• 한국광물학회지
• /
• 제25권1호
• /
• pp.9-21
• /
• 2012

우리나라에는 약 6개소의 사문석광산이 존재하였으며, 그 중에 최근까지 채굴되었던 충남지역의 비봉광산에 대하여 구성광물의 산출상태, 특성 및 성인을 검토하였다. X-선회절분석, X-선형광분석, 주사현미분석, 전자현미분석, 적외선분광분석, 편광현미경관찰 등을 통하여 사문석의 광물학적 특성을 조사하였다. 비봉광산의 사문암체는 선캠브리아기의 변성퇴적암을 관입한 형태로 소규모로 분포하여 나타나며, 사문석, 포스터라이트, 휘석, 투각섬석, 자철석, 녹니석, 운모, 활석, 돌로마이트 등의 다양한 광물들이 산출되었다. 사문암체의 광물조합은 크게 A) 사문석-포스터라이트, B) 사문석, C) 사문석-녹니석(버미큘라이트), D) 사문석-투각섬석, E) 투각섬석-녹니석의 5가지로 구분되어 나타났다. 사문석광물은 리자르다이트와 안티고라이트가 주로 포함되며 크리소타일은 일부 부분적으로 포함되어 산출되는 것으로 나타났다. 사문암체의 구성광물과 그 산출상태로 보아 포스터라이트를 주성분으로 하는 초염기성암의 열수변질작용에 의해 사문석이 형성되었으며, 그후 2차적인 열수작용에 의해 녹니석과 투각섬석 등의 변질광물이 형성된 것으로 나타났다.

• 한국세라믹학회지
• /
• 제26권3호
• /
• pp.347-360
• /
• 1989

Spinel, mullite, forsterite and cordierite composition powders were synthesized from Mg(NO3)2.6H2O, Al(NO3)3.9H2O and SiCl4-ethanol solution by spray pyrolysis method and the sinterability of these powders were investigated. The bulk density of spinel and mullite specimens sintered at 1,$700^{\circ}C$ for 1hr was 3.56g/㎤(99.5% relative density) and 3.16g/㎤(99.7% relative density), respectively. (Green compacts were made from powders prepared at 1,00$0^{\circ}C$). The bulk density of forsterite and cordierite specimens sintered at 1,480 and 1,40$0^{\circ}C$ for 2hrs were 3.217 and 2.155g/㎤, respectively. (Green compacts were made from powders prepared at 1,00$0^{\circ}C$). The constituent compositions of spinel and mullite specimens sintered at 1,$700^{\circ}C$ for 1hr were 27.5wt% MgO and 70.5wt% Al2O3, respectively. Vickers microhardness and fracture toughness of spinel sintered at the above condition were 13.7GPa and 2.6MN.m3/2, respectively, and room temperature bending strength, 425MPa, was nearly maintained even at the elevated temperature. In the case ofmullite specimens, those values were 13.5GPa, 2.2MN/m3/2 and 430MPa, respectively.

• 한국세라믹학회지
• /
• 제40권4호
• /
• pp.350-353
• /
• 2003

Millimeter-wave dielectric ceramics have been used like applications for ultrahigh speed wireless LAN because it reduces the resources of electromagnetic wave, and Intelligent Transport System (ITS) because of straight propagation wave. For millimeterwave, the dielectric ceramics with high quality factor (Q$.$f), low dielectric constant($\varepsilon$), and nearly zero temperature coefficient of resonant frequency ($\tau$) are needed. No microwave dielectric ceramics with these three properties exist except Ba(Mg$\_$1/3/Ta/sub1/3/)O$_3$ (BMT), which has a little high s: In this paper, alumina (Al$_2$O$_3$) and fosterite (Mg$_2$SiO$_4$), candidates for millimeter-wave applications, were studied with an objective to get high q$.$f and nearly zero $\tau$$\_$f/ For alumina ceramics, q$.$f more than 680,000 GHz was obtained but it was difficult to obtain nearly zero Qf. On the other hand, for forsterite ceramics, q$.$f was achieved from 10,000 GHz of commercial for sterite to 240,000 GHz of highly purified MgO and SiO$_2$ raw materials, and $\tau$$\_$f/ was reduced a few by adding TiO$_2$ with high positive $\tau$$\_$f/.

