• Corrosion Science and Technology
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• 제23권3호
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• pp.246-254
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• 2024

Recently, coal-fired power plants are experiencing many problems that they have never experienced before due to an increase in flexible operation. In particular, a two-phase flow accelerated corrosion on water wall tubes in a boiler has not been detected overseas or domestically. There is no response plan to deal with such corrosion problem either. However, oxide film damage and tube material corrosion due to a two-phase flow accelerated corrosion are being discovered on water wall boiler tubes of domestic coal-fired power plants recently. If this situation is severe, it can cause enormous damage such as tube rupture. Therefore, in this paper, in order to prepare a response plan for a two-phase flow accelerated corrosion on water wall tubes in the future, differences between a two-phase flow accelerated corrosion and a single-phase flow accelerated corrosion were investigated and an example of discovery of a two-phase flow accelerated corrosion on water wall tubes was presented.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.2483-2488
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• 2008

To mitigate the effects of cavitation and flashing, several types of orifices have been installed in the pipeline of new nuclear power plants. To review the effects of wall thinning caused by flow-accelerated corrosion by the types of orifices, which are cone and plate, and the relation between flow behavior and local wall thinning, experiments and numerical analyses for the downstream pipe of two types of orifices were performed. The experimental results in terms of static pressure obtained for the experimental facilities were compared with those of three-dimensional (3D) numerical analyses using the FLUENT code. As the results of review of flow-accelerated corrosion effects based on the experiment and numerical analysis, it was identified that the orifice of cone-type can be comparatively mitigated the effects of cavitation and flashing, but can not be mitigated the effect of flow-accelerated corrosion.

• Corrosion Science and Technology
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• 제2권1호
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• pp.41-46
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• 2003

Flow-Accelerated Corrosion behavior concerning both activation and mass transfer process of SA106 Gr.C steel was studied using rotating cylinder electrode in room temperature alkaline solution by DC and AC electrochemical techniques. Passive film was tanned from pH 9.8 by step oxidation of ferrous product into hydroxyl compound. Corrosion potential shifted slightly upward with rotating velocity through the diffusion of cathodic species. Corrosion current density increased with rotating velocity in pH 6.98, while it soon saturated from 1000 rpm at above pH 9.8. On the other hand the limiting current increased with rotating speed regardless of pH values. It seems that activation process, which represents formation of passive film on the bare metal surface, controls the entire corrosion kinetics

• Nuclear Engineering and Technology
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• 제32권6호
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• pp.595-604
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• 2000

Flow-Accelerated Corrosion Behavior of SA106 Gr.C steel in room temperature alkaline solution simulating the CANDU primary water condition was studied using Rotating Cylinder Electrode. Systems of RCE were set up and electrochemical parameters were applied at various rotating speeds. Corrosion current density decreased up to pH 10.4 then it increased rapidly at higher pH. This is due to the increasing tendency of cathodic and anodic exchange half-cell current. Corrosion potential shifted slightly upward with rotating velocity. Passive film was formed from pH 9.8 by the mechanism of step oxidation and the subsequent precipitation of ferrous species into hydroxyl compound. Above pH 10.4, the film formation process was active and the film became stable. Corrosion current density showed increment in pH 6.98 with the rotating velocity, while it soon saturated from 1000 rpm above pH 9.8. This seems that activation process which represents formation of passive film on the bare metal surface controls the entire corrosion process

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2003년도 추계학술발표대회 요약집
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• pp.81.1-81.1
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• 2003

• Corrosion Science and Technology
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• 제15권1호
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• pp.6-12
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• 2016

Flow-Accelerated Corrosion (FAC) is a well-known degradation mechanism that attacks the secondary piping in nuclear power plants. Since the Surry Unit 2 event in 1986, most nuclear power plants have implemented management programs to deal with damages in carbon and low-alloy steel piping. Despite the utmost efforts, damage induced by FAC still occurs in power plants around the world. In order to predict FAC wear, some computer programs were developed such as CHECWORKS, CICERO, and COMSY. Various data need to be input to these programs; the chemical composition of secondary piping, flow operating conditions and piping geometries. CHECWORKS, developed by the Electric Power Research Institute (EPRI), uses a geometry code to calculate geometry effects. Such a relatively simple geometry code is limited in acquiring the accuracy of FAC prediction. Recently, EPRI revisited the geometry code with the intention of updating it. In this study, numerical simulations were performed for two adjacent $90^{\circ}$ elbows and the results were analysed in terms of the proximity effect between the two adjacent elbows.

