Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
권호 표지
DOI QR코드

DOI QR Code

Enhancement of Dyeing Fastness of Artificial Suede (3)

인조스웨드의 견뢰도 향상에 관한 연구 (3)

  • Kim, Kyung Pil (Quality Management Operation Department, Defence Agency for Technology and Quality) ;
  • Kim, Hea In (Department of Organic Material Science and Engineering, Pusan National University)
  • 김경필 (국방기술품질원 품질경영운영실) ;
  • 김혜인 (부산대학교 유기소재시스템공학과)
  • Received : 2016.10.10
  • Accepted : 2016.12.06
  • Published : 2016.12.27
Download PDF
⟨ Previous Next ⟩

Abstract

Silica microgel was prepared by sol-gel process and then functional groups, epoxy group and ethoxy group, were introduced on the particle by coupling treatment with 3-glysidoxypropyltrimethoxysilane. The functional silica microgel(functional SiGel) formation was identified using FT-IR spectrometry. Phase stability for DMF solution of functional SiGel, PU resin and pigment was evaluated by Turbiscan Lab. And physical properties of artificial suede including hand values, morphology and dyeing fastness were investigated. The mean particle size and the specific surface area of the functional SiGel were $0.77{\mu}m$ and $380m^2/g$. Mixture containing the functional SiGel, PU resin and pigment was more stable than the functional SiGel-free mixed solution. Artificial suede prepared by the functional SiGel had appearance and feeling close to natural suede. The migration fastness, the solvent wicking fastness and rubbing fastness of the artificial suede were enhanced to 4~5 grades, 4~5 grades and 3~4 grades, respectively.

Keywords

References

  1. M. Meiji, S. Sei, Japan Pat., 2003-268680(2003).
  2. Y. Hisao, Y. Takeshi, N. Shinji, Japan Pat., 1993-272069(1993).
  3. H. S. Moon, "Japan Chemical Fibers Monthly", Japan Chemical Fibers Association, Tokyo, pp.89-105, 1991.
  4. K. Mitsuaki, T. Hiroyuki, H. Sumio, Japan Pat., 1998-331051(1998).
  5. S. Ioan, G. Grigorescu, and A. Stanciu, Dynamic-mechanical and Differential Scanning Calorimetry Measurements on Crosslinked Poly(ester-siloxane)-urethanes, Polymer, 42, 3633(2001). https://doi.org/10.1016/S0032-3861(00)00747-3
  6. S. Ioan, G. Grigorescu, and A. Stanciu, Poly(estersiloxan) urethanes Compositional Parameters on Differential Scanning Calorimetry and Dynamic-mechanical Measurements, European Polymer J., 38, 2295(2002). https://doi.org/10.1016/S0014-3057(02)00108-8
  7. J. P. Sheth, A. Aneja, G. L. Wilkes, E. Yilgor, G. E. Atilla, I. Yilgor, and F. L. Beyer, Influence of System Variables on the Morphological and Dynamic Mechanical Behavior of Polydimethylsiloxane based Segmented Polyurethane and Polyurea Copolymers: a Comparative Perspective, Polymer, 45, 6919(2004). https://doi.org/10.1016/j.polymer.2004.06.057
  8. S. J. Hinder, C. Lowe, J. T. Maxted, and J. F. Watts, Migration and Segregation Phenomena of a Silicone Additive in aMultilayer Organic Coating, Progress in Organic Coatings, 54, 104(2005). https://doi.org/10.1016/j.porgcoat.2005.04.007
  9. I. Yilgor and J. E. McGrath, 1,3-bis(${\gamma}$-aminopropyl) tetramethyldisiloxane Modified Epoxy Resins: Curing and Characterization, Advanced Polymer Science, 86, 1(1988). https://doi.org/10.1007/BFb0025274
  10. F. Garbassi, M. Morra, and E. Occhiello, "Polymer Surface", John Wiley and Sons, New York, pp.84-97, 1994.
  11. P. F. Bruins, "Silicone Technology", John Wiley and Sons, New York, pp.105-123, 1970.
  12. K. Ishikawa, "Recent Development of Reactive Polymers", CMC, Tokyo, pp.186-198, 2000.
  13. S. Ichinohe, "Research and Development of Polymer Additives", CMC, Tokyo, pp.125-139, 2002.
  14. H. K. Shin, M. W. Huh, and N. S. Yoon, Fabrication of Silica-Containing Breathable Waterproof Polyurethane Dispersion Film, Textile Coloration and Finishing, 27(2), 126(2015). https://doi.org/10.5764/TCF.2015.27.2.126
  15. G. S. Cho, D. H. Lee, H. M. Lim, D. S. Kim, and S. H. Lee, Relationship between the Adsorption of Dye and the Surface Charge Density of Silica Sol, Textile Coloration and Finishing, 26(4), 297(2014). https://doi.org/10.5764/TCF.2014.26.4.297
  16. L. L. Hench and J. K. West, The Sol-gel Process, Chem. Rev., 90, 33(1990). https://doi.org/10.1021/cr00099a003
  17. C. C. J. Brinker and G. W. Scherer, "Sol-Gel Science", Academic Company Press, London, pp.108-123, 1990.
  18. C. C. J. Brinker and G. W. Scherer, "Sol-Gel Science", Academic Company Press, London, pp.100-112, 1990.