• Title/Summary/Keyword: Firing order

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The Effect of Borax Solution on the Reduction of Fine Particles in Flue Gas at a Commercial Circulating Fluidized-bed Boiler Firing Bituminous Coal (순환 유동층 보일러에서 석탄 연소 시 Borax Solution이 연소 배가스중 미세먼지 저감에 미치는 영향)

  • Park, Jae Hyeok;Lee, Dong-Ho;Bae, Dal-Hee;Choi, Yu Jin;Ryu, Hwan-Woo;Kim, Ji-Bong;Han, Keun Hee;Shun, Dowon
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.492-500
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    • 2019
  • In this study, the effect of chemical additives on the reduction of fine particles was identified in $9.2MW_e$ commercial scale circulating fluidized bed boiler firing bituminous coal. Futhermore, a simple and effective method of fine particle collection has been developed to collect the fine particles of the boiler during fossil fuel combustion. Chemical additives were used to reduce particles below 10 PM in the flue gas, and borax solution was used as a chemical additive. In order to identify the particle behavior of PM 10 or less among the collected fine particles, it was analyzed through particle size analyzer and SEM analysis. The Borax solution tends to absorb molten mineral in the flue gas and make fine particles grow. As a result, it was analyzed that particles smaller than $10{\mu}m$ were reduced by using borax solution.

Formation of Ni / Cu Electrode for Crystalline Si Solar Cell Using Light Induced Electrode Plating (광유도 전해 도금법을 이용한 결정질 실리콘 태양전지용 Ni/Cu 전극 형성)

  • Hong, Hyekwon;Park, Jeongeun;Cho, Youngho;Kim, Dongsik;Lim, Donggun;Song, Woochang
    • Journal of Institute of Convergence Technology
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    • v.8 no.1
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    • pp.33-39
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    • 2018
  • The screen printing method for forming the electrode by applying the existing pressure is difficult to apply to thin wafers, and since expensive Ag paste is used, it is difficult to solve the problem of cost reduction. This can solve both of the problems by forming the front electrode using a plating method applicable to a thin wafer. In this paper, the process conditions of electrode formation are optimized by using LIEP (Light-Induced Electrode Plating). Experiments were conducted by varying the Ni plating bath temperature $40{\sim}70^{\circ}C$, the applied current 5 ~ 15 mA, and the plating process time 5 ~ 20 min. As a result of the experiment, it was confirmed that the optimal condition of the structural characteristics was obtained at the plating bath temperature of $60^{\circ}C$, 15 mA, and the process time of 20 min. The Cu LIEP process conditions, experiments were conducted with Cu plating bath temperature $40{\sim}70^{\circ}C$, applied voltage 5 ~ 15 V, plating process time 2 ~ 15 min. As a result of the experiment, it was confirmed that the optimum conditions were obtained as a result of electrical and structural characteristics at the plating bath temperature of $60^{\circ}C$ and applied current of 15 V and process time of 15 min. In order to form Ni silicide, the firing process time was fixed to 2 min and the temperature was changed to $310^{\circ}C$, $330^{\circ}C$, $350^{\circ}C$, and post contact annealing was performed. As a result, the lowest contact resistance value of $2.76{\Omega}$ was obtained at the firing temperature of $310^{\circ}C$. The contact resistivity of $1.07m{\Omega}cm^2$ can be calculated from the conditionally optimized sample. With the plating method using Ni / Cu, the efficiency of the solar cell can be expected to increase due to the increase of the electric conductivity and the decrease of the resistance component in the production of the solar cell, and the application to the thin wafer can be expected.

