• Title/Summary/Keyword: Extraction constant

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Effect of Cu(II) and Al(III) on the Extraction and Separation of Pt(IV) and Pd(II) from Concentrated Hydrochloric Acid Solution with Alamine336 (진한 염산용액에서 구리(II)와 알루미늄(III)이 Alamine336에 의한 백금(IV)과 팔라듐(II)의 추출 및 분리에 미치는 영향)

  • Lee, Manseung;Ahn, Jonggwan;Sun, Panpan
    • Korean Journal of Metals and Materials
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    • v.48 no.2
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    • pp.148-153
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    • 2010
  • The effects of Cu(II) and Al(III) on the extraction and separation of Pt(IV) and Pd(II) have been investigated in a mixed chloride solution using Alamine336 as the extractant. In the HCl concentration range of 1 to 5 M, more than 99% of Pt and Pd could be extracted by Alamine336 from all of the mixed chloride solutions investigated in this study. Lower HCl concentration led to a higher separation factor between Pd and Pt when Alamine336 concentration was constant. Extraction percentage of Cu increased with the increase of HCl concentration, while that of Al was nearly constant at 33% in our experimental range. The optimum conditions to extract Pt and Pd from Cu or Al and the separation factor under these conditions were obtained.

Parameter Extraction of DQ-Axis Inductance and Back-EMF Constant For IPM Type Motors Based on Nonlinear Finite Element Analysis (비선형 효과를 고려한 IPM형 전동기의 DQ축 인덕턴스 및 역기전력상수 파라미터 추출)

  • Choi, Hong-Soon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.3
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    • pp.519-523
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    • 2007
  • In this paper, we propose a precise parameter extraction of interior permanent magnet (IPM) motors based on finite element analysis. For the calculation of the two-axis inductances Ld and Lq, the slotting effect and cross magnetization due to torque angle are considered. It is examined that back electro-motive force (BEMF) constant is affected by the magnetic saturation in different ways dependent on motor types. Numerical analyses and some measurements are performed for a spoke type and a flux barrier type IPM motors

Transport of Zinc Ion in a Contained Liquid Membrane Permeator with Two Micro-Porous Films (지지막을 이용하는 액막 추출기 내에서 아연 이온의 이동)

  • 주창식;이석희;이민규;홍성수;하홍두;정석기
    • Journal of Environmental Science International
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    • v.9 no.2
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    • pp.159-164
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    • 2000
  • For the purpose of development of a liquid membrane permeator which separates metal ions from aqueous solutions continuously and effectively, a continuous membrane permeator with the membrane solution trapped between extraction and stripping phases by two micro-porous hydrophilic films was manufactured. Experimental researches on the separation of zinc ion from aqueous solutions were performed in the liquid membrane permeator with 30 vol % D2EHPA solution in kerosine as liquid membrane. As results, the liquid membrane permeator separates zinc ion from aqueous solutions continuously and effectively in the wide range of operating conditions. A simple mass transfer rate model using equilibrium constant of the extraction reaction for the system used were proposed, and the model was compared with experimental results of separation of zinc ion in the permeator. And the effects of operating factors, such as space time, pH of extraction solution, extraction temperature, on the separation rate of zinc ion in the permeator were experimentally examined.

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An Experimental Study on the Temperature Variation in Heat Storage Zone in the Honeycomb-covered Small Saltless Solar Pond (벌집형 소형 태양열 저장수조의 열저장층 내의 온도변화에 관한 실험적 연구)

  • Pak, Ee-Tong;Hwang, Sung-Il;Hahn, Dong-Kyun
    • Solar Energy
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    • v.9 no.1
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    • pp.30-35
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    • 1989
  • This paper dealt with an experiments on temperature vairation in the heat storage zone due to change of vertical location (height) of sink diffuser and flow extraction in small saltless solar pond ($0.5{\times}0.5{\times}1.0M$), and the honeycomb device for this experimental purpose consisted of one-tired, sealed, and air filled by honeycomb panels. As results of experiments, 1) The storage zone was formed under lower region below the honeycomb device. 2) The higher vertical location of sink diffuser was placed, the more mixing phenomenon increased in the pond at steady flow extraction. 3) The more flow extraction increased, the more mixing phenomenon decreased at constant heat exchanger and variable flow extraction.

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Active components delivery rate from acrylic resin maxillary surgical obturator: Part I

  • Al-Kaabi, Arshad;Hamid, Mohammed A.
    • Advances in materials Research
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    • v.9 no.2
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    • pp.109-114
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    • 2020
  • The purpose of this study was to observe the trend of compounds release from acrylic resin oral prosthesis when used for drug delivery as well as a restoration. In this study, 10 specimens of heat-cured polymethylmethacrylate material were prepared and loaded with methylene blue biological stain. The specimens were then submerged in vials with 5 ml distilled water for 24 hours. The extraction procedure continued for 4 days, each day the specimens were immersed in another 5 ml distilled water vial. All extracted solutions were analyzed by visible light spectroscopy for absorbance comparison. The statistical results showed that the absorbance values were significantly different in the first day of extraction than the following days. However, there was no statistical difference among the 2nd, 3rd and 4th days of extraction. Biological stain loading to acrylic resin at the mixing stage, and then after extraction in distilled water, showed a burst release during the first day followed by a constant release during the following few days.

