• Title/Summary/Keyword: Fe-Cr

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Corrosion Behaviors of ZrN Coated on Dental Co-Cr Alloys (ZrN 코팅된 치과 주조용 Co-Cr 합금의 부식거동)

  • Lee, Sang-Hun;Nah, Jung-Sook;Jang, Jae-Young
    • Journal of Technologic Dentistry
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    • v.35 no.4
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    • pp.343-352
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    • 2013
  • Purpose: The purpose of this study was to investigate to effect of the ZrN coated on corrosion resistance and physical property of dental Co-Cr alloys using various instruments. Methods: The specimens were used, respectively, for experiment, Arc Ion plating was carried out for dental casting alloys using ZrN coated materials with nitrogen gas. ZrN coated surface of each specimen was observed with field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), vickers hardness tester, and electrochemical tester. Results: The current density of ZrN coated specimen was smaller than that of non-coated specimen in 0.9% NaCl solution. Pit nucleated at scratch of specimen. The pitting corrosion resistant |$E_{max}-E_{rep}$| increased in order of ZrN coated (110 mV), and non-coated wire (100 mV). Conclusion: The corrosion potential of the ZrN coated specimen was comparatively high. the surface of ZrN coated specimen was more smooth than that of other kinds of non-coated specimen. ZrN coated surface showed higher hardness than that of non-coated surface.

Influence of Super Carburization on the Roller Pitting Fatigue Life of 0.16C-0.60Si-2.00Cr-0.34Mo Steel (0.16C-0.60Si-2.00Cr-0.34Mo강의 피팅강도에 미치는 고탄소 침탄의 영향)

  • Shin, Jung-Ho;Lee, Woon-Jae;Kim, Young-Pyo;Ko, In-Yong
    • Korean Journal of Metals and Materials
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    • v.50 no.7
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    • pp.517-522
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    • 2012
  • In this study, a super carburizing treatment was applied to improve roller pitting fatigue life. It produced excellent properties of surface hardness and temper softening resistance by forming precipitation of fine and spherodized carbides on a tempered marstensite matrix through the repeated process of carburization and diffusion after high temperature carburizing step 1. The cycle II performed two times carburizing/diffusion cycle (process) after super carburization at $1,000^{\circ}C$ had fine and spherodized carbides to subsurface $200{\mu}m$. In this case, the carbide was $(Fe,Cr)_3C$ and there was not any massive carbides. In the case of Cycle II, the roller pitting fatigue life had a 6.15 million cycles. It was improved 48% compared to normal gas carburizing treatment.

A Study on the Manufacturing and Physical Properties of Conducting Rubber (II) -Barium ferrite System Conducting Rubber- (전도성(導電性)고무의 제조(製造) 및 물성(物性)에 관한(關)한 연구(硏究) (II) -Barium Ferrite 혼합계(混合系) 도전성(導電性)고무-)

  • Lee, Young-Man;Yun, Ju-Ho;Choi, Sei-Young
    • Elastomers and Composites
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    • v.30 no.3
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    • pp.218-228
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    • 1995
  • To make filler loaded conducting rubber which has excellent electronical and physical properties, CR and NBR were mixed with barium ferrite(BaO.6Fe2O3). From the result of this study, vulcanization characteristics shows that curve is upgraded as the filler concentration increases and CR has higher torque than NBR. In physical properties, elongation being higher, modulus comes to decrease. Tear strength gradually decrease after showing the maximum point when is in the 100phr in CR. Resilience is not good to cause the increase in filler concentration. In electrical properties, conductivity becomes low when filler concentration increase. The increase of voltage makes a conductivity grown, but the rate change is weak. The influence of temperature hardly changes on increasing temperature. The morphology and the dispersion of a conductivity filler in vulcanizates through SEM were good. The more filler concentration increases, the shorter the particle interval is.

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Study on (n, α) reactions for the production of 51Cr, 89Sr, 99Tc, 131I, 133Xe, 137Cs and 153Sm radioisotopes used in nuclear medicine

  • Hallo M. Abdullah;Ali H. Ahmed
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3352-3358
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    • 2023
  • Nuclear medicine seems to be a decent choice of medicine in the recent decade. The radioactive isotopes 51Cr, 89Sr, 99Tc, 131I, 133Xe, 137Cs and 153Sm are extremely essential in nuclear medicine. The excitation functions of the 54Fe (n, α) 51Cr, 92Zr (n, α) 89Sr, 102Rh (n, α) 99Tc, 134Cs (n, α) 131I, 136Ba (n, α) 133Xe, 140La (n, α) 137Cs and 156Gd (n, α) 153Sm reactions were calculated in this study using the EMPIRE 3.2.3 and TALYS 1.95 nuclear codes. Additionally, the cross sections at 14-15 MeV were calculated using empirical formulae and the experimental data. The computer codes were compared to the experimental data and Empirical formulas as well as the evaluated data (TENDL 2021, JENDL 3.3, JENDL 5, JEFF 3.3, EAF 2010, CENDL 3.1, CENDL 3.2, ROSFOND 2010, FENDL 3.2 b, and BROND 3.1).

