• Title/Summary/Keyword: Ferrite powder

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Structural and Magnetic Properties of Z-type Barium Ferrite (Z-type 바리움 페라이트의 구조 및 자기적 성질)

  • Nam, In Tak
    • Journal of Industrial Technology
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    • v.28 no.A
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    • pp.119-123
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    • 2008
  • Structural and magnetic properties of $CO_{1-x}Zn_xZ$ ($Ba_3Co_{1-x}Zn_xFe_{24}O_{41}$) hexa-ferrite are studied using XRD, VSM and SEM, respectively. Powder was prepared from co-precipitation and firstly heat treated at $1350^{\circ}C$ for 6 hours in $O_2$ atmosphere. Second heat treatment was performed at 900, 1000, $1100^{\circ}C$ for 6 hours in air, respectively. Saturation magnetization value of first heat treated powder is acceptable and coercivity is high for applying to device. These result may be originated from incomplete formation reaction from M and Y phases to Z phase. Second heat treatment leads to small value of coercivity.

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Preparation of Ultrafine Mn-Zn Ferrite by Direct-Wet Synthesis and a Study of Magnetic Properties (습식직접 합성에 의한 초미분 Mn-Zn Ferrite의 합성과 자성특성에 관한 연구)

  • 이경희;이병하;허원도;황우연
    • Journal of the Korean Ceramic Society
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    • v.28 no.10
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    • pp.757-766
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    • 1991
  • These powder properties were investigated and prepared of ultrafine Mn-Zn ferrite powder by Direct-wet process from variation of oxidation condition. H2O2 oxidation the products were ultrafine spherical particles of about 400${\AA}$ in diameter and superparamagnetics. H2O2 and Air oxidation, Coexistance ultrafine spherical particles of about 400${\AA}$ and cubic particles of about 1000${\AA}$. The products were constructed of superparamagnetic and ferromagnetic particles, and Magnetization were about 30 emu/g. Air Oxidation, Above 6 hr Air 120 ι/hr and 4 hr of Air 180 ι/hr were uniform cubic particles of above 1000${\AA}$. The products were ferromagnetic particles and Magnetization of above 45 emu/g.

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Fabrication of Nano-Sized Complex Oxide Powder from Waste Solution Produced during Shadow Mask Processing by Spray Pyrolysis Process (새도우마스크 제조 공정중 발생되는 폐액으로부터 분무열분해 공정에 의한 복합산화물 나노 분말 제조)

  • Yu Jae-Keun
    • Resources Recycling
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    • v.12 no.6
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    • pp.38-46
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    • 2003
  • In this study, nano-sized Ni-ferrite and $Fe_2$$O_3$+NiO powder was fabricated by spray pyrolysis process in the condition of 1kg/$\textrm{cm}^2$ air pressure using the Fe-Ni complex waste acid solution generated during the manufacturing process of shadow mask. The average particle size of the produced powder was below 100 nm. The effects of the reaction temperature, the concentration of raw material solution and the nozzle tip size on the properties of powder were studied. As the reaction temperature increased from $800 ^{\circ}C$ to $1100^{\circ}C$, the average particle size of the powder increased from 40 nm to 100 nm, the structure of the powder gradually became solid, yet the distribution of the particle size appeared more irregular. Along with the increase of the reaction temperature, the fraction of the Ni-ferrite phase were also on the rise, and the surface area of the powder was greatly reduced. As the concentration of Fe in solution increased from 20g/l to 200g/l, the average particle size of the powder gradually increased from 30 nm to 60 nm, while the distribution of the particle size appeared more irregular. Along with the increase of the concentration of solution, tie fraction of the Ni-ferrite phase was on the rise, and the surface area of the powder was greatly reduced. Along with the increase of the nozzle tip size, the distribution of the particle size appeared more irregular, yet the average particle size of the powder showed no significant change. As the nozzle tip size increased from 1 mm to 2 mm, the fraction of the Ni-ferrite phase showed no significant change, while the surface area of the powder slightly reduced. As the nozzle tip size increased to 3 mm and 5 mm, the fraction of the Ni-ferrite phase gradually reduced, and the surface area of the powder slightly increased.

A Study on the Electric-magnetic Properties of Mg-ferrite with Various Mixing Time of Raw Materials (원료 분말의 혼합 시간에 따른 소결 Mg-Ferrite의 전기.자기적 특성 변화)

  • 김성재;백종규
    • Journal of the Korean Ceramic Society
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    • v.32 no.3
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    • pp.289-294
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    • 1995
  • As the results of the study on the effects of mixing time for raw materials to the electric and magnetic properties of Mg-ferrite, the fraction of spinel phase after calcination and the geometry density of sintered Mg-ferrite increased from 30% to 100% and from 2.5g/cc to 4.25g/cc respectively due to mixing-homobenity of raw materials. The AC resistivity of grains decreased and lattice parameter, saturation magnetization increased due to the increase in Fe+2 of sintered body. conclusively the characteristic of powder after calcination had strong influence on the microstructure, electric, and magnetic properties in Mg-ferrite sintered body.

