• Textile Coloration and Finishing
• /
• v.6 no.2
• /
• pp.55-62
• /
• 1994

The mend for fabric products has been increased remarkably with increasing population, housings, mutistory buildings,...and etc. during the last two decades. However, since fabrics are highly combustible and can produce toxic gases during the combution, fabric products can result in serious human injury as well as financial damage. Acknowledged by this, a new phosphorus based flame retardant suitable for PET fabric has been synthesized by making use of the reaction of diphenyl chloro phosphate and hexamethylenediamine. Since the starting meterials are relatively cheap and the yield of this reaction is high (more than 90%), this reaction seems to be very effective as wall as very economic. By analyzing various spectrophotometric analysis data such as NMR, FT-IR, and Mass, this new flame retardant is identified to be N,N’-Bis(diphenyl chlorophosphoro)diamino hexane. In the mean time, DSC measurement has shown that the melting point and the boiling point of this material are around 115$^{\circ}C$ and around 40$0^{\circ}C$, respectively. The flame retardancy test done on the PET fabric processed by this flame retardant have shown excellent in times of flame contact, times of flame contact for washable. The most economical finishing condition estimated 10% in concentration of BDPDH, Moreover, it has been also found that the drape stiffness of the PET fiber processed by the flame retartant is changed very litter compared to the unprocessed original PET fabrics. Judging from this, the potential of this new phosphrdus based compond as a flame retardant for PET fabric seems to be high.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• v.8 no.10
• /
• pp.3475-3489
• /
• 2014

Here we present a simple flame detection method for an infrared (IR) thermal camera based real-time fire surveillance digital signal processor (DSP) system. Infrared thermal cameras are especially advantageous for unattended fire surveillance. All-weather monitoring is possible, regardless of illumination and climate conditions, and the data quantity to be processed is one-third that of color videos. Conventional IR camera-based fire detection methods used mainly pixel-based temporal correlation functions. In the temporal correlation function-based methods, temporal changes in pixel intensity generated by the irregular motion and spreading of the flame pixels are measured using correlation functions. The correlation values of non-flame regions are uniform, but the flame regions have irregular temporal correlation values. To satisfy the requirement of early detection, all fire detection techniques should be practically applied within a very short period of time. The conventional pixel-based correlation function is computationally intensive. In this paper, we propose an IR camera-based simple flame detection algorithm optimized with a compact embedded DSP system to achieve early detection. To reduce the computational load, block-based calculations are used to select the candidate flame region and measure the temporal motion of flames. These functions are used together to obtain the early flame detection algorithm. The proposed simple algorithm was tested to verify the required function and performance in real-time using IR test videos and a real-time DSP system. The findings indicated that the system detected the flames within 5 to 20 seconds, and had a correct flame detection ratio of 100% with an acceptable false detection ratio in video sequence level.

• Applied Chemistry for Engineering
• /
• v.27 no.6
• /
• pp.577-582
• /
• 2016

In this study, we compared and analyzed the flame retardancy and mechanical properties of three different rigid polyurethane foams (RPUF) containing noble non-halogen phosphorus flame retardant (BHP-RPUF) or halogen-phosphorus flame retardant (TCPP-RPUF) or no flame retardant material (Pure-RPUF). The noble phosphorus-based flame retardant, bis(3-(3-hydroxypropoxy)propyl) phenyl phosphate (BHP), was synthesized by the reaction between disodium phenyl phosphate and 3-chloro-1-propanol. Through universal testing machine (UTM) experiments, the compressive strength of BHP-RPUF was similar to that of TCPP-RPUF. From the result of foam morphology analysis, it was confirmed that BHP-RPUF has the lowest thermal conductivity of $0.023W/m{\cdot}K$. We also measured the size of air bubbles using reaction velocity and SEM, and analyzed how they affect the thermal conductivity. In addition, the heat-resisting property was investigated through TGA analysis. The limited oxygen index (LOI) test confirmed that BHP had the ability to increase the flame retardancy of RPUF.

• Fire Science and Engineering
• /
• v.34 no.4
• /
• pp.101-106
• /
• 2020

This study analyzed flame growth characteristics and carbonization patterns when floor materials were burned vertically using a needle flame produced for this study. It was found that PVC flooring was fire retardant and the area under direct flame contracted inward. Vertical combustion causes solidification in the form of a lump at the bottom and also generates soot in a pattern that progresses upwards. This study found that laminated flooring exhibited no fire retarding characteristics and that the laminated layer of its upper surface was destroyed by fire, causing irregular delamination. The carbonization ranges at the left and right sides were determined to be symmetrical. A vertical combustion test of a sample carpet showed that it exhibited no fire-retarding characteristics. It was observed that if heat accumulated in the carpet, the flame formed an ascending air current, and that when flammable materials were present around the flame, they further accelerated the diffusion of the flame. The carbonization pattern at the carpet surface exposed to direct flame revealed that the carpet surface had melted and had flown downwards and that many tiny holes formed on it.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.21 no.2
• /
• pp.73-78
• /
• 2022

The test apparatus that can be protected from the high-temperature combustion flame and coolant injection was successfully manufactured. In this study, the coolant-injection module had a controllable consistent pressure, and the entire combustion module was protected using a nonflammable composite liner. Every flange was designed in accordance with the DIN standard, and the entire body of the module was designed in accordance with the EN 13445 code. Additionally, the hydraulic pressure test was performed in accordance with the 2014/68/EU directive and EN 13445 standard. Finally, after manufacturing, performance tests (such as pressure tests) were conducted to verify the reliability and safety.