A Study On Heavy Metal Contamination in the Different Size Fractions of Deposited Road Particles(DRPs) (노면퇴적물의 입자 크기에 따른 중금속 오염에 관한 연구)

  • Kim, Boo-Gil;Lee, Byung-Cheol
    • Journal of Environmental Science International
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    • v.15 no.12
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    • pp.1171-1175
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    • 2006
  • Deposited road particles (DRPs) were analysed for heavy metal concentrations at four different roads in a city, Korea. The samples were collected using a roadway surface vacuum cleaning vehicle which was commonly used in collecting roadway surface particles. Six particle size ranges were analyzed separately for twelve heavy metal elements (Cd, Cr, Pb, Ni, Al, As, Co, Cu, Fe, Mn, Zn and Hg). At all sampling sites, the high concentration of the heavy metals occurred in the <74um particle size range, which conventional roadway cleaning vehicles do not remove efficiently. The Pb concentration significantly increased with decreasing particle size of DRPs, and other toxic heavy metals (Cd, Cr and Ni) also showed similar results. The heavy metal concentrations in the smaller size fraction of DRPs is important because they are contaminants that are preferentially transported by road runoff during rainfall.

전이금속촉매를 이용한 톨루엔의 제거에 따른 촉매산화 연구

  • 천태진;신장익;김혜진;김영은;최성우;이창섭
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2004.05a
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    • pp.46-48
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    • 2004
  • 현재 섬유산업에서 배출되는 톨루엔을 제어하기 위해 고가의 귀금속을 제외한 다양한 전이금속촉매를 사용하여 촉매산화반응을 모사가스로 평가하였다. 전이금속촉매의 톨루엔 촉매산화반응 및 표면특성을 요약 정리하면 다음과 같다. 반응온도 160~$640^{\circ}C$에서 톨루엔의 완전산화반응을 나타내었으며 이중 Cu와 Cr 촉매는 $340^{\circ}C$에서 99% 이상의 제어효율을 보여주는 활성이 우수한 촉매로 평가되었다. 또한 $­Al_2O_3$와 5%wt Cr/ $­Al_2O_3$의 FE­SEM을 측정한 결과 전이금속을 첨가 시 지지체 표면에 균일하게 분산되어 있음을 알 수 있었다.

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Corrosion behavior of separator for molten Cab -onate Fuel Cell (MCFC 분리판 부식거동에 관한 연구)

  • 이성일;김귀열
    • Journal of the Korea Safety Management & Science
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    • v.2 no.4
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    • pp.177-186
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    • 2000
  • The molten carbonate fuel cell has conspicuous features and high potential in being used as an energy converter of various fuels to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at $650^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti has been done in (62+38)mol % (Li+K) $CO_3$ melt at 923K by using. steady state polarization and electrochemical impedance spectroscopy method. It found that the corrosion current of these Febased alloys decreased with increasing Ti content, and this attribute to the formation of $LiCrO_2$ layer at the surface.

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Crack driving force prediction based on finite element analysis using standard models

  • Brnic, Josip;Vukelic, Goran;Turkalj, Goran
    • Structural Engineering and Mechanics
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    • v.44 no.5
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    • pp.601-609
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    • 2012
  • Effect of different crack sizes on fracture criterion of some engineering materials was investigated in this work. Using finite element (FE) method coupled with a newly developed algorithm, J-integral values for different crack sizes were obtained for single-edge notched bend (SENB) and compact type (CT) specimen. Specimens with initial a/W ratio from 0.25 to 0.75 varying in crack size in steps of 0.125 were investigated. Several different materials, like 20MnMoNi55, 42CrMo4 and 50CrMo4, usually used in engineering structure, were investigated. For one of mentioned materials, numerical results were compared with experimental and their compatibility is visible.

Advanced Powder Processing Techniques of Ti Alloy Powders for Medical and Aerospace Applications

  • Miura, Hideshi
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.323-331
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    • 2013
  • In this paper, two kinds of advanced powder processing techniques Metal Injection Molding (MIM) and Direct Laser Forming (DLF) are introduced to fabricate complex shaped Ti alloy parts which are widely used for medical and aerospace applications. The MIM process is used to strengthen Ti-6Al-4V alloy compacts by addition of fine Mo, Fe or Cr powders. Enhanced tensile strength of 1030 MPa with 15.1% elongation was obtained by an addition of 4 mass%Cr because of the microstructural modification and also the solution strengthening in beta phase. However, their fatigue strength was lower compared to wrought materials, but was improved by HIP. Subsequently, the effect of feeding layer height (FLH) on the characteristics of the DLF compacts was investigated. In the case of 100 ${\mu}m$ FLH, surface roughness was improved and nearly full density (99.8%) was obtained. Also, tensile strength of 1080 MPa was obtained, which is higher than the ASTM value.

The Crystallographic Properties of TiC Deposited on Different Substrate Steel by Chemical VaporDeposition (화학증착법에 의한 여러 가지 강들위에 증착된 TiC의 결정학적 특성)

  • 윤순길;김호기
    • Journal of the Korean Ceramic Society
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    • v.24 no.6
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    • pp.519-526
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    • 1987
  • TiC was deposited onto several substrate steels by the Chemical Vapor Deposition technique from TiCl4-CH4-H2 gas mixtures in the horizontal resistance furnace. Deposition rates and morphologies of the coatings were investigated with the carbon contents. Deposition thickness increased linearly with the deposition time in the Presence of CH4 gas. The various interlayers of coating by EDS and X-ray Diffraction were proved as Cr7C3 and Fe3C. Chromium contents did not affect the preferred orientation of TiC deposit. The deposition was controlled by a mass transport and a surface reaction in case of 1 wt% C-5.25 wt% Cr steel irrespective of deposition temperature.

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