A Study on the Preplanned Target Allocation Problem for Minimizing Fire Time of Field Artillery (포병부대 계획표적 사격시간 단축을 위한 표적할당에 관한 연구)

  • Hwang, Won-Shik;Chun, Youn-Hwan;Phak, Hyon-Su;Youn, Sang-Heom
    • Journal of the military operations research society of Korea
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    • v.36 no.1
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    • pp.15-27
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    • 2010
  • Fire sequencing problem is to find a sequence of firing on the targets. The latest, because the korea artillery force is inferior in number as compared with north korea force. It is an important question to give a fatal damage to the enemy force by using prompt and accurate fire in order to overcome the lack of artillery force. Minimizing the fire finishing time will secure the adapt ability in tactical operation. In this paper, we developed a mathematical model to do allocation the fire on the targets to decrease to total fire operation time. In order to work out the fire sequencing problem, MIP is developed and the optimum solution is obtained by using ILOG OPL. If this analytical model is applied to the field artillery unit, it will improve the artillery fire force enhancement.

A Study on Ion Extraction Characteristics of Ceramics by Cleaning Agents (보존처리용 세척제에 대한 토기의 이온용출 특성연구)

  • Park, Dae-Woo;Kang, Hyun-Mi;Nam, Byeong-Jik;Jang, Sung-Yoon;Ham, Chul-Hee
    • 보존과학연구
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    • s.31
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    • pp.43-57
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    • 2010
  • This study intends to provide quantitative data about the extraction characteristics of major elements of earthenware by executing soaking test of cleaning agents. It aims at providing basic data for the stability assessment when applying the cleaning agents for conserving earthenware. The data will be extracted from the analysis of co-relationship between the physical characteristics and the ion extraction characteristics. XRD analysis displayed that AT-1, AT-2 and AT-3 which did not generate mullite were fired at lower than 1,000 whereas AT-3 and AT-5 that included mullite were higher than 1,000. The degree of absorption was AT-4 > AT-2 > AT-1 > AT-3 > AT-5 in order and the correlation between the degree of absorption and firing temperature of earthenware displayed a positive correlation. Extraction amount of oxalic acid which was used for the removing iron oxide was AT-1 > AT-2 AT-4 > AT-3 > AT-5 in order. and the ion extraction data displayed that there is a positive correlation with absorption level. However AT-1 and AT-2 which were fired at lower temperature showed that there was no correlation between the ion extraction characteristics and absorption level. Ion extraction of citric acid produced little amount compared with the one of oxalic acid, yet it caused less damage to earthenware than oxalic acid when it applied. The result of ion extraction level in the absorption test displayed that Fe had higher level than in Si, Al from the test for both oxalic acid and citric acid. Based on the regression analysis of the data from the previous studies, the physical characteristics of the earthenware and ion extraction level, further studies will be conducted on the predicting technique on the extraction characteristics of major elements of earthenware samples for the conservation in future.

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Investigation for Utilization of Separator Bag Filter Cement (세퍼레이터 백필터 집진 미립자시멘트 (SBFC : Separator Bag Filter Cement)의 활용성 검토)

  • Kim, Kyoung-Min;Park, Sang-Joon;Yoo, Jea-Kang;Lee, Eui-Bae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.78-83
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    • 2010
  • This paper presents the feasibility of incorporating ultrafine particles collected in the separator bag filter (separator bag filter cement, SBFC) during the cement manufacturing process as an substitution material for cement. SBFC does not require additional processes needed in the existing processes to manufacture high early strength cement such as modifying mineral components and adjusting the firing temperature. Moreover, it can also solve the issue of efficiency decrease resulted from the increase of the grinding time applied in the existing process of manufacturing microcement. Therefore, this research has examined the characteristics of SBFC and fresh properties and mechanical properties after making paste and mortar using SBFC in order to use SBFC as a material to gain early strength of concrete. For results, analyzing the chemical composition and physical properties of SBFC, its blaine value was $6,953cm^3/g$, about double than that of OPC, but its chemical composition showed no significant difference. According to the result of the paste and mortar examination, the paste and mortar mixed with SBFC showed a lower flowability, earlier setting time, and higher compressive strength than that with OPC. The result of microstructure analysis of paste, the paste mixed with SBFC indicated about 9% lower internal porosity at an early age than that of OPC. The compressive strength and flexural strength of mortar were higher in the order of SBFC ratio of 100, 50 and 0% SBFC.