Parameter extraction and signal transient of IC interconnects on silicon substrate (실리콘기판 효과를 고려한 전송선 파라미터 추출 및 신호 천이)

  • 유한종;어영선
    • Proceedings of the IEEK Conference
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    • 1998.06a
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    • pp.871-874
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    • 1998
  • A new transmission line parameter extraction method of iC interconnects on silicon substrate is presented. To extract the acurate parameters, the silicon substrate effects were taken into account. Since the electromagnetic fields under the silicon substrate are propagated with slow wave mode, effective dielectric constant and different ground plane with the multi-layer dielectric structures were employed for inductance and capacitance matrix determination. Then accurate signal transients simulation were performed with HSPICE by using the parameters. It was shown that the simulation resutls has an excellent agreement with TDR/TDT measurements.

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Reactive Extraction of Organic Acid with Amine Extractant, I. (A Study on the Effects of Extractant and Solvent on the Degree of Extraction in Reactive Extraction of Organic Acid) (아민 추출제에 의한 유기산의 반응추출(I) (유기산의 반응추출시 추출도에 미치는 추출제 및 용매의 영향에 관한 연구))

  • Ryu, Oon-Hyung;Lee, Han-Seob;Yoo, Chul-Hwi;Kim, Yong-Yeul;Kang, An-Soo
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.203-213
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    • 1996
  • In physical and reactive extraction system using equilibrium extraction equipment, the effects of extractants, concentration of extractant, and solvent on the degree of extraction were investigated. The organic acids used were acrylic acid and metacrylic acid. Extractants were n-octylamine(OA), di-n-octylamine(DOA), tri-n-octylamine(TOA) and tri-octylmetyl ammonium chloride(TOMAC ; Aliquat 336). We found that the degree of extraction for reactive extraction was 2~9 times than that for physical extraction and that effect of extractants on the degree of extraction of organic acid was the order of OA

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Characterization of the Yellow Croaker Larimichthys polyactis muscle Oil Extracted with Supercritical Carbon Dioxide and an Organic Solvent

  • Lee, Joo-Hee;Asaduzzaman, A.K.M.;Yun, Jun-Ho;Yun, Jun-Hyun;Chun, Byung-Soo
    • Fisheries and Aquatic Sciences
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    • v.15 no.4
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    • pp.275-281
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    • 2012
  • Yellow croaker Larimichthys polyactis muscle oil was extracted using an environmental friendly solvent, supercritical carbon dioxide (SC-$CO_2$), in a semi-batch flow extraction process. SC-$CO_2$ was applied at temperature $35^{\circ}C$ to $45^{\circ}C$ and $150^{\circ}C$ to $250^{\circ}C$ bar of pressure. The flow rate of $CO_2$ (27.79 g/min) was constant throughout the entire 1.5 h extraction period. The oil extraction yield was influenced by the physical properties of SC-$CO_2$ at different temperatures and pressures. The extracted oil was analyzed by gas chromatography to determine the fatty acid composition. According to our results, the SC-$CO_2$ extracted oil was high in eicosapentaenoic acid and docosahexaenoic acid. In addition, the SC-$CO_2$ extracted oil showed greater stability than n-hexane extracted oil based on the peroxide value and acid value. Thus, the quality of yellow croaker oil obtained by SC-$CO_2$ extraction was slightly higher than that of oil obtained by n-hexane extraction.

Correlation Between Arrhenius Equation and Binding Energy by X-ray Photoelectron Spectroscopy

  • Oh, Teresa
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.6
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    • pp.329-333
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    • 2013
  • SiOC films were prepared by capacitively coupled plasma chemical vapor deposition, and the correlation between the binding energy by X-ray photoelectron spectroscopy and Arrhenius equation for ionization energy was studied. The ionization energy decreased with increase of the potential barrier, and then the dielectric constant also decreased. The binding energy decreased with increase of the potential barrier. The dielectric constant and electrical characteristic of SiOC film was obtained by Arrhenius equation. The dielectric constant of SiOC film was decreased by lowering the polarization, which was made from the recombination between opposite polar sites, and the dissociation energy during the deposition. The SiOC film with the lowest dielectric constant had a flat surface, which depended on how carbocations recombined with other broken bonds of precursor molecules, and it became a fine cross-linked structure with low ionization energy, which contributed to decreasing the binding energy by Si 2p, C 1s electron orbital spectra and O 1s electron orbital spectra. The dielectric constant after annealing decreased, owing to the extraction of the $H_2O$ group, and lowering of the polarity.

Composite copper powder from Kelex 100 (Kelex100로부터 구리입자 분말 합성)

  • ;P.R Taylor
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.131-137
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    • 1998
  • A composite copper coated powder was generated by pressure hydrogen stripping copper from Kelex 100 solvent extractant in the presence of silica powder. Within the limitation of solvent extraction under constant conditions, both loading level and stripping rate were reproducible. The stripping copper kinetics are reduced from a divalent state to a metallic state and then deposited on the surface of the silica powder. Copper nucleates heterogeneously on the seed particles. They are giving an agglomerated and non - uniform powder.

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