• 보존과학회지
• /
• 제16권
• /
• pp.64-76
• /
• 2004

지사동 출토 슬래그에 대하여 화학적인 분석과 현미경 조직관찰에 의하여 금속학적인 조사연구를 수행하였다. 화학적인 분석은 ICP, XRD, SEM-EDS로 실행하였으며 슬래그 조직은 금속현미경 및 SEM으로 관찰하였다. 화학적 분석 결과, A 및 C 지구 슬래그의 전철량(Total Fe)은 $39\~45\%$ 로 고대 제철과정에서 발생했던 철분의 평균치에 해당하였다. 또한 CaO 성분은 $3\~8\%$로 많은 양은 아니지만 조재제로 Ca성분을 함유한 재료를 소량 사용한 것으로 사료되었다. A지구에서는 Ti성분이 미량 검출되었으며 C지구에선 Ti 성분과 V 성분이 다량 검출되었다. XRD 분석 결과 Fayalite, Wustite, Magnetite, Ilmenite, Pseudo - brookite, Ulvospinel, Forsterite, Fephroite, Olivine 같은 화합물이 검출되었다. 이는 금속현미경 및 SEM에 의한 관찰에서도 위와 같은 조직을 확인하였다. 따라서 A지구의 로에서는 주로 철광석을 이용한 제련작업을 하였고 C지구의 제철로에서는 철광석을 원료로 하는 제련작업과 사철을 원료로 하는 제련작업이 병행되었던 것으로 추정되었다.

• 한국재료학회지
• /
• 제33권8호
• /
• pp.337-343
• /
• 2023

3Y-TZP (3 mol% yttria-stabilized tetragonal zirconia polycrystals) ceramics have excellent mechanical properties including high fracture toughness, good abrasion resistance as well as chemical and biological stability. As a result, they are widely used in mechanical and medical components such as bearings, grinding balls, and hip implants. In addition, they provide excellent light transmittance, biocompatibility, and can match tooth color when used as a dental implant. Recently, given the materials' resemblance to human teeth, these ceramics have emerged as an alternative to titanium implants. Since the introduction of CAD/CAM in the manufacture of ceramic implants, they've been increasingly used for prosthetic restoration where aesthetics and strength are required. In this study, to improve the surface roughness of zirconia implants, we modified the 3Y-TZP surface with a biocomposite of hydroxyapatite and forsterite using room temperature spray coating methods, and investigated the mixed effect of the two powders on the evolution of surface microstructure, i.e., coating thickness and roughness, and biological interaction during the in vitro test in SBF solution. We compared improvement in bioactivity by observing dissolution and re-precipitation on the specimen surface. From the results of in vitro testing in SBF solution, we confirmed improvement in the bioactivity of the 3Y-TZP substrate after surface modification with a biocomposite of hydroxyapatite and forsterite. Surface dissolution of the coating layer and the precipitation of new hydroxyapatite particles was observed on the modified surface, indicating the improvement in bioactivity of the zirconia substrate.

• 자원환경지질
• /
• 제49권2호
• /
• pp.77-88
• /
• 2016

백석면[Chrysotile, $Mg_3Si_2O_5(OH)_4$]은 사문석군 광물에 속하는 1:1 층상규산염광물로 섬유상의 형태와 구조적 특성으로 인해 다양한 이용과 연구가 진행되었으나, 근래에는 1급 발암물질로 선정되면서 백석면의 분해에 따른 본질적인 무해화를 위한 연구의 관심도가 높아졌다. 따라서 이 연구는 열처리에 따른 백석면의 광물학적 특성 변화를 관찰하여 열분해에 따른 무해화 과정을 알아보고자 하였다. 실험은 캐나다 LAB Chrysotile 광상에서 산출되는 백석면을 이용하여 $600-1,300^{\circ}C$ 범위에서 2시간 동안 열처리를 하였으며, TG-DTA, XRD, FT-IR, SEM-EDS, TEM-EDS 분석을 통해 백석면의 결정구조, 형태 및 화학성분의 변화를 확인하여 광물학적 특성변화를 관찰하였다. 열분해 실험 결과, 섬유상의 hollow tube 구조를 가지는 백석면은 약 $600-650^{\circ}C$에서 흡열반응이 일어남에 따라 팔면체판(MgOH)에서 수산기(OH)가 제거되면서 백석면은 비정질 광물의 형태로 변화하였다(탈수화 1단계). 약 $820^{\circ}C$에서는 발열반응이 관찰되었으며 이는 Mg, Si, O의 재배열 결과 주상의 고토감람석(forsterite, $Mg_2SiO_4$)으로 상전이에 영향을 준 것으로 사료된다(탈수화 2단계). 또한 $800^{\circ}C$ 이상으로 열처리한 일부 시료에서 고토감람석 내 결정구조의 변화가 시작되었고, $1,000^{\circ}C$ 이상에서는 온도 상승에 따라 점진적인 재결정 작용 결과 3차원적으로 성장하여 구형광물로 형태 변화가 나타나며 완화휘석(enstatite, $MgSiO_3$)을 형성하였다. 따라서 이 연구는 다양한 분석법의 적용과 2시간 동안의 열처리를 통하여 백석면의 탈수화 반응에 따른 결정구조의 붕괴와 섬유상 형태의 변형을 확인하였으며, 백석면은 무해 광물인 고토감람석과 완화휘석으로 상전이 됨을 통해 백석면의 무해화 과정을 제시 할 수 있었다.

