• Journal of the Korean Magnetics Society
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• v.18 no.4
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• pp.147-153
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• 2008

It has been well-known that the Fe/GaAs heterostructure has a small lattice mismatch of 1.4% between Fe and GaAs, and the Fe layer is grown epitaxially on the the GaAs substrate. There are rich physics are observed in the GaAs/Fe interface, and the spininjection is actively studied due to its potential applications for spintronics devices. We fabricated Fe wedge layer in the thickness range $0{\sim}3.4$ nm on the GaAs(100) surface with 5-nm thick Au capping layer. The magnetic anisotropy of the Fe/GaAs system was investigated by employing Brillouin light scattering(BLS) measurements in this study. The spin wave excitation of Fe layer was studied as the function of intensity and the in-plane angle of external magnetic field, and thickness of Fe layer. Also these various dependences were analyzed with analytic expression of spin wave surface mode in order to determine the magnetic anisotropies. It has been found that the GaAs/Fe/Au system has additional uniaxial magnetic anisotropy, while the bulk Fe has biaxial anisotropy. The uniaxial anisotropy shows increasing dependency respected to decreasing thickness of Fe layer while biaxial anisotropy is reduced with Fe film thickness. This result allows the analysis that the uniaxial anisotropy is originated from interface between GaAs surface and Fe layer.

• Analytical Science and Technology
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• v.5 no.1
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• pp.91-96
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• 1992

A simple and cheap AC voltammeter was manufactured in our lab. This instrument consists of a DC function generator and a lock-in amplifier. We tested this instrument in some chemical systems. Our data, CV voltammogram and AC voltammogram, obtained form using a Pt working electrode in 1M $H_2SO_4$ and a reversible system of $1{\times}10^{-3}M$ ${Fe(CN)_6}^{3-}$ proved our system works well. The quantitative result of iodine is also obtained.

• Journal of the Korean Chemical Society
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• v.37 no.12
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• pp.1053-1059
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• 1993

The determination of iron(Ⅱ), iron(Ⅲ) and total iron was studied by differential-pulse and Tast polarography in 0.1 M acetate buffer solution at pH 4.60, Half wave potentials of iron(Ⅱ)-DTPA and iron(Ⅲ)-DTPA complexes were -0.150V vs. SCE reference electrode. In the presence of DTPA the redox process of iron(Ⅱ) and iron(Ⅲ) was reversible. Linear calibration plots were obtained for iron(Ⅱ) and iron(Ⅲ) concentration of 0.2∼1.0 mM. The detection limits of iron(Ⅱ) and iron(Ⅲ)by Tast polarographic method were 0.05 mM and 0.07 mM, respectively.

• Analytical Science and Technology
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• v.12 no.6
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• pp.515-520
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• 1999

The spectrophotometric determination of Al(III) with thorin have been investigated. The optimum condition of pH, concentration of ligand and surfactant, and stability were evaluated. The thorin ligand offers selective separation of Al(III) from sample solution containing Fe(III), Ni(II), Cu(II), Pb(II) and Cu(II). Various surfactants were tested and Triton X-100 showed the best stability and the maximum absorbance in an aqueous solution of Al(III)-Thorin-Triton X-100 complex appears about 526 nm. The method was applied for the determination of Al(III) in mixed sample solution. Separation and preconcentration was performed with a short column filled with resorcinol-formaldehyde resin. Control of the pH during the column operation is essential because the adsorption capacities are very sensitive to change in pH. Their separation was carried out in 0.2 M acetic acid-sodium acetate buffer solution (pH 4.5) and 1.0 M $HNO_3$media.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.3
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• pp.405-412
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• 2013

This paper reports the steady-state stresses within the heat affected zone (HAZ) of a welded straight pipe subject to creep. The creep constants and exponent are varied systematically to see the effect of various mismatches in creep properties on the steady-state creep stresses, via detailed two-dimensional finite element (FE) creep analyses. The weldments consist of the base metal and weld metal with the HAZ, which are characterized using the idealized power creep laws with the same creep exponent. The internal pressure and axial loading are considered to see the effect of the loading mode. To quantify the creep stresses, a creep mismatch factor is introduced as a function of the creep constants and exponent. It is concluded that the ratio of the section-averaged stresses for a mismatched case to those for an evenmatched case are linearly dependent on the mismatch factor. The results are compared with the FE results, including the Type IV region, as well as the R5 procedure.

