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The Effects of Sulfur on the Catalytic Reaction between Carbon Monoxide and Nitric Oxide on Polycrystalline Platinum Surface (다결정 백금표면에서의 일산화탄소와 일산화질소의 촉매반응에 미치는 황의 영향)

  • Park, Youn-Seok;Kim, Young-Ho;Lee, Ho-In
    • Applied Chemistry for Engineering
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    • v.1 no.2
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    • pp.215-223
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    • 1990
  • The effects of sulfur on the catalytic reaction between CO and NO on polycrystalline Pt surface, which is very important in the development of catalyst for automobile exhaust gas control, have been studied using thermal desorption spectrometry(TDS) under ultra-high vacuum(UHV) conditions. Sulfur weakened both the adsorptions of CO and NO by direct site blocking and indirect electronic effect. S(a) desorbing below 800 K gave little effect on reaction activity whereas S(a) desorbing above 800 K, which adsorbs as an atomic state, gave much effect on it. The adsorbed sulfur existed on the surface of platinum in the form of islands, and also reduced the adsorption energies of adsorbates by the long-ranged electronic effect. The platinum catalyst in the reaction between CO and NO was poisoned selectively by S(a), poisoning firstly the active sites of this reaction.

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Study of Time-to-go Polynomial Guidance Law with Considering Acceleration Limit (가속도 제한을 고려한 Time-to-go 다항식 유도 법칙 연구)

  • Lee, Chang-Hun;Kim, Tae-Hun;Tahk, Min-Jea
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.38 no.8
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    • pp.774-780
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    • 2010
  • This paper deals with the choice of guidance gain for the time-to-go polynomial (POLY) guidance law when the acceleration limit is existed. POLY is derived based on the assumption that guidance commands are formed by a time-to-go polynomial function. The main characteristic of POLY is that any positive values can be used for its guidance gain. For this reason, it is ambiguous to choose a proper guidance gain. To relieve this difficulty, we firstly derive the closed-form solution of acceleration command and figure out the relationship between the maximum acceleration and guidance gain. From this analysis, we provide a guideline for choosing a guidance gain which satisfies the desired acceleration limit. Finally, the proposed method is demonstrated by simulation study.

Stress Change Varying with Hole Place of RC Column (유공위치 변경에 따른 RC기둥의 내력변화에 관한 실험적 연구)

  • Son, Ki-Sang
    • Journal of the Korean Society of Safety
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    • v.21 no.2 s.74
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    • pp.70-79
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    • 2006
  • many plumbing system are needed in the ceiling of the building as it becomes advanced more and more. This leads to make effective space between ceiling level and slab less. Also, piping system is not suitably arranged and operated if it is bent around the columns which they are a lot. But this system can be more effective if it passes through the columns directly. Most people think that those columns should not be damaged with such as holes. But actually this is existed in a hotel building in switzerland. This study is to fing out how much capacity the columns become damaged and low using model size of $20cm{\times}30cm$ rectangular section, and 160cm long, in the structural test. it's compressive strength is focused on $240kg/cm^{2}$ design strength, commonly used in korea. Compressive test for them was done at Hanyang University using UTM one thousand tone(1000t) capacity. Variable numbers for the study are one hole of dia 3cm with distance 20cm or 40cm, two holes of dia 3cm with 20cm and 40cm distance, one hole of dia 5cm with distance 20cm and 40cm, two holes of dia 5cm with 20cm and 40cm distance, me eccentric hole with 20cm and 40cm distance, Normal(without hole). two test specimens of each variable are made for the test. ED5H20 capacity was 16.7% decreased, compared to normal one. While ED5H40 distant 40cm from the end of column top showed 19.5% capacity decrease, compared to normal one. Strain of ED5H20 diameter 5cm, in distance of 20cm form the top of the column was less 5% than the one of diameter 3cm. Finally, conclusions are that in case of hole diameter 3cm, located at 20cm from the end of the column top, capacity was decreased down to 3, percent only compared to the same diameter hole with 20cm distant from the end of it.

Biological Activity of Tumor Necrosis Factor-α Secreted from Smooth Muscle Cell Overexpressing FADD (FADD 과발현 평활근세포에서 분비하는 Turner Necrosis Factor-α의 작용)

  • Kim, Sun-Mi;Lee, Kyeong-Ah;Kim, Koan-Hoi
    • Journal of Life Science
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    • v.17 no.1 s.81
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    • pp.45-50
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    • 2007
  • This study investigated biological activity of tumor necrosis factor $(TNF)-\alpha$ secreted from smooth muscle cell (SMC) destined for death by expressing Fas associated death domain containing protein (FADD) (FADD-SMC) when the cells are grown without tetracycline in culture medium. In the absence of tetracycline the FADD-SMC secreted approximately 1000 pg/ml $TNF-\alpha$, whereas hardly detectable amount of the cytokine existed in the presence of tetracycline. The culture medium collected from the FADD-SMC grown in the absence of tetracycline increased phosphorylated form of p38 MAPK and up-regulated nuclear factor kappa B (NF-kB). The medium collected without tetracycline also caused death of L929 cells. Depletion of $TNF-\alpha$ with the soluble TNF receptor (sTNFR) inhibited the phosphorylation of p38 MAPK, the up-regulation of NF-kB activity and the death activity of the medium collected from FADD-SMC in the absence of tetracycline. These results indicate that $TNF-\alpha$ secreted from SMC undergoing death is biologically active and can affect cellular function.

