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A Study on the Formation Mechanism of the Fly Ash from Coal Particles in the Coal Burning Boiler (석탄연소 보일러에서 생성된 석탄회의 분석과 형성 메커니즘 해석에 대한 연구)

  • Lee, Jung Eun;Lee, Jae Keun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.12
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    • pp.1691-1701
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    • 1998
  • Fly ash produced in coal combustion is a fine-grained material consisting mostly of spherical, glassy, and porous particles. A study on the formation mechanism of the fly ash from coal particles in the pulverized coal power plant is investigated with a physical, morphological, and chemical characteristic analysis of fly ash collected from the Samchonpo power plant. This study may contribute to the data base of domestic fly ash, the improvement of combustion efficiency, fouling phenomena and ash collection in the electrostatic precipitator. The physical property of fly ash is determined using a particle counter for the measurement of ash size distribution. Morphological characteristic of fly ash is performed using a scanning electron micrograph. The chemical components of fly ash are determined using an inductively coupled plasma emission spectrometry(ICP). The distribution of fly ash size was bi-modal and ranged from 12 to $19{\mu}m$ in mass median diameter. Exposure conditions of flue gas temperature and duration within the combustion zone of the boiler played an important role on the morphological properties of the fly ash such as shape, particle size and chemical components. The evolution of ash formation during pulverized coal combustion has revealed three major mechanisms by large particle formation due to break-up process, gas to particle conversion and growth by coagulation and agglomeration.

Technique for Using Fly Ash as a Bedding Materials at Livestock House (석탄회의 축사 깔짚 이용기술)

  • 고영두;김재황;김두환;고병두;이수칠;이종찬;김삼철
    • Journal of Animal Environmental Science
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    • v.5 no.1
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    • pp.37-44
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    • 1999
  • This study was carried out to improve utilization of substitute fly-ash in bedding material of animal waste treatments. The amount used of fly-ash used in a pigpen or beef stall was 50% lower than that of existing bedding material of animal waste treatments. From the results, substitution effect of fly-ash put over the floor of the stable became much better. Effects of processed fly ash as a spread straw decreased ammonia(NH3) and Hydrogensulfide (H2S) gas at beef stall, but there was no benefit of replacement terms. Effect of processed fly ash as a spread straw increased 4∼5 times replacement terms more than control NH3 and H2S gas was decreased. A lot of maggots and porasites were grown at sawdust pig farm, but fly ash inhibited to grow maggots and paraeters. In conclusion, as substituting fly-ash for 5% sawdust(DM basis) in making animal waste into a compost with fly ash, we can reduce the sawdust purchasing costs and produce the high quality of a compost, especially a pollutant as NH3 and H2S gas, etc. from the process of biodegradation, and as substituting fly-ash(1,540 won per ton ; can be extended the replacement period of spreading straw approximatively 4∼5 times) for sawdusts(111,000 won per ton) will increase a real income in livestock house.

Removal of Unburned-Carbon from Fly-Ash of Bituminous Coal by Froth Flotation (포말부유선광법에 의한 유연탄 비산회의 미연탄소분 제거연구)

  • Son, Sung-Geun;Kim, Jung-Duk;Park, Byung-Wook
    • Resources Recycling
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    • v.5 no.3
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    • pp.44-49
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    • 1996
  • One of the most serious problems in utilizing the fly-ash produced from damcstic coal-firing power plants is lhc unburned-carbon mntained m the fly-ash In this shldy, the effects of fruther and collector an the yield,recuvery,unburnedcarbon rejectiou peiccntage,and process efficiency of product (cleaned fly-ash) wcrc examined when convzntional froth flotation was applied to rejcct the unburned-carbon included in the fly-ash of bituminous coal Alsa,the ash analysis for both thc raw and the clcaned fly-ash was conducted to review the change in thc major elements of fly-ash. Experimental results shawcd lhat tlle rcjectlon oI the unburned-cubon of thc raw fly-ash sample is available upto 92.4% using fiath flotalian and that the putity ol the pmdud(c1eancd fly-ash) attains up to 99.4%.

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Nitrogen Oxides Adsorbing Capacity of High Carbon Fly Ash Containing Cementitious Materials (탄소함량이 높은 플라이애쉬를 함유한 시멘트 페이스트의 질소산화물 흡착 성능)

  • Lee, Bo Yeon
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.3
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    • pp.37-42
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    • 2018
  • The use of fly ash in construction materials is increasing worldwide due the various advantages of using it, such as to produce durable concrete, or to use less cement and thus lower carbon dioxide emissions. The quality of fly ash is often determined by loss on ignition value (LOI), where an upper limit of LOI is set in each country for quality control purpose. However, due to many reasons, production of high LOI fly ash is increasing that cannot be utilized in concrete, ending up in landfill. In this study, the effect of fly ash use in cementitious materials on nitrogen oxides adsorption is examined. In particular, the effect of using high LOI, and thus high carbon content fly ash on nitrogen oxides adsorption is investigated. The results suggest that the higher carbon content fly ash is related to higher nitrogen dioxide adsorption, although normal fly ash was also more effective in nitrogen dioxide adsorption than ordinary portland cement. Also, higher replacement rate of up to 40% of fly ash is beneficial for nitrogen dioxide adsorption. These results demonstrate that high carbon fly ash can be used as construction materials in an environmentally friendly way where strength requirement is low and where nitrogen oxides emissions are high.

