• Title/Summary/Keyword: Excitation temperature

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Effects of Substrate and Annealing Temperatures on the Properties of SrWO4:Dy3+, Eu3+ Phosphor Thin Films (기판 및 열처리 온도에 따른 SrWO4:Dy3+, Eu3+ 형광체 박막의 특성)

  • Kim, Jungyun;Cho, Shinho
    • Korean Journal of Materials Research
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    • v.26 no.10
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    • pp.577-582
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    • 2016
  • $Dy^{3+}$ and $Eu^{3+}$-codoped $SrWO_4$ phosphor thin films were deposited on sapphire substrates by radio frequency magnetron sputtering by changing the growth and thermal annealing temperatures. The results show that the structural and optical properties of the phosphor thin films depended on the growth and thermal annealing temperatures. All the phosphor thin films, irrespective of the growth or the thermal annealing temperatures, exhibited tetragonal structures with a dominant (112) diffraction peak. The thin films deposited at a growth temperature of $100^{\circ}C$ and a thermal annealing temperature of $650^{\circ}C$ showed average transmittances of 87.5% and 88.4% in the wavelength range of 500-1100 nm and band gap energy values of 4.00 and 4.20 eV, respectively. The excitation spectra of the phosphor thin films showed a broad charge transfer band that peaked at 234 nm, which is in the range of 200-270 nm. The emission spectra under ultraviolet excitation at 234 nm showed an intense emission peak at 572 nm and several weaker bands at 479, 612, 660, and 758 nm. These results suggest that the $SrWO_4$: $Dy^{3+}$, $Eu^{3+}$ thin films can be used as white light emitting materials suitable for applications in display and solid-state lighting.

The use of spectroscopic Ellipsometey for the observation of diamond thin film growth by microwave plasma chemical vapor deposition (마이크로웨이브 플리즈마 화학기상증착에 의한 다이아몬드 박막의 성장 관찰을 위한 분광 Ellipsometry의 이용)

  • 홍병유
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.2
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    • pp.240-248
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    • 1998
  • The plasma chemical vapor deposition is one of the most utilized techniques for the diamond growth. As the applications of diamond thin films prepared by plasma chemical vapor deposition(CVD) techniques become more demanding, improved fine-tuning and control of the process are required. The important parameters in diamond film deposition include the substrate temperature, $CH_4/H_2$ gas flow ratio, total, gas pressure, and gas excitation power. With the spectroscopic ellipsometry, the substrate temperature as well as the various parameters of the film can be determined without the physical contact and the destructiveness under the extreme environment associated with the diamond film deposition. It is introduced how the real-time spectroscopic ellipsometry is used and the data are analyzed with the view of getting the growth condition and the accompanied features for a good quality of diamond films. And it is determined the important parameters during the diamond film growth, which include the final sample will be measured with Raman spectroscopy to confirm the diamond component included in the film.

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The Behavior Variation of the Ion Viscosity and the Compressive Strength of the Seawater and Freshwater Flooded Chlorosulfonated Polyethylene After Accelerated Thermally Ageing (가속 열화 후 해수 담수 침지된 Chlorosulfonated Polyethylene의 이온 점도와 압축 강도의 특성 변화)

  • Hong, So Young;Kim, Min Ju;Jeong, Eun Mi;Kim, Jin Pyo;Shin, Yong Deok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.6
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    • pp.490-495
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    • 2019
  • This study performs the thermal aging of chlorosulfonated polyethylene (CSPE) for 807.36 and 1,614.48 hours at $110^{\circ}C$, which is equivalent to 40 and 80 years of aging at $50^{\circ}C$ in nuclear power plants, respectively. Flat-type CSPEs were soaked in seawater for five days and then dried for five days at room temperature. Furthermore, the soaked CSPEs were cleaned for 5 days with fresh water and dried for 1,100 days at room temperature. Through this process, the log IV of the CSPEs decreases, whereas the dissipation factor of the CSPEs increases as thermally accelerated aged years increase at the measured frequency. Although the phase degree of the response voltage versus excitation voltage of the CSPEs increases, that of the response current versus excitation voltage decreases with the thermally accelerated aging. The thermal conductivity of the CSPEs increases slightly, but the thermal diffusivity does not vary with the thermally accelerated aged year increase. The displacement of the compressive strength of the CSPEs decreases gradually as the thermally accelerated aged years increase.

