• Title/Summary/Keyword: FeS

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Effects of NiFeCo of NiFe Insertion Layers on the Giant Magnetoresistance Behavior of Ni/Cu Artificial Superlattice (Ni/Cu 인공초격자에서 NiFeCo 및 NiFe 계면 삽입층이 거대자기저항 거동에 미치는 영향)

  • 송용진;주승기
    • Journal of the Korean Magnetics Society
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    • v.5 no.6
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    • pp.963-967
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    • 1995
  • Ultra thin layers of NiFeCo or NiFe were inserted at the interfaces of Ni and Cu to form a multilayer structure. In case of inserting a NiFe layer, the magnetoresistance was about 6%, the saturation magnetic field was 50 Oe and the hysteresis of R-H (resistance-magnetic field) was very small. In case of inserting a NiFeCo layer, the magnetoresistance increased to about 7% but the saturation magnetic field and hysteresis were also increased. The increase of the output under biased magnetic field was much larger in case of inserting a NiFe layer because of relatively smaller hysteresis in R-H behavior.

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Improvement of Sewage Sludge Dewaterability using Fe(II)/Na2S2O8 (Fe(II)/Na2S2O8을 이용한 하수슬러지 탈수능 개선)

  • Han, Jun-Hyuk;Nam, Se-Yong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.30 no.3
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    • pp.23-28
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    • 2022
  • In order to investigate the degree of sewage sludge dewaterability using Fe(II)/Na2S2O8, STTF, SCST, water content, TS, VS, TB-EPS as carbohydrate and Protein were measured. The dosage of Na2S2O8 was varied from 0.4 to 0.7 mmol/gVS and molar ratio of Fe(II)/Na2S2O8 was varied from 0.5 to 0.7 mol/mol. According to the increase of the dosage of Na2S2O8 and Fe(II)/Na2S2O8 molar ratio, STTF and SCST increased from 1.00 to 15.00 and 4.51, respectively. Water content decreased to 82.6%. TB-EPS as carbohydrate and protein decreasing rate also increased to 37.16% and 57.34%, respectively. Especially, Na2S2O8 0.6 mmol/gVS and Fe(II)/Na2S2O8 0.6 mol/mol condition, water content dercreased to 83.1%, STTF and SCST increased to 13.64 and 4.19 which showed the cost effective improvement of dewaterability. It is considered that SO4- radical generated by Fe(II)/Na2S2O8 degraded EPS and converted bound water to free water.

Electronic Structures and Magnetism of the MgCFe3(001) Surface

  • Jin, Ying-Jiu;Kim, I. G.;Lee, J. I.
    • Journal of Magnetics
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    • v.7 no.4
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    • pp.132-137
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    • 2002
  • The electronic structures and magnetism of the non-oxide perovskite MgCFe$_3$(001) surface were investigated by using the all-electron full-potential linearized augmented plane wave (FLAPW) method within the generalized gradient approximation (GGA). We considered both of the MgFe terminated (MgFe-Term) and the CFe terminated (CFe-Term) surfaces. We found that the minority spin d-bands of Fe(S) of the MgFe-Term are strongly localized and Fermi level (EF) lies just below the sharp peak of the minority spin d-band of Fe(S), while the minority spin d-bands of Fe(S) of the CFe-Term are not localized much and Fermi level (E$_F$) lies in the middle of two peaks of the minority spins. The majority Fe(S) d-band width of MgFe- Term is narrower than that of the CFe-Term. It is found that the magnetic moment of Fe(S) of the MgFe- Term is 2.51 ${\mu}$$_B$, which is much larger than that of 1.97 ${\mu}$$_B$ of the CFe-Term.

Effect of Conductive Additives on $FeS_2$ Cathode ($FeS_2$ 양극에 미치는 전도성 첨가제의 영향)

  • Choi, Yu-Song;Cheong, Hae-Won;Kim, Ki-Youl;Cho, Sung-Baek
    • Journal of the Korea Institute of Military Science and Technology
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    • v.15 no.2
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    • pp.224-230
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    • 2012
  • Thermal batteries have excellent mechanical robustness, reliability, and long shelf life. Due to these characteristics as well as their unique activation mechanism, thermal batteries are widely adopted as military power sources. Li(Si)/$FeS_2$ thermal batteries, which are used mostly in these days, use LiCl-KCl and LiBr-LiCl-LiF as molten salt electrolyte. However, it is known that Li(Si)/$FeS_2$ thermal batteries have high internal resistance. Especially, $FeS_2$ cathode accounts for the greater part of internal resistance in unit cell. Many efforts have been put into to decrease the internal resistance of thermal batteries, which result in the development of new electrode material and new electrode manufacturing processes. But the applications of these new materials and processes are in some cases very expensive and need complicated additional processes. In this study, internal resistance study was conducted by adding carbon black and carbon nano-tube, which has high electron conductivity, into the $FeS_2$ cathode. As a results, it was found that the decrease of internal resistance of $FeS_2$ cathode by the addition of carbon black and carbon nano-tube.