• Journal of Welding and Joining
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• 제19권3호
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• pp.334-341
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• 2001

The chemical and geometric effects of weld on flow-accelerated corrosion (FAC) of SA106 Gr.C low alloy steel pipe in 3.5wt% NaCl and simulated feedwater of nuclear power plant have been investigated by using rotating cylinder electrode. Polarization test and weight loss test were conducted and compared at rotating speed of 2000rpm (3.14m/s) with the variables of chemical and geometric parameters. The results showed that the chemical effects were relatively larger than the geometric effects, and the welded parts were the local anode and preferentially corroded, which could be explained by the differences between microstructural and compositional parameters. On the other hand, under active corrosion conditions, the heat affected zone were severely corroded and microstructural effects became the important role in the whole process.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집A
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• pp.900-907
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• 2000

The three-dimensional turbulent flow in curved pipes susceptible to flow-accelerated corrosion has been analyzed numerically to predict the pressure and shear stress distributions on the inner surface of the pipes. The analysis employs the body-fitted non-orthogonal curvilinear coordinate system and a standard $ {\kappa}-{\varepsilon}$ turbulence model with wall function method. The finite volume method is used to discretize the governing equations. The convection term is approximated by a high-resolution and bounded discretization scheme. The cell-centered, non-staggered grid arrangement is adopted and the resulting checkerboard pressure oscillation is prevented by the application of a modified version of momentum interpolation scheme. The SIMPLE algorithm is employed for the pressure and velocity coupling. The numerical calculations have been performed for two curved pipes with different bend angles and curvature radii, and discussions have been made on the distributions of the primary and secondary flow velocities, pressure and shear stress on the inner surface of the pipe to examine applicability of the present analysis method. As the result it is seen that the method is effective to predict the susceptible systems or their local areas where the fluid velocity or local turbulence is so high that the structural integrity can be threatened by wall thinning degradation due to flow-accelerated corrosion.

• Corrosion Science and Technology
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• 제7권1호
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• pp.61-67
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• 2008

In this paper, electrochemical and microstructural characteristics of nickel-plated Alloy 600 were investigated in order to identify the performance of electroless Ni-plating on Alloy 600 in high-temperature aqueous condition with the comparison of electrolytic nickel-plating. For high temperature corrosion test of nickel-plated Alloy 600, specimens were exposed for 770 hours to typical PWR primary water condition. During the test, open circuit potentials (OCP's) of all specimens were measured using a reference electrode. Also, resistance to flow accelerated corrosion (FAC) test was examined in order to check the durability of plated layers in high-velocity flow environment at high temperature. After exposures to high flow rate aqueous condition, the integrity of surfaces was confirmed by using both scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). For the field application, a remote process for electroless nickel-plating was demonstrated using a plate specimen with narrow gap on a laboratory scale. Finally, a practical seal design was suggested for more convenient application.

• Corrosion Science and Technology
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• 제10권5호
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• pp.175-179
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• 2011

The transportation and deposition of iron corrosion products are important elements that affect both the steam generator (SG) integrity and secondary system in pressurized water reactor (PWR) nuclear power plants. Most of iron corrosion products are generated on carbon steel materials due to flow accelerated corrosion (FAC). The several parameters like water chemistry, temperature, hydrodynamic, and steel composition affect FAC. It is well established that the at-temperature pH of the deaerated water system has a first order effect on the FAC rate of carbon steels through nuclear industry researches. In order to reduce transportation and deposition of iron corrosion products, increasing pH(t) tests were applied on secondary system of A, B units. Increasing pH(t) successfully reduced flow accelerated corrosion. The effect of increasing pH(t) to inhibit FAC was identified through the experiment and pH(t) evaluation in this paper.