인
    • 한국염색가공학회지
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    • 제28권4호
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    • pp.280-289
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    • 2016
  • Silica microgel was prepared by sol-gel process and then functional groups, epoxy group and ethoxy group, were introduced on the particle by coupling treatment with 3-glysidoxypropyltrimethoxysilane. The functional silica microgel(functional SiGel) formation was identified using FT-IR spectrometry. Phase stability for DMF solution of functional SiGel, PU resin and pigment was evaluated by Turbiscan Lab. And physical properties of artificial suede including hand values, morphology and dyeing fastness were investigated. The mean particle size and the specific surface area of the functional SiGel were $0.77{\mu}m$ and $380m^2/g$. Mixture containing the functional SiGel, PU resin and pigment was more stable than the functional SiGel-free mixed solution. Artificial suede prepared by the functional SiGel had appearance and feeling close to natural suede. The migration fastness, the solvent wicking fastness and rubbing fastness of the artificial suede were enhanced to 4~5 grades, 4~5 grades and 3~4 grades, respectively.