• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.109.1-109.1
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• 2015

Understanding the reaction mechanisms and structures underlying the adsorption of biomolecules on semiconductors is important for functionalizing semiconductor surfaces for various bioapplications. Herein, we describe the characteristic behavior of a primary nucleobase adsorbed on the semiconductor Ge(100). The adsorption configuration of guanine, a primary nucleobase found in DNA and RNA, on the semiconductor Ge(100) at an atomic level was investigated using scanning tunneling microscopy (STM) and density functional theory (DFT) calculations. When adsorbed on Ge(100) at room temperature, guanine appears dark in STM images, indicating that the adsorption of guanine on Ge(100) occurs through N-H dissociation. In addition, DFT calculations revealed that "N(1)-H dissociation through an O dative bonded structure" is the most favorable adsorption configuration of all the possible ones. We anticipate that the characterization of guanine adsorbed on Ge(100) will contribute to the development of semiconductor-based biodevices.

• Proceedings of the KSME Conference
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• 2001.06c
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• pp.333-338
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• 2001

Fault tree is a widely used methodology for analyzing product reliability. The fault trees are usually constructed using the experiences of expert reliability engineers in top-down approaches and have different structures according to each expert's subjectivity. In this work it is tried to find a general method for the fault tree construction based on the function tree that is the result of product function deployment. Based on the function tree, the method has the advantage of resulting an objective fault tree since the faults are defined as the opposite concept of functions. The fault tree construction of this work consists of the following steps: 1) definition of product primary function with the viewpoints of product operation and configuration, 2) construction of functional relation chart using a grouping algorithm, 3) abstraction of functional block diagram according to operation sequences and configuration of a product, 4) construction of function tree for each viewpoint, and 5) construction of fault tree by matching the function tree and simplification of the result.

• Journal of the Korean housing association
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• v.22 no.1
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• pp.35-42
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• 2011

The objective of this study is to investigate the functional conformity based on the analysis of the spatial connectivity of block housing using space syntax. Three cases were selected which have important meanings in 1920s. The properties of spatial configuration were derived from an urban-context approach and without urban context analysis, and spatial connectivity and functional conformity were analyzed using references. The results of the study revealed that the arrangement of block housing were different from one another notwithstanding their similar layout characteristics. The relationships between urban streets and housing complexes were identified, and the public spaces were being arranged as semi-public spaces, whereas blocks as private spaces by separating functions. This study provides the implications for the planning of low rise-high density housings by means of analyzing the spatial connectivity of the spatial layout characteristics of European block housing, recognizing the relationships between urban communities and housing complexes.

• Journal of Electrochemical Science and Technology
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• v.15 no.3
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• pp.421-426
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• 2024

Ru dye (Z-907) is a crucial photosensitizing material in dye-sensitized solar cells (DSSCs). To enhance the utilization of Ru dye's photosensitizing properties in bulk heterojunction solar cells, a method was developed to synthesize phenyl-C61-butyric acid methyl ester (PCBM) nanoparticles that are chemically linked to Ru dye. PCBM contains a methoxy (-OCH₃) group, whereas Ru dye incorporates a carboxyl group (-COOH) within its molecular structure. By exploiting these complementary functional groups, a successful bond between Ru dye and PCBM was established through an anhydride functional group. The coupling of PCBM with Ru dye results in a modification of the energy levels, yielding lower LUMO (3.8 eV) and HOMO (6.1 eV) levels, compared with the LUMO (3.0 eV) and HOMO (5.2 eV) levels of Ru dye alone. This configuration potentially facilitates efficient electron transfer from Ru dye to PCBM, alongside promoting hole transfer from Ru dye to the conducting polymer. Consequently, the bulk heterojunction solar cells incorporating this Ru dye-PCBM configuration demonstrate superior performance, with an open circuit voltage (V_oc) of 0.62 V, short circuit current (J_sc) of 0.63 mA cm^-2, fill factor (FF) of 65.6%, and a photovoltaic conversion efficiency (η) of 0.25%.

• Bulletin of the Korean Chemical Society
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• v.32 no.4
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• pp.1231-1236
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• 2011

Chiral discrimination is the ability to distinguish one enantiomeric form over another. The differential binding interaction between two molecules with the same helicity and those with the opposite helicity was investigated by using dispersion-corrected density functional theory. [5]helicene, tetrahydro[5]helicene and the polar D-${\pi}$-A compounds, 3,12-dimethoxy-7,8-dicyano-[5]helicene and 3,12-dimethoxy-7,8-dicyano-tetrahydro[5]helicene were the monomers considered in this study. In gas phase, the dimeric interaction from two helical molecules with the opposite handedness is greater than from those with the same handedness. The stable configurations of such dimers were identified. The most stable configuration tends to be the one with maximum contact between monomers.