• 천문학회지
• /
• 제44권1호
• /
• pp.13-21
• /
• 2011

We model dust around Herbig Ae/Be stars using a radiative transfer model for multiple isothermal circumstellar dust shells to reproduce the multiple broad peaks in their spectral energy distributions (SEDs). Using the opacity functions for various types of dust grains at different temperatures, we calculate the radiative transfer model SEDs for multiple dust shells. For eight sample stars, we compare the model results with the observed SEDs including the Infrared Space Observatory (ISO) and AKARI data. We present model parameters for the best fit model SEDs that would be helpful to understand the overall structure of dust envelopes around Herbig Ae/Be stars. We find that at least four separate dust components are required to reproduce the observed SEDs. For all the sample stars, two innermost dust components (a hot component of 1000-1500 K and a warm component of 300-600 K) with amorphous silicate and carbon grains are needed. Crystalline dust grains (corundum, forsterite, olivine, and water ice) are needed for some objects. Some crystalline dust grains exist in cold regions as well as in hot inner shells.

• 자원환경지질
• /
• 제26권1호
• /
• pp.1-10
• /
• 1993

The Andong serpentinite body is distributed along the Andong fault, and shows an elliptical shape. The serpentinite is composed of serpentine minerals and other various minerals such as forsterite, pyroxene, talc, tremolite, chlorite, prehnite, calcite and dolomite. The serpentine minerals consist primarily of lizardite with minor chrysotile. Antigorite rarely occurs in some veins. The serpentinite is largely divided into two alteration zones by the occurrence and mineral assemblages. One of the alteration zones is composed of a large amount of serpentine minerals. The other is characterized by tremolite and chlorite. The alteration zone composed of tremolite and chlorite seems to have been formed by hydrothermal alteration after the formation of serpentinite. It is considered that the serpentinite have been formed by alteration of the ultramafic rock such as peridotite.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2007년도 제38회 하계학술대회
• /
• pp.1281-1282
• /
• 2007

Effect of tension coating on reducing iron losses of thin grain-oriented 3% Si-Fe steel sheets was investigated. Conventional grain-oriented electrical steel sheets have a forsterite coating layer and a tension coating layer in order to apply tensile stress to the rolling direction of the sheets. However the proposed coating method in this paper is to form only a tension coating layer on the both surfaces of the sheets. Iron losses with the tension coating were reduced by 8% under the condition of 1.7 T and 60 Hz. Consequently the proposed tension coating is applicable to $80{\mu}m$-thick 3% Si-Fe steel sheets.

• 자원환경지질
• /
• 제31권5호
• /
• pp.447-458
• /
• 1998

The spinel Ihelzolite of ultramafic xenoliths are found in the alkali basalt from eastern part of the Cheju island, Korea. The xenolith is are mainly composed of olivine, orthopyroxene, clinopyroxene and spinel. Based on the chemical compositions of the constituent minerals, the ultramafic xenolith belong to upper mantle peridotite. Each minerals have a protogranular texture. Olivine with kink band texture partly shows undulatory extinction. Some clinopyroxenes have spongy textured rims. Brown spinels occur in the interstices between olivine and pyroxene grains. Olivine is mostly forsterite $(Fo_{89-90})$. Orthopyroxene is enstatite $(Wo_{1.3}En_{88.4}Fs_{10.3})$ with 3.87~5.25 wt% $Al_{2}O_{3}$. Clinopyroxene is diopside $(Wo_{48.0}En_{46.2}Fs_{5.8})$ with 6.75~5.03 wt% $Al_{2}O_{3}$. Spinel has the Mg value of 75.9 and its Cr-number is 10.2. According to the PoT estimations for the mantle xenoliths, equilibrium temperatures of the xenoliths range from 1023 to $1038^{\circ}C$ and pressure is 18 kbar. Spinellhelzolite from this area, which is characterized by lower Cr-number (10.2) and homogeneous chemical compositions, supports that these ultramafic xenoliths are derived from the upper mantle.