• Title/Summary/Keyword: Formaldehyde(HCHO)

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A Study of Improvement on Collaboration Treatment Method of Electroplating Wastewater (도금폐수의 공동처리를 위한 공정개선에 관한 연구)

  • 이내우;최재욱;안병환
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.93-101
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    • 1997
  • A modified procedure for electroplating wastewater treatment using formaldehyde and hydrogen peroxide can destroy free cyanide. The representative diagram which is quite sensitive on reaction temperature is showed for this kinds of treatment. Principally free cyanide and some kinds of cyanide complex should be treated first, and then toxic heavy metals can be removed because cyanide component will be inhibited to remove other pollutants, if it is not destroyed perfectly. Formaldehyde and hydrogen peroxide are added in controlled amounts to cyanide treatment tank. Reasonable amounts of these chemicals are (HCHO/CN)=0.9 and ($H_2O_2/CN$)=1.1 in molar ratios, it is also variable on reaction temperature. Of course, actual treatment processes depending on plating material and chemical are good applicable, also to systematize operation manual for treating electroplating wastewater process, further works are desirable.

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A Study on the Emission of Hazardous Volatile Compounds in Wood and Steel Furniture (목재 및 철재가구중의 유해물질 방출에 관한 연구)

  • Kim, Sun-Tae;Park, Kyung-Su;Kim, Byoung-Eog;Woo, Soon-Hyung
    • Analytical Science and Technology
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    • v.11 no.3
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    • pp.194-201
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    • 1998
  • The formaldehyde vapor produced from wood and steel furniture was absorbed in distilled water and derivatized with acetylacetone and determined by UV-visible spectrophotometry. Variation in HCHO emission with time was monitored at room temperature. The emission of volatile compounds from wood, wood-based and steel-based materials was investigated in a 50 mL glass vial. The concentration of the gases emitted in a glass vial was determined by ion-trap GC-MS.

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Radiolysis of Methanol and Methanolic Solutions by Co-60 Gamma-Rays (Co-60 갬마線에 의한 Methanol 및 Methanolic Solution 의 Radiolysis)

  • Choi, Sang-Up
    • Journal of the Korean Chemical Society
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    • v.6 no.1
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    • pp.73-77
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    • 1962
  • Yields of hydrogen, methane, carbon monoxide, formaldehyde and ethylene glycol by gamma-radiolysis of methanol have been determined at room temperature and compared with values reported in the literature. The G-values obtained by the present studies are as follows: $G(H_2)=4.98,\;G(CH_4)=0.28,\;G(CO)=0.09,\;G(HCHO)=2.14\;and\;G(C_2H_6O_2)=3.07.$ The effects of water, methyl borate and alkali halides added to methanol prior to radiolysis have also been investigated. It is observed that alkali iodides and bromides affect the G-values, particularly, of hydrogen, formaldehyde and/or ethylene glycol, whereas alkali chlorides and fluorides have less pronounced effects.

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Analysis of formaldehyde in chamber by GC/MS (GC/MS를 이용한 탈취시험용 chamber내의 HCHO 분석)

  • 허귀석;유연미;이진홍
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.346-347
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    • 2002
  • 악취는 인간의 생활환경에 불쾌감과 혐오감을 주는 감각공해로서 악취를 줄여 쾌적한 환경을 유지하고자하는 연구가 증가함에 따라 이에 관련된 탈취제품이 많이 상품화되고 있다. 그러나 탈취성능에 대한 체계적인 평가가 이루어지지 않아 탈취제품의 성능을 개관적으로 평가할 수 있는 시험분석법의 개발이 필요하다. 본 연구에서는 여러 악취물질 중 포름알데히드를 대상으로 탈취제품의 성능을 평가하기 위한 시험분석법을 개발하기 위하여 최적 측정조건을 확립하고자 하였다. (중략)

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The Study of Indoor Air Quality at Schools in Chung-Nam Area (충남 지역 학교의 실내공기질에 관한 연구)

  • Cho, Tae-Jin;Choi, Han-Seam;Jeon, Young-Taek;Lee, Che-Won;Lee, Jong-Dae;Jou, Hye-Mee;Son, Bu-Soon
    • Journal of Environmental Science International
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    • v.17 no.5
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    • pp.501-507
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    • 2008
  • The concentrations of HCHO(formaldehyde), $PM_{10}$(particulate matter), $CO_2$(carbon dioxide) and TBC(total bacteria counter) distribution in schools(Chung-Nam Area) were examined, and the results were compared with the recommended criterion of the administration law of indoor air. The subjects were an elementary school, a middle school and a high school in Chung-Nam area, and the concentration of TBC was examined by Single Stage Air Cascade Sampler, which applied the inertia collision catching method of 28.29L/min(flux) during 5 months from March, 2007 to July, 2007. The instrument(LD-3B, SIBATA Company)was used to examine $PM_{10}$, by a light scattering method and a light transmission method. The instrument(Airboxx(KD Engineering) was used to examine $CO_2$. The instrument(Z300XP(Environmental sensor)was used to examine HCHO. The result indicated that the $PM_{10}$ average concentrations of the surveyed classrooms were $49{\mu}g/m^3$ in Spring and $59{\mu}g/m^3$ in Summer. The $CO_2$ average concentration of the surveyed schools were 576 ppm in the classroom and 527 ppm in the stateroom. The average concentration of TBC were $729CFU/m^3$ in an elementary school, $401CFU/m^3$ in a middle school, $381CFU/m^3$ in a high school. The HCHO average concentration of the surveyed schools were 0.03 ppm in the classroom, 0.02 ppm in the stateroom.

