• Title/Summary/Keyword: Formation Rate

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Evaluation of Bromate Formation Pathway by Ozonation in Domestic Raw Waters (국내 수계 원수에서 오존공정에 의한 브로메이트 생성 경로 평가)

  • Lee, Kyung-Hyuk;Lim, Jae-Lim;Park, Sang-Yeon;Kim, Seong-Su;Kang, Joon-Wun
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.6
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    • pp.905-910
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    • 2006
  • In order to evaluate the optimum operation condition of ozonation to minimize bromate formation, based on the NOM characteristics of raw waters, the pathway of bromate formation by ozonation in domestic raw waters was investigated. Considering the bromate formation reactions, the fractions of bromate formation from bromide by OH radical and molecular ozone were calculated with measured values of ozone decay rate ($k_c$) and Rct. The results showed that molecular ozone is more important role in the formation of bromate in domestic raw waters than OH radical. The ratio of bromide oxidation reaction by molecular ozone ranged 73~88%. Fractions of $HOBr/OBr^-$ reaction with both molecular ozone and OH radical were also determined. OH radical reaction with $HOBr/OBr^-$ was dominant. The differential equations based on the stoichiometry of bromate formation were established to predict the formation rate of bromate by ozonation. The results shows good correlation with experimental results.

Effect of sequence variations within DNA melting region on the rate of formation of open complexes at $\lambdaP_{R}$ promoter ($\lambdaP_{R}$ 프로모터 열린복합체 형성에 미치는 DNA melting 부위 염기서열의 영향)

  • 정현채;노정혜
    • Korean Journal of Microbiology
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    • v.28 no.1
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    • pp.19-26
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    • 1990
  • To examine the effects of sequence variations near the transcriptional start site on the rate of formation of the open complexes at bacteriophage $\lambda P_{R}$ promoter, two mutant promoters were created by site-specific mutagenesis using synthetic oligonucleotides. Mutant I coatains changes at positions -3 and -4 from TT to CC, thus having a 6-bp long G/C stretch between -10 region and transciptional start site (+1). Mutant II has changes at positions -5 and -6 from GG to AA, thereby having a 9-bp long A/T stretch between positions -11 and -3. Selective filter binding assays were performed to measure the rate of formation of the open complexes between the wild-type or two mutant $P_{R}$ promoters on 664 bp fragments and E. coli RNA polymerase at two temperatures. At 37.deg.C, the wild-type and two mutants showed similar rates for the formation of open complex. The second order rate constant $k_{a}$ and $\tau _{int}$, as determined from the .tau.-plot analysis, were $(6.0\pm0.4)\times10^{6}M^{-1}sec^{-1}$ and $11\pm5$sec, respectively. At 18.deg.C, however, the wild-type and two mutant promoters showed differences in the kinetic parameters. k for the wild-type promoter was (2.2$\pm$0.1)\times 10^{6}M^{-1}sec^{-1}$ and $\tau _{int}$ was 76$\pm$sec. Mutant I and II exhibited differences mainly in the rate of isomerization ($\tau_{int,I}=91\pm$10 sec, int,II=34$\pm$ sec), whereas the second order rate constant $k_{a}$ was similar to the wild type value. This result implies that at $18^{\circ}C$, the isomerization rate is determined by both protein conformational change and DNA melting, which are separable kinetically according to the 3-step mechanism of Roe et al.(1984,1985), and that the base changes affected mainly the rate of DNA melting as predicted.lting as predicted.

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Detailed Analysis of NO Formation Routes with Strain Rate in H2/Air Nonpremixed Flames (H2/Air 비예혼합화염의 화염신장율에 따른 NO 생성경로의 상세해석)

