• Title/Summary/Keyword: Functional finishing

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Synthesis and Characterization of the New Functional Polymer ―Synthesis of Polymer Containing Phosphorus― (새로운 기능성 고분자의 합성 및 그 특성에 관한 연구(I) ―인 함유 고분자의 합성―)

  • Moon, Byeong Hwa;Son, Tae Won;Lim, Sang Kyn;Koo, Kang
    • Textile Coloration and Finishing
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    • v.8 no.4
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    • pp.4-10
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    • 1996
  • Poly(4-morphonylphosphonate of bisphenol A) (PMPB) was synthesized by the interfacial polymerization of phosphonic dichloride, 4-morphonyl (PDCM) and bisphenol A in an aqueous-organic biphasic system. Synthesized polymer was found to be PMPB by using EA, FT-IR and $^{1}$H-NMR. Prepared PMPB had different values of molecular weight depending on the solubility in the organic phase: the higher the solubility, the higher the molecular weight. PMPB is amorphous and its thermal decomposition temperature is about 35$0^{\circ}C$. PMPB is congenial to application to polypropylene by blending because of no reaction with polypropylene.

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Functional Improvement of Poly(Vinyl Alcohol) Polarized Film by $O_2$ Low Temperature Plasma Treatment (산소 저온 플라즈마 처리에 의한 PVA 편광필름의 기능성 개선)

  • Park, Young-Mi;Hwang, Jong-Ho;Gu, Kang
    • Textile Coloration and Finishing
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    • v.16 no.3
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    • pp.14-21
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    • 2004
  • In this research, we accomplished in order to improving color fastness of sublimation for Poly (vinyl alcohol) (PVA)-iodine polarized film. The poor iodine sublimation problem has greatly improved by $O_2$ low temperature plasma treatment. We obtained the followings: (1) plasma treatment has contributed in adhesive ability via peel strength, AFM image and roughness were investigated, But the improvement in adhesive strength was not linearly proportional to the treatment time. (2) $O_2$ plasma treated PVA-iodine polarized film was good enough as to maintain the transmittance and polarization even after iodine cone. of 0.05mol/L and dipping time of 50sec. (3) $O_2$ low temperature plasma treated PVA-iodine polarized film has obtain high durability because of good adhesive strength.

Functional Finishing of Cotton Fabrics by Treatment with Chitosan

  • Shin, Youn-Sook;Min, Kyung-Hye;Jang, Jeong-In
    • Proceedings of the SOHE Conference
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    • 1997.12a
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    • pp.33-37
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    • 1997
  • Cotton fabric was treated with chitosan solution by pad-dry(-cure) method to impart antimicrobial properties. Four chitosans of different degree of deacetylation(DAC: 65~95%) with similar molecular weight(ca. 50, 000) and one chitosan oligomer(MW 1, 800, DAC 86%) were used. Antimicribial activity against Staphylococcus aureus was evaluated by the Shake Flask Method. Treated fabrics were laundered up to 20 times according to AATCC Test Method 60-1986 and antimicrobial activity of laundered fabrics was evaluated. The antimicrobial activity was increased with the concentration and DAC of chitosan used. And the cured samples showed better durability to laundering than not-cured samples. Crosslinker and binder decreased the antimicrobial activity of fabrics treated with chitosan oligomer and were not effective to improve the durability to washing.

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Thermodynamics of Reactive Dyes with Different Functional Groups (작용기의 종류에 따른 반응염색의 열역학)

  • 도성국
    • Textile Coloration and Finishing
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    • v.10 no.3
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    • pp.36-42
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    • 1998
  • The dyeabilities of C.I. Reactive Blue 19(B19, MW ; 626), C.I. Reactive Blue 4(B4, MW ; 637) and C.I. Reactive Black 5(B5, MW : 991) were investigated. Initial dyeing rates were increased and the amount of dye on the fabric at equilibrium was decreased with temperature like other ordinary dyeing processes. Activation entropy$(\Delta{S}^*)$ was decreased because of loose bonding between dyestuffes and fiber molecules at transition state. It can be clarified that the entire reaction is exothermic and the number of molecular species at transition state becomes greater from decrease in activation enthalpy$(\Delta{H}^*)$ and the increase in activation free energy$(\Delta{G}^*)$ with temperature, respectively. The amount of B19 on the fabric at equilibrium was greater than that of B4, because B4 became unreactive towards textile substrates through hydrolysis. Due to the biggest size of the dye molecule, the reaction rate of B5 was the slowest but its difunctional group played an important role in achieving the greatest amount of dye on the fabric at equilibrium.

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Development of Functional Textile Material by Using Chitosan 1. Preparation and Characterization of Chitosan Fiber and Chitosan Fiber Coated with S-carboxymethyl Keratein (키토산을 이용한 기능성 소재 개발 1. 키토산 섬유와 S-카르복시메틸케라틴 코팅 키토산 섬유의 제조와 특성)

  • 민경혜;신윤숙
    • Textile Coloration and Finishing
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    • v.11 no.3
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    • pp.32-40
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    • 1999
  • Chitosan fiber was prepared by wet spinning with various draw ratio. Chitosan fiber was coated with f-carboxymethyl keratein(SCMK) by extruding chitosan solution into 1 M NaOH solution containing 1% SCMK. Among three chitosan used in this study(chitosans of 5 cps, 50 cps, 100 cps), 50 cps chitosan gave the best tenacity and optimum concentration was 5%. SCMK coating increased the tenacity of chitosan fiber. Regardless of SCMK coating, tenacity and elongation of both chitosan fibers were increased with the increase of draw ratio. Chitosan fiber showed antimicrobial activity against Staphyloccus aureus showing 66∼72% of bacteria reduction rates. On the other hand, chitosan fiber coated with SCMK didn't show any antimicrobial activity.