The studies on wrinkle recovery improvement for silk fabrics (견직물의 방추성 개선연구)

  • 김병호;정진영
    • Journal of Sericultural and Entomological Science
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    • no.11
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    • pp.23-29
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    • 1970
  • This experiment is to improve the wrinkle recovery (W.R.) of silk fabrics. The silk fabrics is creased very well, and the crease is the serious defection of it. This experiment is to improve the nature by use of formaldehyde on fabrics. The reagents used were HCl, CH$_3$COOH, CaC$_2$, HCHO, Na$_2$CO$_3$, NH$_4$OH, NaOH and NaHCO$_3$. The silk fabrics was treated, to compare 1 he influence of conditions, by varying the quantities of reagents and the temperature of solution, and the reaction time. The cotton fabrics and the viscose rayon were sunk with the silk at the same condition to be compared the influence. 1) Those of the most suitable temperature to improve for the better W.R. are 75$^{\circ}C$ for silk, 35-45$^{\circ}C$ for cotton, and no particular temperature under 75$^{\circ}C$ for viscose rayon. 2) The W.R. improvements after treated at the temperature of 1) were 11% for silk and 33.4% for cotton. 3) There are the best treating time for every fabrics. They were 60 to 90 min. for viscose rayon when HAC Ras used for solvent. It took, however, 60min. of the best time for silk, 120 min. for cotton, and 40 min. for viscose rayon when acetic anhydride instead of HAC was used. 4) It was possible to improve 16.6% of W.R. for silk at the most suitable treating time, 25.0% for cotton, and 13.3% for viscose rayon. 5) Acetic anhydride was rather more effective to improve W.R. of both silk and viscose rayon than HAC. 6) Treating time was also shorter in case of using acetic anhydride than HAC. 7) The improvement of W.R. were 8.3% for silk at the 10 to 14 ml. of HCHO the best volume, 21. 5% for cotton at 18m!. of HCHO, and 70% of for viscose rayon at 14 to 18ml. of HCHO. 8) The most effective quantity of HCI is 14 ml. for both silk and cotton. The W.R. improvement of silk was 22.2%, and that of cotton 19.5%. 9) The W.R. of 83.3% the best for silk and 61. 6% for cotton were gained when 4.2gr. of NaHCO$_3$ brings down the percent of W.R. for both silk and cotton. 10) The more NaOH and NH$_4$OH as neutralizing agents, the less effectivity of W.R. until the quantities of the reagents are reached to a special range which are 3. 3m!. for silk and 3.3-6.6 ml. for cotton, and then we can see the W.R. increasing as the quantities of reagents are increased. These facts were evident in case of silk and cotton. We can also see with this fact that the reminder of 〔OH$\^$-/〕 neutralizing 〔CH$\^$+/〕in solution makes it possible to treat formaldehyde on fabrics. 11) Low curing temperature was comparatively better for silk, and high temperature better for cotton. 12) The result of this experiment shows that the Improvement of W.R. for silk was possible to 94% which means 22% W.R. increase compared to the untreated silk. This effect also shows that the improvement to W '||'&'||' W (wash and wear) of silk will be possible.

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Characteristics of pollutant emission from wallpapers - Around TVOC and HCHO - (벽지에서 발생되는 오염물질 방출특성 - TVOC와 HCHO를 중심으로 -)

  • Jang, Seong-Ki;Kim, Mi-Hyun;Lee, Hong-Suk;Lim, Jun-Ho;Jang, Mee;Seo, Soo-Yun
    • Analytical Science and Technology
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    • v.18 no.6
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    • pp.542-551
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    • 2005
  • This study is to investigate the characteristics of emission concentration according to wallpaper sort and emission time using small chamber method. The target compounds included 45 VOCs and formaldehyde, which were respectively determined by adsorption sampling and thermal desorption coupled with GC/MS method, and by sampling in DNPH cartridge and HPLC method. The emission factor of TVOC and HCHO was detected to $1.1mg/m^2{\cdot}h$ and $0.01mg/m^2{\cdot}h$ respectively, and the wallpapers of 25 satisfied emission standard. TVOC emission factor appeared in order of the concentration of PVC, natural, and Non-PVC wallpaper, while HCHO was detected very low concentration without relation to wallpaper sort. The paraffin hydrocarbons appeared to be the most contributable class of hydrocarbons in terms of their concentrations, followed by aromatics, and olefins, halogenated hydrocarbons was not detected. PVC wallpapers plentifully emitted TVOC above other wallpapers, and toluene was showed higher concentration of 10 times than natural wallpaper. In addition to, emission factor according to elapse was gradually decreased.