Nitrogen을 도핑시킨 Ge-Sb-Te 박막의 광전자 및 광흡수 분광학 연구

  • Sin, Hyeon-Jun;Jeong, Min-Cheol;Kim, Min-Gyu;Lee, Yeong-Mi;Kim, Gi-Hong;Jeong, Jae-Gwan;Song, Se-An;Sun, Zhimei
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.186-186
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    • 2013
  • Nitrogen doped Ge-Sb-Te (N-GST) thin films for phase change random access memory (PRAM) applications were investigated by synchrotron-radiation-based x-ray photoelectron spectroscopy and absorption spectroscopy. Nitrogen doping in GST resulted in more favorable N atoms' bonding with Ge atoms rather than with Sb and Te atoms [1,2], which explains the higher phase change transition temperature than that of undoped Ge-Sb-Te thin film. Surprisingly, it was noticed that N atoms also existed in the form of molecular nitrogen, $N_2$, which is detrimental to the stability of the GST performance [3]. N-doped GST experimental features were also supported by ab-initio molecular dynamic calculations [2]. References [1] M.-C. Jung, Y. M. Lee, H.-D. Kim, M. G. Kim, and H. J. Shin, K. H. Kim, S. A. Song, H. S. Jeong, C. H. Ko, and M. Han, "Ge nitride formation in N-doped amorphous Ge2Sb2Te5", Appl. Phys. Lett. 91, 083514 (2007). [2] Zhimei Sun, Jian Zhou, Hyun-Joon Shin, Andreas Blomqvist, and Rajeev Ahuja, "Stable nitride complex and molecular nitrogen in N doped amorphous Ge2Sb2Te5", Appl. Phys. Lett. 93, 241908 (2008). [3] Kihong Kim, Ju-Chul Park, Jae-Gwan Chung, and Se Ahn Song, Min-Cherl Jung, Young Mi Lee, Hyun-Joon Shin, Bongjin Kuh, Yongho Ha, Jin-Seo Noh, "Observation of molecular nitrogen in N-doped Ge2Sb2Te5", Appl. Phys. Lett. 89, 243520 (2006).

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Chemical Species of Uranium and Vanadium in Organic Acid Media (유기산용액에서 우라늄과 바나듐의 화학종에 관한 연구)

  • Ki-Won Cha;Cong-Sik Yu;Jong-Hun Kim
    • Journal of the Korean Chemical Society
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    • v.29 no.6
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    • pp.615-622
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    • 1985
  • The chemical species formed by uranium and vanadium and their equilibria have been investigated in the various concentrations of oxalic and acetic acids by the ion exchange chromatography and UV-Vis spectrophotometry. Uranyl and vanadyl ions seem to be form the complex as $UO_2(C_2O_4)_2=$, $UO_2(C_2O_4)_3^{4-}$ and $VO_2(C_2O_4)-2^{3-}$ respectively in the concentration range of 0.005∼0.05M oxalic acid concentration. In the case of acetic acid the equilibria of $UO_2^{2+}+3Ac^-=UO_2(Ac)_3^-$ and $VO_2^++2Ac^-=VO_2(Ac)_2^-$ were existed individually according to the increase of acetic acid concentration.

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Film Properties of Cold Blending Emulsion Between Poly(vinyl Acetate) and Poly(vinyl acetate-co-ethylene) Emulsion (Poly(vinyl acetate)와 Poly(vinyl acetate-co-ethylene) 에멀젼을 이용한 상온 블렌드 에멀젼의 Film 특성)

  • Kim, Ho-Young;Yoo, Sung-Hee;Choi, Yong-Hae
    • Journal of Adhesion and Interface
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    • v.12 no.4
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    • pp.117-124
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    • 2011
  • This study was made on the poly(vinyl acetate) (PVAc) and poly(vinyl acetate- ethylene) (VAE) emulsion polymer blend which used PVA as protective colloid, and the PVA used as protective colloid was existed in each emulsion film before blend and even in the film after the blend consecutively. It makes us expect excellent adhesive power among particles that form the blend. Emulsion blends with different Tg are important target of concerning, and PVAc/VAE emulsion blend suggested simple and excellent research method. As a result of blend, elongation was lowered by the increase of PVAc, and the plasticizer used in making PVAc affected on the Tg of blend and lowered Tg of VAE emulsion, and the synergy effect of two blends was seen for the tensile strength, thermal resistance, and adhesive strength.