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Synthesis of Tialite Ceramic Pigments and Coloring in Glazes (Tialite계 세라믹 안료의 합성 및 유약에서의 발색)

  • Kim, Yeon-Ju;Lee, Byung-Ha
    • Korean Journal of Materials Research
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    • v.21 no.8
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    • pp.450-455
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    • 2011
  • [ $Al_2TiO_5$ ]has a high refractive index and good solubility of the chromophore in the $Al_2TiO_5$ lattice, which allows this structure to be a good candidate for the development of new ceramic pigments. However, pure $Al_2TiO_5$ is well known to decompose on firing at $900{\sim}1100^{\circ}C$. However, this process can be inhibited by the incorporation of certain metal cations into its crystalline lattice. In this study, the synthesis of gray ceramic pigment was performed by doping cobalt on the $Al_2TiO_5$ crystal structure. The $Al_2TiO_5$ was synthesized using $Al_2O_3$ and $TiO_2$, and doped with $Co_3O_4$ as a chromophore material. In order to prevent the thermal decomposition during the cooling procedure, MgO was added to samples by 0.05 mole, 0.1 mole, and 0.15 mole as a stabilizer. The samples were fired at $1500^{\circ}C$ for 2 hours and cooled naturally. The crystal structure, solubility limit, and color of the synthesized pigment were analyzed using XRD, Raman spectroscopy, UV, and UV-vis. $Al_2O_3$ was available for the formation of $CoAl_2O_4$, which should also be considered in order to explain the small amount of this phase detected in the sample with the higher $Co^{2+}$ content (${\geq}$ 0.03 mole). It was found that the solubility limit of $Co^{2+}$ in the $Al_2TiO_5$ crystal was 0.02 mole% through an analysis of Raman spectroscopy. Through the addition of a pigment with 0.02 mole% of $Co^{2+}$ to lime-barium glaze, stabilized gray color pigments with 66.54, -2.35, and 4.68 as CIE-$L^*a^*b^*$ were synthesized.

Comparison of Muscle Onset Times During Perturbation Between Subjects With and Without Work-Related Chronic Low Back Pain (직업성 만성요통 환자와 정상성인에서 동요 유발 시 근 수축 개시시간 비교)

  • Roh, Kyung-Sun;Kwon, Oh-Yun;Yi, Chung-Hwi;Jeon, Hye-Seon
    • Physical Therapy Korea
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    • v.14 no.2
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    • pp.21-28
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    • 2007
  • The purpose of this study was to compare the onset times of muscle activities and the order of muscle firing in erector spinae, multifidus, rectus abdominis and biceps brachii during perturbation between subjects with and without work-related chronic low back pain (LBP). Twenty-nine subjects, 14 with and 15 without LBP, participated in this study. The muscle responses were measured by surface EMG (electromyography) during perturbation in eye opened and eye closed conditions. The EMG onset times of the erector spinae, multifidus, rectus abdominis and biceps brachii were similar between groups in eye closed condition. But the onset times of the erector spinae, multifidus, rectus abdominis were significantly delayed in subjects with LBP in eye opened condition. The results provide an evidence for impaired feed-forward control of the trunk muscles in subjects with LBP. Further studies are needed to identify whether the impaired feed-forward control of the trunk muscles is the contributing factor to LBP.

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Development of CNT-dispersed Si3N4 Ceramics by Adding Lower Temperature Sintering Aids