Prediction of Maximum Fly Ash Conveying Capacity of Fly Ash System in a Power Plant (발전 보일러용 비회 이송설비에서 최대 비회 이송량 예측)

  • Jin, Kyung-Yong;Moon, Yoon-Jae;Lee, Jae-Heon;Moon, Seung-Jae
    • Plant Journal
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    • v.11 no.1
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    • pp.50-57
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    • 2015
  • This study presents prediction of maximum fly ash conveying capacity of fly ash system in a power plant. The mixture ratio and pressure drop characteristics of air-fly ash flow in piping system are not well understood due to the complexity of particle motion mechanism. In this paper, the researcher investigated the optimum mixture ratio when the pressure drop of fly ash conveying system is equal to maximum static pressure of displacement fly ash transport blower and the capacity of fly ash transport according to the optimum mixture ratio by experimenting the fly ash conveying system of domestic D coal thermal power plants, which is currently in operation. The experiment results showed that the maximum fly ash conveying capacity of fly ash system were founded under the condition of maximum air volume 5,040 m3/h, static pressure of trip condition 1,163 mmH2O. In addition, it was predicted maximum mixture ratio of the air-fly ash was 8.66 and maximum capacity of fly ash conveying was 52,600 kg/h under these conditions.

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A Study on Properties of Domestic Fly Ash and Utilization as an Insulation material (국산 Fly Ash의 특성 및 단열재로의 이용에 관한 연구)

  • 박금철;임태영
    • Journal of the Korean Ceramic Society
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    • v.20 no.2
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    • pp.135-146
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    • 1983
  • This study is to investigate the properties of domestic fly ash for utilization as data in regard to fly ash which is by-product of domestic coal powder plants and the possibility of utilization as insulation material of domestic fly ash. Composition refractoriness size distribution density contents of hollow particles and crystalline phase were examined as the properties of domestic fly ash. As to the fired test pieces of fly ash by itself that varied contents of hollow particles with four kinds and of the fly ash-clay-saw dust system linear shrinkage bulk density app. porosity compressive strength thermal conductivity and structures were investigated for the possibility of utilization as an insulation material. The results are as follows : 1. The properties of the fly ash I) The constituent particle of the fly ash is spherical and it contains not a few hollow particles (floats by water 0.30-0.50 floats by $ZnCl_2$ aq.(SpG=1.71) 6.97-16.72%). ii) The chemical compositions of fly ash are $SiO_243.9-54.1%$ , $Al_2O_321.0-30.7%$ Ig loss is 7.4-24.1% and the principal of Ig loss is unburned carbon. iii) Fly ash was not suitable to use for mortar and concrete mixture because Ig. loss value is higher than 5% 2. Utilization as insulation material I) The test pieces of original fly ash floats by water floats by ZnCl2 aq(SpG=1.71) p, p t by ZnCl2 aq.(SpG=1.71) that were fired at 110$0^{\circ}C$ represented 0.11-0.18 kcal/mh$^{\circ}$ C as thermal conductivity value. ii) The test pieces which (76.5-85.5) wt% fly ash-(8.5, 9.5) wt% clay-(5.0-15.0) wt% saw dust system(68.0-72.0) wt% fly ash -(17.0-18.0)wt% clay-(10.0-15.0) wt% saw dust system and 59.5 wt% fly ash-25.5 wt% clay-15.0wt% saw dust system were fired at 110$0^{\circ}C$ the thermal conductivity was less than 0.1Kcal/mh$^{\circ}$ C. iii) In view of thermal conductivity and economic aspect insulation materials which added saw dust as blowing agent and clay as inorganic binder are better than that of fly ash as it is or separated hollow fly ash particles. iv) When the saw dust contents increased in the (59.5-90.0) wt% saw dust system and when amount of clay de-creased and firing temperature decreased under the condition of equal addition of saw dust app. porosity increased but bulk density compressive strength and thermal conductivity decreased.