• Resources Recycling
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• v.25 no.6
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• pp.65-72
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• 2016

We studied a selective recovery condition of vanadium (V) from FALL (Fly Ash Leach Liquor) produced at a fossil fuel power station using heavy oil. By applying a spectroscopy to quantify the V in a sample, we identified a concentration range V interfered by on presence of metals such as Ni, Fe Also, the optimal vanadium precipitation rate according to the amount of 5.0M $NH_3$ loaded to the sample, solution pH and stirring time. As a result of the experiment, the maximum selective recovery ratio of V was achieved to be higher than 91.5% when the stirring duration was less than 1 minute at pH 7.0, and $25^{\circ}C$.

• Journal of the Korean Chemical Society
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• v.51 no.1
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• pp.14-20
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• 2007

The anodic dissolution of electrodeposited iron group elements (Fe, Co, Ni) were studied in phthalate buffer solution. The pH dependence of the corrosion potential, the corrosion current and Tafel slope was measured for each element. Based on the electrochemical parameters including Tafel slopes, we proposed the redox mechanism of the corrosion and the passivation. The adsorption of various phthalate species on the electrodeposited iron group elements seemed to be affected the corrosion mechanisms.

• Analytical Science and Technology
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• v.24 no.3
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• pp.231-235
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• 2011

A spectrofluorimetric method for the determination of EDTA in real samples such as mayonnaise, powder detergent and cleansing cream with tiron (4,5-dihydroxy-1,3-benzenedisulfonic acid) as a fluorimetric reporter was developed. When tiron is chelated with Cu(II), the fluorescent intensity is decreased by a quenching effect. However, when Cu(II)-tiron chelate reacts with EDTA, fluorescent intensity is increased as tiron is released. Several experimental conditions such as pH of the sample solution, the amount of Cu(II), the amount of tiron, heating temperature and heating time were optimized. Fe(III) interfered more seriously than any other ions, interference of Fe(III) could be disregarded, because Fe(III) was scarcely contained in selected real samples. The linear range of EDTA was from $8.0{\times}106{-8}\;M$ to $2.0{\times}10^{-6}\;M$. With this proposed method, the detection limit of Fe(III) was $5.2{\times}10^{-8}\;M$. Recovery yields of 92.7~99.3% were obtained. Based on experimental results, it is proposed that this technique can be applied to the practical determination of EDTA.

• Applied Chemistry
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• v.15 no.2
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• pp.113-116
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• 2011

A sensitive and selective determination method of Fe(II) ion by luminol-H₂O₂ system using a chelating reagent has been presented. A metal ion-chelating ligand complex such as Fe(II)-diethylenetriamine pentaacetic acid (DTPA) produced higher chemiluminescence (CL) intensity as well as longer lifetime in luminol-H₂O₂ system than metal exist as free ions. Furthermore, the catalytic activity of Cu(II) and Pb (II) complexes with chelating reagents in luminol-H₂O₂ system was lost since chelating reagents act as a masking agent although free Cu(II) and Pb(II) ions have high catalytic activity. On the optimized conditions, the calibration curve of Fe(II) ion was linear over the range from 1.0×10^-7 to 2.0×10^-5 M with correlation coefficient of 0.996. The detection limit was calculated to be 4.0×10^-8 M.

• Journal of Life Science
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• v.17 no.2 s.82
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• pp.266-271
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• 2007

Bisphenol A (BPA) has been widely used as a monomer for production of epoxy resins and polycarbonate plastics. The annual production of BPA exceeds 640,000 metric tons in worldwide. BPA, a suspected phenolic endocrine disrupter, is moderately soluble and frequently detected in industrial wastewater. To date, HPLC and GC has been used for BPA analysis. However, HPLC and GC-analysis need high operation lost, experts, and an elaborate pre-treatment of samples, and is difficult to apply on-time and mass analysis. Therefore, simple, mass and rapid detection of BPA in environments is necessary. In the present study, spectrophotometric method of BPA quantification was developed. Based on blue-color product formation with BPA and ferric chloride/ferricyanide under the optimized conditions, the standard curve was acquired $({\lambda}_{750}=0.061\;BPA\;[{\mu}M]+0.07155,\;R^2=0.992)$. Using an established method, the BPA contents in the soil extract, and different water samples and living products, including disposable syringe, cup and plastic tube, were analyzed. The results suggested that the method is useful for BPA determination from different massive samples. Since the BPA metabolites, nontoxic 4-hydroxyacetophenone or 4-hydroxybenzaldehyde, did not form blue-color product, this method is also useful to screen a microorganism for BPA bioremediation.