Enhanced HCHO Sensing Performance of NiO-decorated In2O3 Nanorods (NiO가 장식된 In2O3 Nanorods의 HCHO 감지 특성 향상)

  • Zion Park;Younghun Kim;Youjune Jang;Yujin Kim;Soohyun Han;Jae Han Chung;Young-Seok Sim
    • Journal of Sensor Science and Technology
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    • v.33 no.5
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    • pp.310-317
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    • 2024
  • Formaldehyde (HCHO) is a major primary indoor air pollutant with various adverse effects on the human body, includingsuch as sick building syndrome, lung cancer, and nasal cancer. Therefore, gas sensors for effective HCHO detection detecting HCHO are crucial for maintaining a healthy indoor environments, and research is being conducted to develop high-performance sensors for this purpose. AnOne of the effective methods for enhancing the to enhance sensing properties is involves modifying the p-n heterojunction structure, which improves sensing through via electronic sensitization based on the expanded depletion region and chemical sensitization that dissociates specific gases. In this studyHerein, weWe fabricated NiO-decorated In2O3 NRs using an e-beam evaporator based on the glancing angle deposition technique by optimizing the NiO thickness (0, 1, 2, and 3 nm). When exposed to 50 ppm HCHO, NiO-decorated In2O3 NRs showed a 3.91%-fold enhancement in the gas response (Ra/Rg-1= 23.9) and a 41.47% faster response time (40.7 s) than-compared to bare In2O3 NRs with an extremely low theoretical detection limit of ≈approximately 9.3 ppb.

A study on the characteristics and reduction of pollutant emission by finishing with natural materials for improving the IAQ (실내공기질 개선을 위한 자연소재마감재의 오염물질 방출특성 및 저감에 관한 연구)

  • Lee, Ji-Young;Park, Jin-Chul;Rhee, Eon-Ku
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.1174-1179
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    • 2006
  • This study aims to reduce the pollutant emission for improving the IAQ by finishing with natural materials. To investigate the concentration of pollutants such as Vocs, HCHO, both the chamber experiment and field measurement were conducted. The results of the study can be summarized as flows. (1) According to the chamber experiment of pollutant-emitting porwer of diatomite materials showed that VOCs and formaldehyde emission rates were lower and satisfied to the most on the HB Grade. (2) The field measurement of pollutant-emitting concentration of clay materials were lower 35% than other materials. (3) The Vocs and formaldehyde were most emitted from furnitures and the emission rate were found to be proportional to indoor air temperature. To control the emitted pollutants efficiently, the reasonable selection of finishing with natural materials are required.

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The Evaluation of Air Quality in Educational Child Care Centers (영유아 교육시설에서의 실내공기질 평가)

  • Lim, Ji-Hye;Pang, Seung-Ki;Shon, Jang-Yeul
    • The Journal of Sustainable Design and Educational Environment Research
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    • v.9 no.1
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    • pp.1-10
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    • 2010
  • It is indispensable for child care centers to investigate and manage indoor air quality (IAQ) because they perform education and day care for children who usually have weak immunity. Nevertheless, there is insufficient research being done, given its importance. This study aims to investigate indoor pollutants' concentration and to seek the causes in order to improve the air quality conditions. Also it aims to secure data which can be used for further researches. Measurements were performed for air temperature, relative humidity, carbon dioxide, carbon monoxide, fine particle mass, formaldehyde and volatile organic compounds. Temperature, humidity, CO and CO2 were measured 30times(1min/time) and PM10 was measured 10times (3min/time). Formaldehyde and volatile organic compounds were measured and analyzed based on The Indoor Air Quality Official Test Method. The results show that the temperatures were within the comfort zone in over half of the centers. CO2 was found to be the main pollutants as its concentration exceeded the IAQ standard. The concentrations of TVOC and PM10 exceeded the standard, by 32% and 24% respectively, whereas those of HCHO and CO were under the standard. HCHO and CO concentrations were under the guideline. 24% of child care centers for education were found to exceed the standard in 2 or more of the pollutants. 82% of were found to exceed the standard by 1 or more. Therefor it is requested for IAQ to manage and improve in child care center for education.