• Title/Summary/Keyword: Fuel-N

Search Result 960, Processing Time 0.033 seconds

Development of an Integrity Evaluation System (WIES) for Fuel Channels in CANDU Reactors (중수로 연료관 건전성 평가시스템(WIES) 개발)

  • Choi, Sung-Nam;Kim, Hyung-Nam;Yoo, Hyun-Joo;Kwon, Dong-Kee;Hwang, Won-Gul
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.34 no.9
    • /
    • pp.1273-1279
    • /
    • 2010
  • Pressure tubes at the CANada Deuterium Uranium (CANDU) nuclear power plants are periodically inspected in accordance with the CSA N285.4 code. If flaws that do not satisfy the criteria given in CSA N285.4 are detected, the code permits a fitness-for-service assessment to determine the acceptability of the flawed pressure tubes. In this paper, the Wolsong In-service Evaluation System (WIES) is introduced; this system has been developed for the assessment of the flawed pressure tubes and is based on CSA N285.8. Since the system evaluates the integrity of flawed pressure tubes exactly and promptly during an in-service inspection, it will help in operating the Wolsong nuclear power plants without prolonging the outage period.

Radiation Shielding Analysis on The Spent Fuel Storage Facility for the Extended Fuel Cycle (장주기(長週期) 핵연료(核燃料) 저장시설(貯藏施設)에서의 방사선차폐해석(放射線遮蔽解析))

  • Lee, Tae-Young;Ha, Chung-Woo;Yook, Chong-Chul
    • Journal of Radiation Protection and Research
    • /
    • v.9 no.2
    • /
    • pp.90-96
    • /
    • 1984
  • Estimated dose rates in spent fuel pool storage with the extended fuel cycle core management were reviewed and compared with design limit after calculation with the aid of DLC-23/CASK(22 n, 18 g) nuclear data and ANISN code. Radioactivity and gamma spectrum within spent fuel assemblies were calculated with ORIGEN code by extended fuel cycle model. In the calculation of dose rate, the fuel pool geometry was assumed to be infinite slab. Also, composition materials and radiation source within assemblies which are being stored in pool storage were assumed to be uniformly distributed throughout all the assemblies. As a result of culculation of dose rate from stored assemblies and waterborne radionuclides in pool water, the calculated dose rates appear to be lower than design basis limit under normal condition as well as abnormal condition.

  • PDF

Electrochemical Characteristics of Electrode by Various Preparation Methods for Alkaline Membrane Fuel Cell (알칼리막 연료전지용 전극의 제조방법에 따른 전기화학적 특성 분석)

  • Yuk, Eunsung;Lee, Hyejin;Jung, Namgee;Shin, Dongwon;Bae, Byungchan
    • Journal of the Korean Electrochemical Society
    • /
    • v.24 no.4
    • /
    • pp.106-112
    • /
    • 2021
  • Catalyst poisoning by ionomers in membrane electrode assemblies of alkaline membrane fuel cells has been reported recently. We tried to improve the membrane electrode assembly's performance by controlling the solvent's ratio during electrode manufacturing. 4 Different mixing ratios of N-Methyl-2-pyrrolidone (NMP) and ethylene glycol (EG) gave four different cathode electrodes with platinum and Fuma-Tech ionomers. The electrode with higher EG improved polarization performance by about 36% compared to the NMP-based commercial ionomer. The dependence of the ionomer's dispersibility on the solvent seems responsible for the difference, which means that the non-uniform distribution of ionomers improves the performance of the electrode. High-frequency resistance, internal resistance corrected polarization curve, Tafel slope, mass activity, and impedance spectroscopy characterized the electrode. We can find that the existence of poor solvent improves cathode electrode performance. It seems to be the result of reduced poisoning of the catalyst according to the particle size distribution of the ionomer.

Pt Doping Mechanism of Vanadium Oxide Cathode Film Grown on ITO Glass for Thin Film Battery

  • Kim, Han-Ki;Seong, Tae-Yeon;Jeon, Eun-Jeong;Cho, Won-Il;Yoon, Young-Soo
    • Journal of the Korean Ceramic Society
    • /
    • v.38 no.1
    • /
    • pp.100-105
    • /
    • 2001
  • An all solid-state thin film battery (TFB) was fabricated by growing, undoped and Pt-doped vanadium oxide cathode film ( $V_2$ $O_{5}$ ) on I $n_2$ $O_3$: Sn coated glass, respectively. Room temperature charge-discharge measurements based on Li/Lipon/ $V_2$ $O_{5}$ full-cell structure with a constant current clearly shows that the Pt-doped $V_2$ $O_{5}$ cathode film is superior, in terms of cyclibility. X-ray diffraction (XRD) results indicate that the Pt doping process induces a more random amorphous structure than an undoped $V_2$ $O_{5}$ film. In addition to its modified structure, the Pt-doped $V_2$ $O_{5}$ film has a smoother surface than the undoped sample. Compared to an undoped $V_2$ $O_{5}$ film, the Pt doped $V_2$ $O_{5}$ cathode film has a higher electron conductivity. We hypothesize that the addition of Pt alters electrochemical performance in a manner of making more random amorphous structure and gives an excess electron by replacing the $V^{+5}$. Possible mechanisms are discussed for the observed Pt doping effect on structural and electrochemical properties of vanadium oxide cathode films, which are grown on I $n_2$ $O_3$: Sn coated glass.