Harmonics Control of Electric Propulsion System using Direct Torque Control (직접벡터제어방식을 사용하는 전기추진시스템의 고조파 제어)

  • Kim, Jong-Su;Oh, Sae-Gin
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.13 no.12
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    • pp.2618-2624
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    • 2009
  • Harmonics (or distortion in wave form) has always existed in electrical power systems. It is harmless as long as its level is not substantial. However, with the recent rapid advancement of power electronics technology, so-called nonlinear loads, such as variable frequency drives for motor power/speed control, are increasingly finding their way to shipboard or offshore applications. In this paper a new approach to direct torque control (DTC) of induction motor drive is presented. In comparison with the conventional DTC methods the inverter switching frequency is constant and is dramatically increased, requiring neither any increase of the sampling frequency, nor any high frequency dither signal. The well-developed space vector modulation technique is applied to inverter control in the proposed DTC-based induction motor drive system, thereby dramatically reducing the current harmonics. As compared to the existing DTC approach with constant inverter switching frequency, the presented new approach does not invoke any concept of deadbeat control, thereby dramatically reducing the computations.

Homologous Expression and T3SS-Dependent Secretion of TAP-Tagged Xo2276 in Xanthomonas oryzae pv. oryzae Induced by Rice Leaf Extract and Its Direct In Vitro Recognition of Putative Target DNA Sequence

  • Kim, Seunghwan;Nguyen, Thi-Dieu-Hanh;Lee, Joohee;Hong, Myoung-Ki;Pham, Tan-Viet;Ahn, Yeh-Jin;Lee, Byoung-Moo;Han, Ye Sun;Kim, Dong-Eun;Kim, Jeong-Gu;Kang, Lin-Woo
    • Journal of Microbiology and Biotechnology
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    • v.23 no.1
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    • pp.22-28
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    • 2013
  • Xo2276 is a putative transcription activator-like effector (TALE) in Xanthomonas oryzae pv. oryzae (Xoo). Xo2276 was expressed with a TAP-tag at the C-terminus in Xoo cells to enable quantitative analysis of protein expression and secretion. Nearly all TAP-tagged Xo2276 existed in an insoluble form; addition of rice leaf extracts from a Xoosusceptible rice cultivar, Milyang23, significantly stimulated secretion of TAP-tagged Xo2276 into the medium. In a T3SS-defective Xoo mutant strain, secretion of TAPtagged Xo2276 was blocked. Xo2276 is a Xoo ortholog of Xanthomonas campestris pv. vesicatoria (Xcv) AvrBs3 and contains a conserved DNA-binding domain (DBD), which includes 19.5 tandem repeats of 34 amino acids. Xo2276- DBD was expressed in E. coli and purified. Direct in vitro recognition of Xo2276-DBD on a putative target DNA sequence was confirmed using an electrophoretic mobility shift assay. This is the first study measuring the homologous expression and secretion of Xo2276 in vitro using rice leaf extract and its direct in vitro binding to the specific target DNA sequence.

A Study on the Development of an Efficient Training Education System for Merchant Marine Officers (효율적인 해기사 실습교육제도의 개발에 관한연구)

  • 정연철;박진수;김성규
    • Journal of the Korean Institute of Navigation
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    • v.14 no.4
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    • pp.53-70
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    • 1990
  • Much efforts have been made to improve the training education system for last decades. however, it still leaves much room form improving the system. The reason for this is that the have been many changes in given educational conditions, national and international, and that there existed the lack of training facilities on shore and the limits of capacity on the training ship. The existing program adopts a straight-through system of which the course has to be completed at same time, and also forces students to study the course, disregarding their aptitude for sea life. Consequently, the program resulted in frustrating the learning desire of some students and, as a consequence, in deteriorating the quality of the entire training education. This paper aims to develop an efficient training program including curriculla by the literature survey and the teaching and sea experiences on the training ship "HANBADA" and merchant ships, where the authors have been for many years. Compared with the existing one, the new training model suggested in this paper has some advantages as follows : First, the new model adopts multi-state system which consists of various short-term training courses according to each purpose. This system will be helpful for student to find their aptitude for sea life earlier and to understand classes of major subjection shore. Second, the model includes new curriculla which consist of core subjects (for example, navigation, marine operation, marine transportation, watch keeping and nautical English for deck cadets and internal and external combustion engine, auxiliary machinery, electric and electronics and engine maintenance for engine cadets), by incorporating existing 20 subjects in 5 subjects. These curriculla may contribute to embodying the characteristics of training education where the above mentioned subjects must be linked with each other. In order to implement this new training model efficiently and effectively, the following prerequisties must be prepared : $\circled1$ The contents of each subject included in the new model should be systematically developed. $\circled2$ The educational schedule should be adjusted according to the new model.new model.

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