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Effect of Molar Ratio of $Fe_2O_3$ and BaO Addition on the Characteristics of Sr-Ferrite ($Fe_2O_3$몰비 및 B\ulcorner첨가가 Sr-Ferrite 특성에 미치는 영향)

  • 문기훈;심영재;조성걸
    • Journal of the Korean Ceramic Society
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    • v.34 no.5
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    • pp.453-460
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    • 1997
  • Sr-ferrite having magnetoplumbite structure is similar to Ba-ferrite in magnetic characteristics, but better magnetic characteristics for using motor application. To improve remanence magnetic flux density(Br) and coercive force(iHc), it is necessary that sintered ferrites must have high density and grain size less than 1 $\mu$m. By varying n values in SrO.nFe2O3 basic composition, calcination temperature, and BaO addition, Sr-ferrite powder and sintered specimen was prepared. The n values, calcination temperature, and BaO addition affected secondary phase formation, particle size, and particle shape. BaO addition enhanced Fe2O3 secondary phase and hexagonal shape particle. Fe2O3 phase reduced sintered density which greatly decreased Br.

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Preparation for Mn-Zn Ferrite Soft Magnetic Underlayer Perpendicular Magnetic Recording Disk using Mn-Zn-Fe-O Metal Target (Mn-Zn-Fe-O 금속타깃을 이용한 수직자기기록디스크의 하지연자성층용 Mn-Zn ferrite 박막제작)

  • Kong, Sok-Hyun;Kim, Kyung-Hwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.9
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    • pp.883-887
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    • 2006
  • In order to attain high-rate deposition of Mn-Zn ferrite thin film for soft magnetic underlayer in perpendicular magnetic recording media, a reactive sputtering using powder-metal targets under the mixture gas of Ar and $O_{2}$ was performed. It was succeeded that Mn-Zn ferrite films with (111) crystal orientation were deposited on Pt(111) underlayer without any annealing process. The film revealed 3.4 kG of 4 ${\pi}Ms$, 70 Oe of coercivity. The deposition rate of the new method was 16 times as high as that of the conventional method using ferrite target.

Structural and Magnetic Properties of (CoFe2O4)0.5(Y3Fe5O12)0.5 Powder

  • Lee, Jae-Gwang;Chae, Kwang-Pyo;Lee, Young-Bae;Lee, Sung-Ho
    • Journal of Magnetics
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    • v.10 no.3
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    • pp.80-83
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    • 2005
  • Cobalt ferrite and garnet powders were grown using a conventional ceramic method in two different ways for understanding the magnetic interaction between structurally different materials. Structures of these powders were investigated by using an X-ray diffractometer (XRD) and the magnetic interaction between iron ions and the magnetic properties of the powders were measured by a $M\ddot{o}ssbauer$ spectroscopy and a vibrating sample magnetometer (VSM), respectively. The result of the XRD measurement showed that the annealing temperature higher than $1200^{\circ}C$ was necessary to grow a $(CoFe_2O_4)_{0.5}(Y_3Fe_5O_{12})_{0.5}$ powder. $M\ddot{o}ssbauer$ spectra for the powders grown separately and mixed mechanically consisted of sub-spectra of cobalt ferrite and garnet, however, powders annealed together had an extra sub-spectrum, which was related with the magnetic interaction between the grain surface of cobalt ferrite and the one of the garnet. In case of annealing the powders at the temperature large enough to crystallize them, raw chemicals became fine cobalt ferrite and garnet particles at first and then these fine particles were aggregated and formed large grains of ferrite powders. The result of the VSM measurement showed that the powders prepared at $1200^{\circ}C$ had the similar saturation magnetization and the coercivity regardless of the preparation method.

Characteristic of Electromagnetic Wave Shielding Coatings by Thermal Spray (용사에 의한 페라이트 자성재료 코팅의 .전자파 차폐특성)

  • 정태식;박경채
    • Proceedings of the KWS Conference
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    • 2000.10a
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    • pp.240-242
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    • 2000
  • This study was investigated absorption properties of electromagnetic wave in thermal sprayed Sr-ferrite coatings. The experiment of this study was ; manufactured thermal spraying powder for improving absorption-efficiency, processed for increasing strength of thermal spray coatings, and measured the electromagnetic wave shielding efficiency. This study was obtained excellent absorption-efficiency by thermal sprayed Sr-ferrite coatings.

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