• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 1996년도 추계학술강연 및 발표대회 강연 및 발표논문 초록집
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• pp.9-9
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• 1996

• 한국분말재료학회지
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• 제13권4호
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• pp.285-289
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• 2006

Co-Fe-Ni-B-Si-Cr based amorphous strips containing nitrogen were manufactured via melt spinning, and then devitrified by crystallization treatment at the various annealing temperatures of $300^{\circ}C{\sim}540^{\circ}C$ for up to 30 minutes in an inert gas $(N_2)$ atmosphere. The microstructures were examined by using XRD and TEM and the magnetic properties were measured by using VSM and B-H meter. Among the alloys, the amorphous ribbons of $Co_{72.6}Fe_{9.8}Ni_{5.5}B_{2.4}Si_{7.1}Cr_{2.6}$ containing 121 ppm of nitrogen showed relatively high saturation magnetization. The alloy ribbons crystallized at $540^{\circ}C$ showed that the grain size of $Co_{72.6}Fe_{9.8}Ni_{5.5}B_{2.4}Si_{7.1}Cr_{2.6}$ alloy containing 121 ppm of nitrogen was about f nm, which exhibited paramagnetic behavior. The formation of nano-grain structure was attributed to the finely dispersed Fe4N particles and the solid-solutionized nitrogen atoms in the matrix. Accordingly, it can be concluded that the nano-grain structure of 5nm in size could reduce the core loss within the normally applied magnetic field of 300A/m at 10kHz.

• 한국분말재료학회지
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• 제18권5호
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• pp.430-436
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• 2011

Joining of NiO-YSZ to 316 stainless steel was carried out with B-Ni2 brazing alloy (3 wt% Fe, 4.5 wt% Si, 3.2 wt% B, 7 wt% Cr, Ni-balance, m.p. 971-$999^{\circ}C$) to seal the NiO-YSZ anode/316 stainless steel interconnect structure in a SOFC. In the present research, interfacial (chemical) reactions during brazing at the NiO-YSZ/316 stainless steel interconnect were enhanced by the two processing methods, a) addition of an electroless nickel plate to NiO-YSZ as a coating or b) deposition of titanium layer onto NiO-YSZ by magnetron plasma sputtering method, with process variables and procedures optimized during the pre-processing. Brazing was performed in a cold-wall vacuum furnace at $1080^{\circ}C$. Post-brazing interfacial morphologies between NiO-YSZ and 316 stainless steel were examined by SEM and EDS methods. The results indicate that B-Ni2 brazing filler alloy was fused fully during brazing and continuous interfacial layer formation depended on the method of pre-coating NiO-YSZ. The inter-diffusion of elements was promoted by titanium-deposition: the diffusion reaction thickness of the interfacial area was reduced to less than 5 ${\mu}m$ compared to 100 ${\mu}m$ for electroless nickel-deposited NiO-YSZ cermet.

• 소성∙가공
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• 제20권7호
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• pp.491-497
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• 2011

This work describes a method for determining material parameters included in recrystallization and grain growth models of metallic materials. The focus is on the recrystallization and grain growth models of Ni-Fe based superalloy, Alloy 718. High temperature compression test data at different strain, strain rate and temperature conditions were chosen to determine the material parameters of the model. The critical strain and dynamically recrystallized grain size and fraction at various process conditions were generated from the microstructural analysis and strain-stress relationships of the compression tests. Also, isothermal heat treatments were utilized to fit the material constants included in the grain growth model. Verification of the determined material parameters is carried out by comparing the average grain size data obtained from other compression tests of the Alloy 718 specimens with the initial grain size of $59.5{\mu}m$.

• 한국표면공학회지
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• 제47권6호
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• pp.293-296
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• 2014

Fe-Ni has been of great interest because it is known as one of low thermal expansion alloys as various application areas. This alloy was fabricated by electroforming process, and effect of heat treatment on thermal expansion and hardness was investigated. Nano-crystalline structure of 13.3 - 63.5 nm in size was observed in the as-deposited alloy. To investigate the effect of heat treatment on grain growth and mechanical/thermal properties, we conducted hardness and coefficient of thermal expansion (CTE). From this, we confirmed these properties were varied by heat treatment. In this nano-crystalline alloy, we could observe abnormal behavior in thermal expansion between $350-400^{\circ}C$. Additionally, an abrupt change in hardness has also been observed. However, once the grains grow up to micro-sized the mechanical and thermal properties mentioned above were stabilized similar to those of bulk alloys due to heat treatment.

• 대한금속재료학회지
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• 제47권9호
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• pp.558-566
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• 2009

The alloying effect of a small amount of nickel on low alloy steel for application to flue gas desulfurization(FGD) systems was studied. The structural characteristics of the rust layer were investigated by scanning electron microscopy(SEM). The electrochemical properties were examined by means of potentiostatic polarization test, potentiodynamic polarization test, and electrochemical impedance spectroscopy(EIS) in a modified green death solution of 16.9 vol.% $H_2SO_4$+0.35 vol.% HCl at $60^{\circ}C$ and an acid rain solution of $6.25{\times}10^{-5}M\;H_2SO_4+5.5{\times}10^{-3}M\;NaCl$ at room temperature. It was found that as the amount of nickel increased, the corrosion rate increased in the modified green death solution, which seemed to result from micro-galvanic corrosion between NiS and alloy matrix. In acid rain solution, the corrosion rate decreased as the amount of nickel increased due to the repulsive force of $NiFe_2O_4$ rust against $Cl^-$ ions by electronegativity.