Local Structure Refinement of the $BaFe_{1-x}Sn_xO_{3-y}$ System with Fe K-Edge X-Ray Absorption (XANES/EXAFS) Spectroscopy

  • 김민규;곽기섭;로권선;여철현
    • Bulletin of the Korean Chemical Society
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    • v.18 no.7
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    • pp.743-749
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    • 1997
  • Local structure refinement of the BaFe1-xSnxO3-y system (x=0.00-0.50) has been carried out with Fe K-edge x-ray absorpion spectroscopic studies. It is found out that the Fe ions are placed in two different symmetric sites such as tetrahedral and octahedral sites in the compounds by comparison with Fe K-edge x-ray absorption near edge structure (XANES) spectrum of the γ-Fe2O3 compound as a reference. Small absorption peaks of dipole-forbiden transitions appear at a pre-edge region of 7111 eV due to the existence of Fe ions in the tetrahedral and octahedral sites. The peak intensity decreases with the substitution amount of Sn ion. Three different absorption peaks of 1s→4p dipole-allowed transition appear on the energy region between 7123 and 7131 eV. The peaks correspond to 1s→4p main transition of Fe ions in tetrahedral and octahedral sites and 1s→4p transition followed by the shakedown process of ligand to metal charge transfer. The bond distances between Fe ions in the tetrahedral site and nearest neighboring oxygen atom (Fe-4O), and those in octahedral site (Fe-6O) are determined with the extended x-ray absorption fine structure (EXAFS) analysis. Two different interatomic distances increase with the substitution amount of Sn ion and also the bond lengths of Fe-4O are shorter than those of Fe-6O in all compounds.

Nano-structure and Magnetic Properties of FePd Superlattice Thin Film (FePd 인공격자박막의 나노구조 및 자기적 특성)

  • Kang, J.G.;Chung, I.S.;Koo, J.W.;Koh, J.H.;Koo, S.M.;Nam, S.M.;Ha, J.G.
    • Journal of the Korean Magnetics Society
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    • v.18 no.5
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    • pp.190-194
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    • 2008
  • Epitaxial $L1_0$ FePd (001) thin films were successfully manufactured by sputtering deposition method. The structure and magnetic properties of FePd thin films were characterized as a function of Fe compositions. It was found that the long-range ordering parameter had a maximum for the stoichiometric composition, whereas the magnetic anisotropy had a maximum as the Fe content is decreased to slightly above the stoichiometric composition. This indicates that the stoichiometry is directly contributed to the chemical ordering and the magnetic anisotropy. These results imply that nonstoichiometric FePd compositions, with a slight excess of Pd, may in fact be preferred for applications that require high magnetic anisotropy.

Characteristics of Magnetic Tunnel Junctions Comprising Ferromagnetic Amorphous NiFeSiB Layers (강자성 비정질 NiFeSiB 자유층을 갖는 자기터널접합의 스위칭 특성)

  • Hwang, J.Y.;Rhee, S.R.
    • Journal of the Korean Magnetics Society
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    • v.16 no.6
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    • pp.279-282
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    • 2006
  • Magnetic tunnel junctions (MTJs), which consisted of amorphous ferromagnetic NiFeSiB free layers, were investigated. The NiFeSiB layers were used to substitute for the traditionally used CoFe and/or NiFe layers with the emphasis being given to obtaining an understanding of the effect of the amorphous free layer on the switching characteristics of the MTJs. $Ni_{16}Fe_{62}Si_{8}B_{14}$ has a lower saturation magnetization ($M_{s}:\;800\;emu/cm^{3}$) than $Co_{90}Fe_{10}$ and a higher anisotropy constant ($K_{u}:\;2700\;erg/cm^{3}$) than $Ni_{80}Fe_{20}$. The $Si/SiO_{2}/Ta$ 45/Ru 9.5/IrMn 10/CoFe $7/AlO_{x}/CoFeSiB\;(t)/Ru\;60\;(in\;nanometers)$structure was found to be beneficial for the switching characteristics of the MTJ, leading to a reduction in the coercivity ($H_{c}$) and an increase in the sensitivity resulted from its lower saturation magnetization and higher uniaxial anisotropy. Furthermore, by inserting a very thin CoFe layer at the tunnel barrier/NiFeSiB interface, the TMR ratio and switching squareness were improved more with the increase of NiFeSiB layer thickness up to 11 nm.

Differences in the Electronic Structures of Bulk and Powder FeV2O4 Spinel Oxide Investigated by Using Synchrotron Radiation (방사광을 이용한 FeV2O4 스피넬 산화물의 덩치상태와 분말상태의 전자구조 차이 연구)

  • Hwang, Ji-Hoon;Kim, D.H.;Lee, Eun-Sook;Kang, J.S.;Kim, W.C.;Kim, C.S.;Han, S.W.;Hong, S.C.;Park, B.G.;Kim, J.Y.
    • Journal of the Korean Magnetics Society
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    • v.21 no.6
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    • pp.198-203
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    • 2011
  • The electronic structure of ferrimagnetic spinel oxide of $FeV_2O_4$ has been investigated by employing soft x-ray absorption spectroscopy (XAS) and soft x-ray magnetic circular dichroism (XMCD). The Fe 2p and V 2p XAS spectra show that the valence states of Fe and V ions are ${\sim}Fe^{2.3+}$ mixed-valent states and ${\sim}V^{3+}$ states, respectively. In Fe 2p XMCD spectra, finite XMCD signals are observed for divalent $Fe^{2+}$ states only, but not for $Fe^{3+}$ states. This finding indicates that the magnetic moments of $Fe^{2+}$ ions are ordered ferromagnetically but that those of $Fe^{3+}$ ions are cancelled, implying that $Fe^{2+}$ ions play an important role in determining magnetic properties of $FeV_2O_4$.