Variability Analysis of Dynamic Characteristics in Rubber Engine Mounts Considering Temperature Variation (온도변화를 고려한 고무엔진마운트의 동특성 변동성 해석)

  • Hwang, In Seong;Ahn, Tae Soo;Lee, Dooho
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.23 no.6
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    • pp.553-562
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    • 2013
  • Vehicle vibrations arise from engine and road surface excitations. The engine mount system of a passenger car sustains the engine weight and insulates the excitation force from the engine system. The dynamic properties of viscoelastic material used for the vehicle engine mounts have large variation due to environmental factors such as environmental temperature and humidity etc. The present study aims to investigate the variability of dynamic characteristics in rubber engine mounts considering both environmental temperature change and material model errors/uncertainty. The engine mounts for a passenger car were modeled using finite element method. Then, the dynamic stiffness variability of the engine mounts were estimated using Monte Carlo simulation method. In order to estimate the variations in the storage and loss moduli of the viscoelastic materials, the material properties of the synthetic rubber were expressed as a fractional-derivative model. Next, in order to simulate the uncertainty propagation of the dynamic stiffness for the engine mounts due to the storage and loss moduli variations, the Monte Carlo simulation was used. The Monte Carlo simulation results showed large variation of the engine-mount stiffness along frequency axis.

PL Study on the Oxygen-Plasma-Treated ZnO Thin Film (산소 플라즈마 처리 후 ZnO 박막에 대한 PL 연구)

  • Cho, Jae-Won;Rhee, Seuk-Joo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.12
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    • pp.992-995
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    • 2011
  • The optical properties of ZnO thin film, being treated by O-plasma, have been studied using Photoluminescence(PL) spectroscopy with the change of temperature from 10 K to 290 K. Two characteristic peaks were identified at 10 K : 3.357 eV($D^{\circ}X$) and 3.324 eV(TES). The peak of $D^{\circ}X$ is believed to be due to neutral donor bound excitons where the donor is in the ground state. However, the TES(Two Electron Satellite) peak indicates the excited state of the donor(excitation energy was ~30 meV). The donor binding energy was estimated to be 44 meV, which indicates the possible presence of the neutral donor bound excitons at RT. The thermal effect including thermal broadening was identified from temperature evolution of the spectrum. Both the peak intensity and the peak energy have decreased as the temperature increases. As the temperature approaches to RT, the two peak merges into one broad peak, which is considered a combination of multiple peaks having different physical origins.

Optimal Current Detect MPPT Control of PV System for Robust with Environment Changing (환경변화에 강인한 태양광 발전의 최적전류 MPPT 제어)

  • Choi, Jung-Sik;Ko, Jae-Sub;Chung, Dong-Hwa
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.10
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    • pp.47-58
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    • 2011
  • This paper proposes the optimal current detect(OCD) maximum power point tracking(MPPT) control of photovoltaic(PV) system for robust with environment changing. The output characteristics of the solar cell is a nonlinear and affected by a temperature, the solar radiation and temperature. Conventional MPPT control methods are tracked the maximum power point by constant incremental value. So these methods are slow the response speed and generated the vibration in steady state and cannot track the MPP in environment condition changing. And power loss is generated because of the self-excitation vibration in MPP region. To solve this problem, this paper proposes the novel control algorithm. Proposed algorithm is detected the optimal current in two control region using the output power and current curve. Detected current is used the converter switching for tracking the MPP. Proposed algorithm is compared output power error to conventional algorithm with radiation and temperature changing. In addition, the validity of the algorithm is proved through the output error response characteristics.

