• Transactions of the Korean hydrogen and new energy society
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• v.19 no.4
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• pp.313-321
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• 2008

Dynamics of the proton exchange membrane fuel cell is specially important when the system is frequently working on transient conditions. Even though the dynamics of proton exchange membrane fuel cell for residential power generation is less critical than that of PEMFC for transportation application, the system dynamics of PEMFC for RPG can be very important for daily start-up and stop. In particular, thermal management of the PEMFC for RPG is very important because the heat generation from electrochemical reaction is delivered to the home for hot water usages. Additionally, the thermal management is also very important for heat balance of the system and temperature control of the fuel cell. The objective of this study is to develop a dynamic system model for the study of PEMFC performance over various BOP options. Basic simulation results will be presented.

• Journal of Drive and Control
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• v.21 no.2
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• pp.1-7
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• 2024

This paper proposes a novel cooling system for hydrogen fuel cell cooling systems by integrating heat pump technology to enhance operational efficiency. The study analyzed the cooling efficiency of the fuel cell cooling system. With the increasing focus on eco-friendly vehicle technologies to address environmental concerns and global warming, the transportation sector, a major contributor to greenhouse gas emissions, needs technological enhancements for better efficiency. The proposed cooling system was modeled through 1-D simulations. The analysis results of parameters such as thermal balance, temperature, and pressure of each component confirmed the stable operation of the system. By examining variations in the cooling system's flow rate, compressor RPM, and the Coefficient of Performance (COP) based on different refrigerants, initial research was conducted to derive optimal operating conditions and parameter values.

• Journal of Electrochemical Science and Technology
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• v.11 no.2
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• pp.99-116
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• 2020

The article provides information on ceramic / nanostructured materials which are suitable for solid oxide fuel cells (SOFCs) working between 500 to 1000℃. However, low temperature solid oxide fuel cells LTSOFCs working at less than 600℃ are being developed now-a-days with suitable new materials and are globally explored as the "future energy conversion devices". The LTSOFCs device has emerged as a novel technology especially for stationary power generation, portable and transportation applications. Operating SOFC at low temperature (i.e. < 600℃) with higher efficiency is a bigger challenge for the scientific community since in low temperature regions, the efficiency might be less and the components might have exhibited lower catalytic activity which may result in poor cell performance. Employing new and novel nanoscale ceramic materials and composites may improve the SOFC performance at low temperature ranges is most focused now-a-days. This review article focuses on the overview of various ceramic and nanostructured materials and components applicable for SOFC devices reported by different researchers across the globe. More importance is given for the nanostructured materials and components developed for LTSOFC technology so far.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.8
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• pp.510-515
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• 2016

Single-chamber solid oxide fuel cells (SC-SOFCs) consist of only one gas chamber, in which both the anode and the cathode are exposed to the same fuel-oxidant mixture. Thus, this configuration shows good thermal and mechanical resistance and allows rapid start-up and -down. In this study, the unit cell consisting of $La_{0.8}Sr_{0.2}MnO_3$ (cathode) / $Zr_{0.84}Y_{0.16}O_{2-x}$ (electrolyte) / $Ni-Zr_{0.84}Y_{0.16}O_{2-x}$ (anode) was fabricated and its electrochemical property was investigated as a function of temperature and the volume ratio of fuel and oxidant for SC-SOFCs. Impedance spectra were also investigated in order to figure out the electrical characteristics of the cell. As a result, the cell performance was governed by the polarization resistances of the electrodes. The cell exhibited an acceptable cell-performance of $86mW/cm^2$ at $800^{\circ}C$ and stable performance for 3 hs under 0.7 V.

• New & Renewable Energy
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• v.3 no.1 s.9
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• pp.46-53
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• 2007

Direct Methanol Fuel Cell, DMFC is a potential power source for portable IT application. DMFC works at low temperature ($<100^{\circ}C$) without fuel processing. Methanol has high energy density, fuel economy, and easiness to handle. This paper focuses high efficient catalyst to increase utilization in the electrode, new membrane reducing methanol crossover, new material parts, and optimization of system integration. Lightweight and small-sized DMFC based on new materials, efficient stack, and improved system control will be applied to the 50W prototype system for the notebook computer.

• Transactions of the Korean hydrogen and new energy society
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• v.19 no.3
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• pp.209-216
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• 2008

In the present study, a mathematical model has been formulated for the performance of polymer electrolyte fuel cells. Modify the concentration polarization equation using concentration coefficient that represents the characteristics of bipolar plate reactant distribution. The model predictions have been compared with experimental results and good agreement has been demonstrated for the cell polarization curves. The effects of operating parameters on the performance of fuel cells have been studied. Increases of operation pressure reduce the effect of temperature on the performance.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.235-238
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• 2005

Sulfonated poly(ether sulfone) copolymers (PESs) were synthesized using hydroquinone 2-potassium sulfonate (HPS) with other monomers (bisphenol A and 4-fluorophenyl sulfone). PESs with different $mole\%$ of hydrophilic group were prepared by changing the mole ratio of HPS in the polymerization reaction. The chemical structure and the thermal stability of these polymers were characterized by using $^1H-NMR$, FT-IR and TGA techniques. The PES 60 membrane, which has $60 mole\%$ of HPS unit in the polymer backbone, has a proton conductivity of 0.091 S/cm and good insolubility in boiling water. The TGA showed that PES 60 was stable up to $272^{\circ}C$ with a char yield of about $29\%\;at\;900^{\circ}C\;under\;N_2$ atmosphere. To investigate the single cell performance, the catalyst coated PES 60 membrane was used and a single cell test was carried out using $H_2/O_2$ gases as fuel and oxidant at various temperatures. We observed that the cell performance was enhanced by increasing the cell temperature. A current density of $1400 mA/cm^2$ at 0.60 V was obtained at $70^{\circ}C$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.12
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• pp.1022-1030
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• 2009

Numerical analysis was carried out to investigate the effect of GDL (Gas diffusion layer) porosity on the performance of PEMFC (proton exchange membrane fuel cell). A complete three-dimensional model was chosen for single straight channel geometry including cooling channel. Main emphasis is placed on the heat and mass transfer through the GDL with different porosity. The present numerical results show that at high current densities, the cell voltage is influenced by the GDL porosity while the cell performance is nearly the same at low current densities. At high current densities, low value of GDL porosity results in decrease of the fuel cell performance since the diffusion of reactant gas through GDL becomes slow with decreasing porosity. On the other hand, for high GDL porosity, the effective thermal conductivity becomes low and the heat generated in the cell is not removed rapidly. This causes the temperature of fuel cell to increase and gives rise to dehydration of the membrane, and ultimately increase of the ohmic loss.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.743-748
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• 2022

The initial operation stability of hydrogen-fueled, solid oxide fuel cell with Ni thin-film anode fabricated by direct current sputtering was evaluated in terms of electrochemical properties such as peak power density, open circuit voltage, overpotential, and alternating current impedance at 500℃. Hydrogen and air were used as anode fuel and cathode fuel, respectively.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.8
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• pp.1040-1049
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• 2010

The strengthened regulations for atmospheric emissions from ships have caused a necessity of new, alternative power system in ships for the low pollutant emissions and the high energy efficiency. Recently, new kinds of propulsion power system such as fuel cell system, which use hydrogen as an energy source, have been sincerely considered. The purpose of this work is to predict the performance of methanol fueled SOFC/GT hybrid power system and to analyze the influence of operating temperature of stack, current density of stack, pressure ratio of turbine, temperature effectiveness of recuperator, turbine inlet temperature.