• 한국세라믹학회지
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• 제39권8호
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• pp.769-774
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• 2002

금속 산화물 상태으 혼합분말을 수소 환원하여 $Al_2O_3$ 분말 표면에 20 nm 크기의 Fe-Ni 합금이 균일하게 분산된 복합분말을 합성하였다. 상압소결을 이용하여 제조한 $Al_2O_3$/Fe-Ni 나노복합재료는 전 소결 온도 범위에서 단지 $Al_2O_3$와 ${gamma}$-Fe-Ni 상만으로 구성되어 있었고, $1350^{\circ}C$ 이상의 소결 온도에서 98% 이상의 치밀화를 이루었다. 최대 파괴강도와 파괴인성은 각각 574 MPa과 3.9 MP$a{\cdot}m1/2$로서 동일한 소결 조건의 순수 $Al_2O_3$ 보다 약 20% 증가하였다. 나노복합재료는 강자성 거동을 보였으며 분산상의 평균 입자 크기가 감소함에 따라 증가된 보자력 값을 나타내었다.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1995년도 추계학술발표회논문집(2)
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• pp.723-728
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• 1995

Alloy 600 표면에 레이저 빔을 이용하여 Ni, Cr 흔합분말 및 순수 Cr 분말로 표면합금층을 만들었다. 표면 합금층은 모재와 정합계면를 이루고 있으며 레이저 표면용용 시편에서와 같이 크게 면선단 응고부와 셀룰라 응고부로 나눌 수 있고, 모재에는 레이저 처리과정에서 생긴 수십 $\mu\textrm{m}$ 두께의 열영향 부위가 존재하였다. 그리고 합금층 내부에는 레이저 표면 용용된 시편과 달리 구형의 커다란 기공(pores)이 존재하였다. 레이저 표면 합금층에서 합금원소의 조성 분포를 조사하기 위해 레이저 처리된 시편에 대해 WDX 분석을 하였고, 합금층 내부에 Ni, Cr, Fe 원소의 조성 분포는 매우 균일하였다.

• 대한의용생체공학회:의공학회지
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• 제6권1호
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• pp.37-46
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• 1985

Development of a dental Ni-Cr alloy system for porcelain veneering crown and bridge was studied in this research. The principles of alloy design were a) It should not contain toxic beryllium. b) It should have low melting Point. c) It should be easily ground and polished. d) It should possess an adequate strength to resist the deformational force In the mouth. e) It should be bondable Ivith porcelain by chemically. After investigating the effect of minor elements such as boron and rare earth metals on the mechanical properties of the Ni-Cr alloy system, the compromised ideal composition for dental use was determined. The composition was l9.6%, Cr, 5.6% Mo, 3.4% Si, 1, 0% Fe, 0.01% Ti, 0.5-1.0% B, 0.2-0.6% misch metal, balance Ni. To compare the performance of experimental alloy with commercially available alloys, the properties such as strength, melting point, and bond strength were measured. The results Ivere as follows: a) Boron increases the strength of the alloy but reduces the elongation. b) Misch metal increases the strength when the boron content is low, but does not increase the strength when boron content is high. And it reduces the elongation drastically, c) Mechanical strength of the experimental alloy was not superior to commercially available Be containing alloy, but handling performance such as castability, ease of granting and polishing, and cuttability were superior to the Be containing alloy.

• KEPCO Journal on Electric Power and Energy
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• 제1권1호
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• pp.109-113
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• 2015

초임계 이산화탄소 발전 시스템 구축을 위해서는 고온, 고압의 열악한 환경에 노출되는 터빈, 열 교환기, 압축기와 같은 핵심 부품들의 내식성 평가는 반드시 수행되어야 한다. 이를 위해 후보소재 3종 Ferritic-Martensitic Steel (T92), Austenitic Steel (SS316L), Ni-based Alloy (IN738LC)를 선정하여 고온의 유사 초임계 $CO_2$ 발전 환경에서의 내식성 평가를 진행하였다. $600^{\circ}C$, $700^{\circ}C$의 2개의 온도 구간에서 $CO_2$ 분위기를 조성하여 800 시간 동안 노출시킨 뒤, Weight Change, Surface Morphology, Cross Section, Composition을 분석하였다. Cr-rich Protective Layer를 형성하는 Ni-based Alloy와 Fe/Cr-rich oxide를 형성하는 Austenitic Steel은 우수한 부식 저항성을 보인 반면에 Ferritic-Martensitic Steel은 높은 Weight Change와 Fe-rich Non-Protective Oxide가 관찰되어 상대적으로 낮은 부식 저항성을 보였다.