  • Matsuoka, Mitsuaki;Yoshio, Sara;Tatami, Junichi;Wakihara, Toru;Komeya, Katsutoshi;Meguro, Takeshi
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.333-336
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    • 2012
  • The study to give electrical conductivity by dispersing carbon nanotubes (CNT) into silicon nitride ($Si_3N_4$) ceramics has been carried out in recent years. However, the density and the strength of $Si_3N_4$ ceramics were degraded and CNTs disappeared after firing at high temperatures because CNTs prevent $Si_3N_4$ from densification and there is a possibility that CNTs react with $Si_3N_4$ or $SiO_2$. In order to suppress the reaction and the disappearance of CNTs, lower temperature densification is needed. In this study, $HfO_2$ and $TiO_2$ was added to $Si_3N_4-Y_2O_3-Al_2O_3$-AlN system to fabricate CNT-dispersed $Si_3N_4$ ceramics at lower temperatures. $HfO_2$ promotes the densification of $Si_3N_4$ and prevents CNT from disappearance. As a result, the sample by adding $HfO_2$ and $TiO_2$ fired at lower temperatures showed higher electrical conductivity and higher bending strength. It was also shown that the mechanical and electrical properties depended on the quantity of the added CNTs.

Air Pollutant Variations Observed at Deokjeok Island in the Yellow Sea During April 1999 to June 2000 (1999년 4월부터 2000년 6월까지 황해 덕적도에서 관찰된 대기오염물질 변화 특성)

  • 김영성;이승복;김진영;배귀남;문길주;원재광;윤순창
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.4
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    • pp.347-361
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    • 2003
  • Sulfur dioxide (SO$_2$), ozone, total suspended particulates (TSP) and PM$_{2.5}$ were measured at Deokjeok Island in the Yellow Sea during April 1999 to June 2000. Although the emission amount of air pollutants is quite low in this small island of 36 km$^2$ with 1.4 thousand inhabitants, there are pollutant sources such as an oil -firing power plant and a wharf for ferryboat. The island is also influenced from the emissions from the greater Seoul area in the east and from China in the west. In order to characterize the pollutant variations due to interactions between transport and local emissions. the correlation between variations of SO$_2$ and ozone was investigated. Mass and ion concentrations of TSP and PM$_{2.5}$ were examined on selected episode days of positive and negative correlations between the two gaseous species in spring and winter. The effects of transport were pronounced on the days of positive correlation in spring with higher concentrations of ozone and PM$_{2.5}$. TSP concentrations were also high on these days because of high wind speeds. On the days of negative correlation in spring, frequent fog associated with low wind speeds facilitated SO$_2$ oxidation and increased sulfate accompanied with decrease in nitrate in PM$_{2.5}$ and chloride in TSP. This latter phenomena was noticeable since it showed that chemical composition of fine particles could be significantly altered not only during the transport but also by local environment.ronment.

COLOR STABILITY AND SURFACE TEXTURE TO TEMPERATURE AT STASHING OF PORCELAIN RESTORATION (도재수복물의 표면첨색시 온도에 따른 색조안정성과 표면조도의 평가)

  • Beak Eun-Ju;Bae Tae-Seong;Song Kwang-Yeob;Park Charn-Woon
    • The Journal of Korean Academy of Prosthodontics
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    • v.29 no.3
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    • pp.87-99
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    • 1991
  • The effect of oven firing on the color stability and surface texture of extrinsic stains used characterization and color modification of metal cermic restoration were studied by comparing different temperatures and techniques. They were autoglaze technique, applied glaze technique, two step low-fusing glaze technique and one step low-fusing glaze technique. Autoglaze technique and applied glaze technique were air-fired to manufacturer's recommended temperature. Two step low-fusing glaze technique is separated staining and overglazing. Thin slurry of stain powder were air-fired to $1500^{\circ}F$, Overglaze powder powder was then mixed with seam medium and air-fired to $170^{\circ}F$. One step low-fusing glaze technique is combined staining and overglazing. Thin slurry of stain and glaze powder were air-fired to $170^{\circ}F$. The obtained results were as fellows. 1. Slightly significant color differences by colorimeter were found between different stain application and fusion techniques(P<0.05). 2. Two step low-fusing glaze method showed the most rough surface, especially ceramco orage stain(P<0.05). 3. Surface roughness increased gradually in order of autoglaze, applied glaze, one step low-fusing glaze but they were not significantly different(P<0.05). 4. When two step low-fusing glaze was applied, both color measurement and surface texture were sinificantly different from other groups(P<0.05).

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