  • Kim, Jong-Hyun;Hwang, Cheol-Hong;Lee, Chang-Eon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.8
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    • pp.604-611
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    • 2008
  • Detailed analysis of NO formation routes and its contributions with strain rate in hydrogen/air flames were numerically investigated. LiG detailed reaction mechanism has been used for calculation, which is compared with experimental data in literature. It shows good agreement with experiment for both temperature and NO mole fraction. Three routes have been found important for NO formation in hydrogen flames. These are the Thermal route, NNH route and $N_2O$ route. Strain rate were varied to discuss the $EI_{NO}$ reduction trend in hydrogen nonpremixed flames, which are analyzed by each NO formation routes. As a result, as the strain rate increase, $EI_{NO}$ decrease sharply until strain rate $100s^{-1}$ and decrease slowly until strain rate $310s^{-1}$ again, after that $EI_{NO}$ keeps nearly constant. It can be identified that $EI_{NO}$ trend with the strain rate is well explained by a combination of variation of production rate of above Thermal, NNH and $N_2O$ route. Also result of Thermal-Mech. that includes only thermal NO reaction is compared with those of Full-Mech. As a result, It can be identified that there was difference between the two results of calculation. It is attributed to result that Thermal-mech did not consider contributions of NNH and $N_2O$ route. From these result, we can conclude that NOx emission characteristics of hydrogen nonpremixed flames should consider contributions of above three routes simultaneously.

A Characteristics of Thick and Hard Al-Cu Alloy by Overlaying Welding Process (오버레이 용접법에 의한 Al-Cu 합금 경화후막의 특성)

  • 박정식;양변모;박경재
    • Journal of Welding and Joining
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    • v.14 no.4
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    • pp.53-61
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    • 1996
  • It was attempted to improve the wear resistance of Al alloy under the load condition by making a formation of the thicker surface hardening alloy layers. The thicker surface hardening alloy layers were formed on 6061 Al alloys overlayed by MIG and TIG welding process with Cu powders feeding. The characteristics of hardening and wear resistance have been investigated in relation to the microstructures of alloyed layers, with a selection of optimum alloying conditions for formation of overlaying layer. The results obtained were summarized as follows With increasing feeding rate of Cu powders by MIG welding, the hardness and specific wear of the overlay weld alloys were increased. It is considered that these high hardness and specific wear of overlay weld alloys were due to the formation of Θ($Al_2Cu$) phases. With increasing feeding rate of Cu powders by TIG welding, the hardness and specific wear of the overlay weld alloys were increased in feeding rates 12 and 18g/min. However, the hardness and specific wear were decreased in the powder feeding rate 38g/min. It is considered that considered that decrease of hardness and specific wear in the powder feeding rate 38g/min due to formation of ${\gamma}$($Al_4Cu_9$) phases.

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[발표취소] Star formation in overdense region around z=1.44 radio galaxy 6CE 1100+3505

  • Shim, Hyunjin
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.49.1-49.1
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    • 2015
  • Star formation in galaxies that lie in dense environment tends to increase as the redshift of the cluster increases. At z~1.4, the situation turns to be complex; some clusters still harbor galaxies with vigorous star formation, and others are populated with relatively old, massive galaxies. We present the result from narrow-band photometric study of the fields around the radio galaxy 6CE 1100+3505 at z=1.44. Deep H- and H-narrow band data have been obtained using CFHT/WIRCAM which cover the corresponding wavelengths for redshifted $H{\alpha}$. While the number of IRAC 3.6, and $4.5{\mu}m$ selected sources show clear excess within the central ~1Mpc area from the radio galaxy, number of galaxies identified to show excess in H-narrow band is very small. We discuss the possible integrated star formation rate in this overdense structure, and the implication to the evolution of cosmic star formation rate as a function of environment.

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Star formation efficiency of galaxies in groups and clusters

  • Jung, Su-Jin;Shim, Hyunjin
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.55.2-55.2
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    • 2013
  • We examine the effect of environment on star formation activity of a sample of a galaxy group catalogue constructed from the Sloan Digital Sky Survey(SDSS DR8) given in Tempel et al.(2012). As an environmental parameter, we use the richness of the galaxy group. According to this parameter, we select 6846 galaxies in dense environment and 297335 galaxies in low environment. By comparing the two samples, we identify the different relationship between star formation rate and stellar mass. In order to compare galaxies in different environment, we fixed other parameters(color, apparent magnitude), which can affect star formation efficiency except for stellar mass. Also, based on HI mass from the ALFALFA survey, we study the environmental dependence of Kennicutt-Schmidt law which show the correlation between star formation rate and gas content.