• Polymer(Korea)
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• v.34 no.1
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• pp.69-73
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• 2010

Effects of reaction time and temperature on the isomerization and dehydrobromination reactions of brominated butyl rubber were investigated. The structural composition of brominated butyl rubber was determined by Fourier transform infrared spectroscopy (FT-IR) and proton nuclear magnetic resonance spectroscopy($^1H$-NMR), Density functional theory (DFT) was used to study on the isomerization and dehydrobromination mechanisms of model compounds. The geometries for model compounds of 3-bromo-5,5,7,7-tetramethyl-2(2',2',4',4'-tetramethyl)pentyl-1-octylene (3BrOE), 1-bromo-5,5,7,7-tetramethyl-2(2',2',4',4'-tetramethyl)pentyl-2-octylene (1Br2OE) and 5,5,7,7-tetramethyl-2(2',2', 4',4'-tetramethyl)pentyl-1,3-octadiene (CD) had been optimized by using density functional theory at B3LYP/3-21G and B3LYP/6-31G levels. The predicted energy of 3BrOE lies higher than that of 1Br2OE which suggests that 1Br2OE configuration is more stable than the 3BrOE configuration. Compared with the energy barrier, the pathway of dehydrobromination is less competitive than that of isomerization. This is qualitatively consistent with the experimental results.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.5
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• pp.2360-2367
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• 2012

Architecture is widely regarded as one of important fields representing their own culture. In most cities of our nation, there has been the tendencies of negligence in keeping its record properly to be used. So, the purpose of this study is to collect the basic informations and analyse them to develop the appropriate programs for us. This study aims to offer fundamental characteristics of functional configurations in architectural museums through comparative analysis between korean and foreign museums. In so doing, it deals with the relationship between identity of museum policy and its spatial program such as archiving center, exhibition center and communication-research center. For the prove of such relationship this study attempt to compare multiple cases such as MAXXI, Nai etc. Finally this study propose that, in considering the establishment of a new architectural museum, the space program should be considered as a continuous changing process in order to make the museum as a cultural multi-complex.

• International conference on construction engineering and project management
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• 2009.05a
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• pp.622-627
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• 2009

Business process engineering (BPE) is a top-down management approach for increasing efficiency and productivity through radical and fundamental changes to the business processes of the organization. BPE requires firms to initially develop a model of the existing business processes of the firm to distinguish functional tasks from processes used for coordinating inputs, activities and outputs. The model is used for understanding the business processes in the organization and to simulate the effect of changes to the processes. The model can also be used to justify business processes, which involves assessing whether the business process provides value to the customer in its current configuration. Justification requires a careful examination of the key business processes used by the firm to identify systemic shortcomings in the process and to create a new business process to produce greater efficiency. BPE also considers automating as many business processes as possible to increase operational efficiency and the integration of business process tasks. The construction industry has been slow to adopt BPE because of its project approach in which a major firm contracts with various functional service providers and regards each project as unique. The industry focuses on functional task efficiency rather than business process efficiency. There is no formal methodology or criteria for determining whether a business process is effective for a construction firm in its current configuration. The use of performance measures such as costs, task duration times or other metrics can be useful in evaluating the effectiveness of an existing business process and for modeling the possible outcome of a fundamental and radical change to the process.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.1D
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• pp.81-89
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• 2009

CM(Configuration Management) is a field of management that focuses on establishing and maintaining consistency of a product's performance and its functional and physical attributes with its requirements, design, and operational information throughout its life. Recently upcoming concept of CM, regardless of various definitions, consists of the organization and the process for value creation through project change management, value preservation by Risk, Project Management implementation by Change management. The CM provide a basis for, and a record of, the project's performance in meeting the scope, time, cost. Overseas international companies have already adopted the CM system and enjoyed the benefits arising from such systems. And the CM provides perspectives and insights applicable to all types of projects. This study presents the review on the current systems now in use at jobsites and known to be efficient, and the introduction and application of configuration systems now at big issue. Hereby indicates the connective system consisted of work process, change control and knowledge referring to the methods and actual cases as an effective promotion of CM.

• Korean Institute of Interior Design Journal
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• v.22 no.4
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• pp.149-157
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• 2013

As a period of pluralism, today's museum architecture has been expanding social and cultural meaning. So, Various expressions are appearing in museum architecture. Accordingly, the museum must be very reproducible and comply with aesthetic requirements. At the same time, museum construction in urban design and features must satisfy professional requirements. SANAA is one of contemporary architects has been decisively deleted existing fixed and functional layout type of program through 'The new hierarchy'. Thus, the experience of the space will vary. Now, museum space is urgently needed than ever before crustal movements. Thus, this study aims to contribute an alternative to the museum space configuration according to the trend of the times through 'The new hierarchy' of SANAA. This paper is limited to the cases of the SANAA's museum architecture. We analyze the characteristics of representation on 'The new hierarchy' appear in the museum space configuration and then, examine the value of the spatial. SANAA's 'New Hierarchy' is going to set the cognitive boundary by expression targeting plane and the surface. It is completely different than the previous boundaries. Characteristics of the expression represents non-centrality, decentrally, non-oriented, uncertainty, non-territorialization, uniformity. It is steady that identity of Space, Human, Environment in Museum. They have a relationship each concept of Independence, autonomy, equality.