• Fire Science and Engineering
• /
• v.24 no.4
• /
• pp.12-17
• /
• 2010

The purpose of this study is to determine how effectively waste tire recycled material mixed with flame retardant work in combating fire. As discovered in the previous study, waste tire mixed with cement mortar has more insulation capacity. However, this mortar is weak against fire. Therefore flame retardant, with a specific proportional mix, will be added to increase its fire prevention capacity. Tests will be made in accordance with ISO 5657 procedures for measuring fire ignition time, flame and shape variation of test pieces at the Building Material Test Institute. The test piece will be set up with horizontal levels having a constant radiation heat of $1{\sim}5W/cm^2$. Temperature transfers and increases from the surface into the interior. Combustible gases result due to pyrolysis, and regular contact is maintained between the fire source and the center of the test piece for assessment purposes. Ignition has not been occurred without adding retardant meaning that there is almost no possibility of ignition of waste tire particle. This fact can be considered as fire load to appreciate a volume of combustion materials. Flame is not occurred due to heat-absorbing effect by adding non-organic series retardant into waste tire particle. Conclusions have been summarized as follows; 1) Combustion of building material can be decreased by adding retardant to waste tire-mixing mortar. But compressive strength and insulation capacity of the material should be measured later. 2) Firing prevention and ignition are main points of building fire. Reasonable fire engineering assessment of interior material should be made for establishing effective disaster prevention system.

• 한국연소학회:학술대회논문집
• /
• 2014.11a
• /
• pp.339-342
• /
• 2014

Rotary kiln produces lime from limestone through thermal decomposition. Ring formation in kiln internal wall is known issue that decreases productivity. The cause of ring formation is temperature imbalance as flame leans toward upper wall. Therefore, burner nozzle geometry was changed to improve air-fuel mixing state which leads to prevention of ring formation. CFD simulation and experimental test were performed in this study to investigate the effect of air-fuel mixing on flame structure, temperature and $NO_X$ concentration. It is shown that combustion efficiency has been enhanced and $NO_X$ concentration has been decreased by using swirl flow for secondary combustion air. It's also shown that flame has been straightened by using straight flow for secondary combustion air.

• 한국연소학회:학술대회논문집
• /
• 2014.11a
• /
• pp.285-288
• /
• 2014

Experiments have been performed for the burners used in the non-oxidizing direct fired furnaces for the cold rolled plate to investigate the effect of fuel/air mixing patterns of the burner nozzle on flame shape, temperature and combustion gas concentration. CFD simulation has also been performed to investigate the mixing state of air-fuel for a nozzle mixing burner and a partially pre-mixing burner. A partially pre-mixing burner showed that flame temperature increased up to $26^{\circ}C$ on average compared than that of the nozzle mixing. It also showed that the mixing distance is important at the partially pre-mixing burner. Test results for a partially pre-mixing burner showed that the residual oxygen concentration and the volume ratio of $CO/CO_2$ of the flame were applicable to be used in field furnaces.

• Journal of the Korean Society of Combustion
• /
• v.9 no.4
• /
• pp.22-27
• /
• 2004

Lean premix combustion is a best method in low $NO_x$ gas turbine combustor and we must know the characteristics of NO emission in high temperature and pressure condition in premix flame. Numerical analysis was performed to investigate the NO emission characteristics by adopting a counterflow as a model problem using detailed chemical kinetics. Methane $(CH_4)$ was used as a test fuel which is the main fuel of natural gas. The tested parameters were stretch rate, equivalence ratio, initial temperature, and pressure in premix flame. Results showed that NO emission was high in low stretch rate, near stoichiometric equivalence ratio, high initial temperature, and high pressure. Also, the pressure effect was sensitive in high temperature condition.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.2 no.2
• /
• pp.12-23
• /
• 1994

In order to investigate the effect of turbulent intensity on combustion characteristics, new flame factor model was developed. The principal study is the evaluation of interaction of swirl, tumble and unstrutural component of flow characteristics and correlation between turbulent intensity and flame factor. Computational and experimental study has been, performed such as quasi-dimensional cycle simulation, three dimensional flow analysis, engine performance test and diagnostic simulation. From these studies, it was found that flame factor was a function of engine speed and turbulent intensity.