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Synthesis and Optical Properties of Novel Chemosensor Based on Rhodamine 6G

  • Kim, Hyungjoo;Son, Young-A
    • Textile Coloration and Finishing
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    • v.24 no.4
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    • pp.233-238
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    • 2012
  • The opto-functional materials have been developed as a promising research topic toward the end uses for optical materials and applications. The attractive area in this part was the design of sensor molecules for detecting harmful environmental factors. These harmful factors impart undesired effects on wide range of chemical and biological phenomenon. In this context, many researchers have studied luminescence chemosensor materials. These sensor molecules showed optical signals such as color or fluorescence change by detecting harmful environmental factors. In this study, the novel fluorescence chemosensor 1 has been designed and synthesized through reaction of rhodamine 6g hydrazide and 2-hydroxy-1-naphthaldehyde. The chemosensor 1 had been analyzed by UV-Vis and fluorescence spectrophotometer. We found that this chemosensor 1 has 'off-on' and dual type sensing properties toward $Cu^{2+}$ and $Mg^{2+}$.

Dyeing of Polyvinyl Alcohol Fibers in Filament Yarn Form with Reactive and Vat Dyes

  • Rashad, Mahmood;Kim, Sam-Soo;Huh, Man-Woo;Yoon, Nam-Sik
    • Textile Coloration and Finishing
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    • v.19 no.5
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    • pp.17-23
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    • 2007
  • As polyvinyl alcohol(PVA) filament yarn is commercially used in many fields due to its high strength and modulus properties. This research was carried out to study the dyeing behavior of PVA and to find out appropriate dye for better dyeing. As the dyeing behavior of PVA fiber is similar to cellulose due to the same functional group, reactive and vat dyes were selected for the dyeing. Color strength of PVA fibers treated with vat dyes was found to be better than those with reactive dyes, because of the low fixation of reactive dye on fibers. Most of the reactive dye may became hydrolyzed, and flushed away with water in washing. Colorfastness to laundering was shown to be very high for both of the reactive-dyed and vat-dyed PVA fibers.

Hydrophilization of PP Fiber through Atmospheric Pressure Plasma Processing (대기압 플라즈마 처리를 통한 PP 섬유의 친수화)

  • Cho, Hang Sung
    • Textile Coloration and Finishing
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    • v.33 no.3
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    • pp.113-119
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    • 2021
  • Polypropylene fiber has the advantages of light weight, heat retention and antibacterial properties, but it is difficult to expand its market because it cannot be dyed or imparted functionality due to its hydrophobic properties. Atmospheric pressure plasma processing can modify the surface of the fiber and create polar functional groups on the surface of the fiber. In this study, an experiment was conducted on the hydrophilization of the ultra-hydrophobicity of polypropylene through plasma processing and surface changes before and after plasma processing. The ultra-hydrophobicity of polypropylene is the cause of impossible for dyeing and imparting functionality. Untreated polypropylene became hydrophilic, and it was confirmed that the ratio of oxygen and carbon(O/C) increased about 11 times from untreated polypropylene 0.017 to plasma-treated polypropylene 0.190.

Dyeing Properties of Functional PET Double Knit Fabric (기능성 폴리에스터 이중 편성물의 염색 특성)

  • Lee, Bum Hoon
    • Textile Coloration and Finishing
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    • v.34 no.3
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    • pp.146-156
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    • 2022
  • In this study, the dyeing properties of double knit fabric composed of PET/PTT bi-component fiber and quick dry fiber were examined with disperse dyes. In addition, the shrinkage characteristics were investigated during the dyeing process. The K/S values and shrinkage rate of PET/PTT bi-component fiber were higher than those of PET/co-PET bi-component fiber and quick dry fiber. In the dye bath, dye migration of exhausted on PET/PTT bi-component fiber to quick dry fiber was found at high dyeing temperature. It was not found that there was a significant difference in K/S value on dyeing temperature between 115℃ and 130℃. But the slight color difference of two sides of a double knit fabric was found.

Physicochemical Properties and Palatability of Pork Fed with Tangerine-Peel (감귤 껍질을 급여한 돈육의 물리화학적 특성 및 기호성)

  • Jung In-Chul;Park Kyung-Sook;Yang Tae-Ik;Moon Yoon-Hee;Yang Seung-Joo;Youn Dong-Hwa
    • Journal of the East Asian Society of Dietary Life
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    • v.16 no.2
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    • pp.174-179
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    • 2006
  • This study was carried out to investigate the possible for utilization of garbage in pig feed by investigating the functional characteristics of pork from pigs fed tangerine-peels. The samples consisted of the pork loin from pigs not fed with tangerine-peel (control), the pork loin fed with 3% and 5% tangerine-peel during growing and finishing period (TP-1), and fed with 6% and 10% tangerine-peel during growing and finishing period (TP-2) there is no respective comparison here. The pH, VBN content TBARS value, bacterial counts, surface color, water holding capacity, loss degree and rheological properties of the samples were determined by physicochemical properties, and the sensory scores were evaluated. The pH, TBARS value, surface color, water holding capacity and loss degree were not different among the samples, but the VBN content and bacterial counts of TP-1 and TP-2 were significantly lower than those of the control (p<0.05). The hardness, springiness, cohesiveness, gumminess and chewiness, taste, aroma, tenderness and juiciness were not different among the samples, but the shear force value and palatability of TP-1 were the highest among the samples (p<0.05).

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