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HOW MODEL VARIANCE IN HIGH-REDSHIFT STAR FORMATION SHAPES COSMIC REIONIZATION HISTORY (다양한 고적색편이 별탄생 모형에 따른 우주 재이온화 역사의 변이)

  • Ahn, Kyungjin
    • Publications of The Korean Astronomical Society
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    • v.34 no.3
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    • pp.67-79
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    • 2019
  • We present a semi-analytical method to calculate the global evolution of the ionized state of the intergalactic medium, on the basis of physically motivated star formation histories in the early universe. This method incorporates not only the conventional scenarios in which the star formation rate is proportional to the growth rate of the halo collapse fraction, but also the more sophisticated scenarios in which the star formation is self-regulated. We show that this variance in the star-formation model strongly impacts the resulting reionization history, which bears a prospect for observational discrimination of these models. We discuss how observations of the anisotropic polarization of the cosmic microwave background and the global 21cm signal from the high-redshift universe, most notably by Planck and EDGES, may probe the history of reionization.

Film Formation in $CO_2$ Corrosion with the Presence of Acetic: An Initial Study

  • Ismail, Mokhtar Che;Mohd, Muhammad Azmi;Turgoose, Stephen
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.22-26
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    • 2008
  • Formation of protective iron carbonate films in $CO_2$ corrosion can reduce corrosion rate substantially and the effects have been incorporated in various prediction models. The $CO_2$ corrosion with the presence of free acetic acid is known to increase corrosion rate below scaling temperature. The possible interaction between the formation of iron acetate and iron carbonate films can affect the protectiveness of the film. The study is done using 3% NaCl solution under stagnant $CO_2$ -saturated condition at the scaling temperatures at various pH values and HAC concentrations. The result show that the presence of HAc does not affect the formation of protective iron carbonate film but delays the attainment of protective iron carbonate due to a possibility of solubilising of ferrous ions and thinning of the films.

Temporal Variation of Air Temperature in Ice-Valley at Milyang in Association with Ice Formation

  • Lee, Soon-Hwan;Hwang, Soo-Jin
    • Journal of the Korean earth science society
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    • v.28 no.5
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    • pp.598-602
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    • 2007
  • A long-term in situ observation was carried out in the Ice-valley at Milyang in order to explain the factors and processes associated with the summertime ice formation. The variation of temperature inside Ice-valley in relation with ice formation in summer time was found to depend on precipitation rate in spring and cold air sinking in autumn and winter. The rate of temperature rising tends to correspond to sensible heat release depending on the precipitation amount at the freezing location. The reason of the cold air accumulation in a talus in the Ice-valley is the cold air sinking over the surface of talus due to the occurrence of outside clod air mass and the accumulated cold air from autumn to spring flow outside at the bottom of talus. The out-flowing cold air can result in the ice formation in the hot summer.

Protoplast Formation and Regeneration of Pediococcus pentosaceus and Leuconostoc mesenteroides Isolated from Kimchi (김치에서 분리한 Pediococcus pentosaceus와 Leuconostoc mesenteroides의 원형질체 형성 및 재생)

  • 김연희;박연희
    • Microbiology and Biotechnology Letters
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    • v.23 no.3
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    • pp.359-364
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    • 1995
  • Two lactic strains, Leuconostoc mesenteroides Lu5 and Pediococcus pentosaceus P1 isolated from Kimchi, were used to determine the optimum conditions for protoplast formation and regeneration. The maximum protoplast formation rate was obtained with both strains at early exponential growth phase and decreased rapidly during growth phase. For P. pentosaceus P1, 30 $\mu$g/ml of lysozyme treatment was sufficient to obtain over 90% of protoplast formation and 300 $\mu$g/ml for L. mesenteroides Lu5, showing great difference in sensitivity of these strains to lysozyme. For both strains, best results were obtained at pH 7, using 0.5 M sucrose as osmotic stabilizer. For regeneration of protoplast, the highest regeneration rate was obtained after 15 minutes of lysozyme treatment and declined drastically with prolonged digestion.

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