A Two-dimensional Steady State Simulation Study on the Radio Frequency Inductively Coupled Argon Plasma

  • Lee, Ho-Jun;Kim, Dong-Hyun;Park, Chung-Hoo
    • KIEE International Transactions on Electrophysics and Applications
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    • v.2C no.5
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    • pp.246-252
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    • 2002
  • Two-dimensional steady state simulations of planar type radio frequency inductively coupled plasma (RFICP) have been performed. The characteristics of RFICP were investigated in terms of power transfer efficiency, equivalent circuit analysis, spatial distribution of plasma density and electron temperature. Plasma density and electron temperature were determined from the equations of ambipolar diffusion and energy conservation. Joule heating, ionization, excitation and elastic collision loss were included as the source terms of the electron energy equation. The electromagnetic field was calculated from the vector potential formulation of ampere's law. The peak electron temperature decreases from about 4eV to 2eV as pressure increases from 5 mTorr to 100 mTorr. The peak density increases with increasing pressure. Electron temperatures at the center of the chamber are almost independent of input power and electron densities linearly increase with power level. The results agree well with theoretical analysis and experimental results. A single turn, edge feeding antenna configuration shows better density uniformity than a four-turn antenna system at relatively low pressure conditions. The thickness of the dielectric window should be minimized to reduce power loss. The equivalent resistance of the system increases with both power and pressure, which reflects the improvement of power transfer efficiency.

Temperature Dependent Optical Performance of the NaSr(PO3)3:Eu2+ Blue Phosphors (NaSr(PO3)3:Eu2+ 청색 형광체의 온도 의존적 형광 특성)

  • Yoon, Chang yong;Lee, Sang ho
    • Journal of the Korean Society of Radiology
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    • v.15 no.3
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    • pp.391-399
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    • 2021
  • Eu2+ doped polyphosphate NaSr(PO3)3 blue-emitting phosphors were synthesized by the conventional solid state method in a reductive atmosphere. The phase formation of NaSr(PO3)3 phosphors were characterized by using the X-ray powder diffraction (XRD) measurement. The photoluminescence emission and excitation spectra of the NaSr(PO3)3:Eu2+ phosphor, and decay curves were measured. Under the near-UV excitation, the phosphor exhibits a band emission around 420 nm assigned to the 4f65d→f7(8S7/2) transition of Eu2+. The temperature dependent emission spectra and decay curves were measured to elevate the thermal properties of the Eu2+ doped phosphors. The as-prepared NaSr(PO3)3:Eu2+ phosphors show a strong temperature dependent performance, which can serve as a promising temperature sensor.

PbS Quantum-dots in Glasses

  • Liu, Chao;Heo, Jong
    • Ceramist
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    • v.10 no.3
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    • pp.7-14
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    • 2007
  • PbS QDs in glasses have attracted much attention due to the potentials for near-infrared applications. Growth of PbS QDs in the glass is discussed and size of PbS QDs formed in the glass can be tuned by varying the thermal treatment conditions. Hyperbolic-band approximation and four-band envelope function provide good simulation of the exciton energies of PbS QDs. Absorption and photoluminescence of PbS QDs was tuned into $1{\sim}2{\mu}m$ wave-length regime with large full width at half maximum photoluminescence intensity (>160 nm). Photoluminescence intensity of PbS QDs in the glasses was closely related to size of quantum dots, temperature, excitation and defects. Decrease in temperature shifted the photoluminescence bands to shorter wavelength and switched the photoluminescence from darkened state and brightened state.

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Resonance of Natural Convection and Heat Transfer inside a Square Cavity due to a Vibrating Wall (사각 공동구의 벽면 가진에 의한 자연 대류 유동의 공진 현상 및 열전달에 관한 연구)

  • Hur, N.;Kim, Y.;Kang, B.
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.483-488
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    • 2001
  • In the present study a numerical simulation is performed on a natural convection inside a square cavity with a vibrating wall. The study has been conducted varying the heat transfer rate, wall excitation frequency and also the orientation of the cavity. The temperature and velocities inside the cavity was observed and also, the heat transfer coefficients on the heating wall was seen. From the results, it can be seen that the temperature inside the cavity decreases when excited with the proper frequency and the heat transfer coefficient increased with cavity inclination angle, ${\theta}$. It is also found from the results that flow resonance is occurred near the inclination angle ${\theta}=90^{\circ}$.

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