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A Study on Development of Shotcrete Material using Fly Ash (Fly Ash을 이용한 Shotcrete 재료의 개발에 관한 연구)

  • 한오형;강추원
    • Explosives and Blasting
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    • v.21 no.2
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    • pp.21-30
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    • 2003
  • Currently, the shotcrete used as basic support in the tunnel excavation, has the advantages of maintaining high-level strength in condition of early shooting with thin thickness based on the excavation characteristics of rock mass. Therefore supreme equipment and materials were developed and the great strides have continued. Also, the development of measurement technology and the rocks behaviors of undergound are evaluated in detail and the designs of strength and thickness are made. The reinforcement materials development of new material is carried on. Most of the coal fly ash produced in Korea fire power plant is fly ash and bottom mash. Fly ash has been producing to be applied in many fields such as cement, aggregate, construction, civil, agriculture and fisheries. Also a lot of experiments are actively on the way. Therefore in this experiment, in order to use the fly ash mixed with concrete as a material of shotcrete, the experiment was performed in the best content to reduce the compression strength and the shooting rebound ratio of the excavated surface to use fly ash as a substitute material of concrete. As a result, when 15%.wt substitution was made to the fly ash, about 10% of compression strength and 6% of rebound ratio was reduced.

A Study on Physical Properties of Mortar Mixed with Fly-ash as Functions of Mill Types and Milling Times

  • Seo, Sung Kwan;Chu, Yong Sik;Shim, Kwang Bo;Jeong, Jae Hyun
    • Journal of the Korean Ceramic Society
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    • v.53 no.4
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    • pp.435-443
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    • 2016
  • Coal ash, a material generated from coal-fired power plants, can be classified as fly ash and bottom ash. The amount of domestic fly ash generation is almost 6.84 million tons per year, while the amount of bottom ash generation is 1.51 million tons. The fly ash is commonly used as a concrete admixture and a subsidiary raw material in cement fabrication process. And some amount of bottom ash is used as a material for embankment and block. However, the recyclable amount of the ash is limited since it could cause deterioration of physical properties. In Korea, the ashes are simply mixed and used as a replacement material for cement. In this study, an attempt was made to mechanically activate the ash by grinding process in order to increase recycling rates of the fly ash. Activated fly ash was prepared by controlling the mill types and the milling times and characteristics of the mortar containing the activated fly ash was analyzed. When the ash was ground by using a vibratory mill, physical properties of the mortar mixed with such fly ash were higher than the mortar mixed with fly ash ground by a planetary mill.

AN EXPERIMENTAL STUDY ON THE PROPERTIES & APPLICATION FOR FLY ASH OF CONBINED HEAT POWER PLANT - FOCUSSED HIGH STRENGTH CONCRETE - (열병합발전소 플라이애쉬의 특성 및 활용방안에 관한 실험적 연구 -고강도 콘크리트를 중심으로-)

  • 권영호;백명종;이보근;박칠림
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.211-216
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    • 1994
  • This study dealt with the properties for fly ash of conbined heat power plant and application for concrete industry. For this purpose, fly ash sampled Ulsan conbined heat power plant and analyzed for physical and chemical properties. As analyzed results of fly ash, contents of $SiO_ and Al_O_ $in the fly ash of Ulsan were less than those of Thermo-electric power plant(Boryuing), but contents of CaO were tem times as much as those of Boryung, because of these differences, it is expected that pozzolanic activity of concrete using fly ash of Ulsan will be different from another fly ash. Concrete specimens were tested to evaluate concrete preformance when 10 to 50 percent of the portland cement by weight in the concrete mix was replaced with fly ash of conbined heat power plant. As test results, workability and consideration in the fresh concrete were increased and concrete strength was showed more than 400kg/$\textrm{cm}^2$ for the required age. This study would be provided valuable data for the practical utilization of fly ash(conbined heat power plant). In the future, properties of fly ash concrete including long term strength, elapsed time, pozzolanic activity, modulus of elasticity, sulfate resistance, shrinkage, freeze-thaw durability and so on will be studied.

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Electrostatic Beneficiation of Coal Fly Ash Utilizing Triboelectric Charging with Subsequent Electrostatic Separation

  • Lee, Jae-Keun;Kim, Seong-Chan
    • Journal of Mechanical Science and Technology
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    • v.15 no.6
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    • pp.804-812
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    • 2001
  • A triboelectrostatic separation system for removing unburned carbon from coal fly ash is designed and evaluated. Fly ash from a coal-fired power plant is used as an accepted additive in concrete where it adds strength, sulfate resistance and reduced cost, provided acceptable levels of unburned carbon are maintained. Unfortunately, unburned carbon in coal fly ash absorbs some of other additives and reduces the concrete strength. This paper describes to investigate dry triboelectrostatic process to separate unburned carbon from coal fly ash and utilize it into economically valuable products. The laboratory-scale triboelectrostatic separation system consists of a particle feeding system, a tribocharger, a separation chamber, and collection systems. Particles of unburned carbon and fly ash can be imparted positive and negative surface charges, respectively, with a copper tribocharger due to differences in the work function values of the particles and the tribocharger, and can be separated by passing them through an external electric field. Results showed that fly ash recovery was strongly dependent on the electric field strength and the particle size. 70wt% of fly ash containing 6.5wt% of carbon contents could be recovered at carbon contents below 3%. The triboelectrostatic separation system showed a potential to be an effective method for removing unburned carbon from coal fly ash.

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