  • PDF

Application of CV Cycling to the Activation of the Polymer Electrolyte Membrane Fuel Cell (고분자 전해질막 연료전지의 활성화를 위한 CV 활성화법)

  • Cho, Ki-Yun;Jung, Ho-Young
    • Applied Chemistry for Engineering
    • /
    • v.23 no.5
    • /
    • pp.445-449
    • /
    • 2012
  • The activation process of the membrane-electrode assembly (MEA) is important for the mass production of the polymer electrolyte membrane fuel cell. The conventional activation process for the MEA requires excessive time and hydrogen gas and it might become the barrier for the commercialization of the fuel cell. The conventional activation process is based on hydrolysis of ion conducting membrane. In the study, we suggest the cyclic voltammetry (CV) technique as an on-line activation process and the CV activation process consists of two steps : 1) the humidification of the polymer electrolyte membrane and the electrode with 100% RH humidified nitrogen ($N_{2}$) gas, and 2) the removal step of the oxide layer on the surface of the Pt catalyst with CV cycling. The cycling reduces the activation time of the MEA by 2.5 h and use of hydrogen gas by 1/4.

Endothermic Properties of Liquid Fuel Decomposition Catalyst Using Metal Foam Support (메탈폼 지지체를 이용한 액체연료 분해반응 촉매의 흡열특성)

  • Mun, Jeongin;Kim, Nari;Jeong, Byunghun;Jung, Jihoon
    • Korean Chemical Engineering Research
    • /
    • v.59 no.4
    • /
    • pp.481-486
    • /
    • 2021
  • In a hypersonic vehicle to solve the heat problem generated during flight, a cooling technology is being developed which uses the endothermic effect that appears during the decomposition reaction of the mounted fuel. In this study, the decomposition reaction of n-dodecane fuel was performed using HZSM-5 as a catalyst, and the catalyst was coated on metal foam to maximize the endothermic effect of the catalytic decomposition reaction and suppress coke formation. The reactor was a stainless steel flow reactor with a outer diameter of 1.27 cm, and the reaction temperature was 550 ℃, the reaction pressure was 4 MPa, and the flow rate was 12 ml per minute. As a result of the catalytic decomposition reaction using a catalyst coated with HZSM-5 on the metal foam, the heat sink was 2887 kJ/kg as a maximum, the gas phase conversion rate was 34%, and the amount of coke produced on the metal foam decreased by about 56% as the catalyst was coated compared to the uncoated catalyst.

Cubic Equation of State Analysis for the Prediction of Supercritical Thermodynamic Properties of Hydrocarbon Fuels with High Critical Compressibility Factor (고 임계 압축인자를 갖는 탄화수소 연료의 초임계 열역학적 물성 예측을 위한 상태방정식 분석)

  • Jae Seung Kim;Jiwan, Seo;Kyu Hong Kim
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.26 no.5
    • /
    • pp.24-34
    • /
    • 2022
  • In order to predict the cooling performance of a regenerative cooling channel using hydrocarbon fuel operating in the supercritical region, it is essential to predict the thermodynamic properties. In this study, a comparative analysis was performed on two-parameter equations of state (SRK(Soave-Redlich-Kwong), PR(Peng-Robinson) equations of state) and three-parameter equations of state (RK-PR equations of state) to appropriately predict density and specific heat according to the critical compressibility factor of polymer hydrocarbons. Representatively, n-dodecane fuel with low critical compressibility factor and JP-10 fuel with high critical compressibility factor were selected, and an appropriate equation of state was presented when predicting the thermodynamic properties of the two fuels. Finally, the prediction results of density and specific heat were compared and verified with NIST REFPROP data.

Fretting Characteristics of TiN Coated Zircaloy-4 Tube (TiN코팅한 지르칼로이-4튜브의 프레팅 특성)

  • 성지현;김태형;김석삼
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
    • /
    • 2000.06a
    • /
    • pp.269-275
    • /
    • 2000
  • The fretting wear characteristics of TiN coated Zircaloy-4 tube were investigated experimentally The fretting wear experiment was performed using TiN coated Zircaloy-4 tube as the fuel rod cladding material and uncoated Zircaloy-4 tube as one of grids. TiN coating is probably one of the most frequently and successfully used PVD coatings for the mitigation of fretting wear. In this study, TiN coating by PVD was employed for improvement of Zircaloy-4 tube fretting characteristics. The fretting tester was designed and manufactured for this experiment. TiN coated Zircaloy-4 tube was used as the moving specimen, uncoated ZircaBoy-4 tube as the stationary one. The number of cycles, slip amplitude and normal load were selected as main factors of fretting wear. The results of this research showed that the wear volume of TiN coated Zircaloy-4 tube increased as number of cycles, normal load and slip amplitude increase but the quantity of volume was lower than the case of uncoated Zircaloy-4 tube pairs.

  • PDF