• 한국결정학회지
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• 제7권1호
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• pp.64-72
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• 1996

증기압 제어를 위한 저온부를 없애고, 고온부의 단일 온도영역만으로 GaAs 단결정을 성장 시키는 단일 온도대역 수평 Bridgman(1-T HB: single temperature zone horizontal Bridgman)방식에서는 증기압에 상응할만한 반응관 내부의 압력을 As 초과 유입량의 기화에 의하여 유지해야 하므로 그 양을 정밀하게 결정해 주어야 한다. 이것을 위하여, 우선적으로 Ga-As 계에서의 열화학적 특성을 규명하였고, 이에 근거하여 단일 온도대역 수평 Bridgman 법으로 결정성장할 때의 As 초과 유입량을 GaAs 장입량, 반응관 칫수, 온도구배 등에 의한 일반해로 유도하였다. 따라서 단일 온도대역 수평 Bridgman 법에 의한 GaAs 단결정 성장의 이론적 근거를 마련하였다.

• 천문학회보
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• 제44권1호
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• pp.44.3-44.3
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• 2019

Massive stars, supernovae, and kilonovae are among the most luminous radiation sources in the universe. Observations usually show near- to mid-infrared (NIR-MIR, 1-5~micron) emission excess from H II regions around young massive star clusters (YMSCs) and anomalous dust extinction and polarization towards Type Ia supernova (SNe Ia). The popular explanation for such NIR-MIR excess and unusual dust properties is the predominance of small grains (size a<0.05micron) relative to large grains (a>0.1micron) in the local environment of these strong radiation sources. The question of why small grains are predominant in these environments remains a mystery. Here we report a new mechanism of dust destruction based on centrifugal stress within extremely fast rotating grains spun-up by radiative torques, namely the RAdiative Torque Disruption (RATD) mechanism, which can resolve this question. We find that RATD can destroy large grains located within a distance of ~ 1 pc from a massive star of luminosity L~ 10^4L_sun and a supernova. This increases the abundance of small grains relative to large grains and successfully reproduces the observed NIR-MIR excess and anomalous dust extinction/polarization. We show that small grains produced by RATD can also explain the steep far-UV rise in extinction curves toward starburst and high redshift galaxies, as well as the decrease of the escape fraction of Ly-alpha photons observed from HII regions surrounding YMSCs.

• 혜화의학회지
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• 제21권1호
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• pp.1-9
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• 2012

Objectives : The aim of this experiment is to find out relationship between the effect of cosmetics and 4 types of pattern identification about fluid-humor, which are based on the general idea of traditional oriental medicine, Qi-Blood and deficiency-excess. Methods : Korean female volunteers in good health (n=25, $23.12{\pm}2.83$) participated in this experiment. Three Korean medical doctors classified them into 4 groups: Blood-deficiency: group A; Blood-excess: group B; Qi-deficiency:group C; Qi-excess:group D). Cosmetics that contains herb extract for Blood deficiency were given to all volunteers and they used the cosmetics for 4 weeks. Volunteers were assessed non-invasively with the skin measuring devices before and after using cosmetics. And we analyzed the correlation of skin physiological parameters with 4 groups. Results : Three doctors diagnosed participants and classified them into 4 groups ; group A(n=8),group B(n=7), group C(n=3), group D(n=5) as highest score. After 4 weeks, facial skin moisture showed no significant difference in comparison between 4 groups. Sebum showed significant increase in Group A and significantly decreased Group B. Measurement of facial skin elasticity tended to increase in Group A, C, D but skin elasticity was decreased significantly in Group B. Conclusions : In case of a group that pattern identification about fluid-humor corresponds to herb extract in cosmetic, skin improving effect was better than the other group that pattern identification oppose to properties of herb in cosmetic. Therefore, from the view of traditional oriental medicine, it is very important to understand user's pattern of identification or physical conditions and properties of herbs in cosmetics on the matter of safety and efficacy.

• 한국결정성장학회지
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• 제12권4호
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• pp.184-189
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• 2002

초음파 분무 MOCVD법에 의한 $(Pb_{0.91}La_{0.09})(Zr_{0.65}Ti_{0.35})O_3$(PLZT) 박막의 제조와 광학적, 전기적 특성을 조사하였다. Pb의 휘발성을 고려하여 0.2M의 precursor에 Pb를 5 wt%, 10 wt%과잉 첨가하였다. ITO-coated glass 기판 위에 산소분위기에서 30분 동안 증착한 후 in-situ 상태의 RTA (rapid thermal annealing) 방식으로 열처리를 하였다. 단일 perovskite상의 결정화 온도는 $600^{\circ}C$였다. Pb를 10 wt% 과잉 첨가한 박막의 최대 광투과율은 520nm에서 약 84%로 광학적 특성이 우수하였으며, 유전상수는 약 308의 값을 가졌고, 누설전류는 Pb를 0, 5 wt% 과잉 첨가한 PLZT 박막보다 낮은 값을 가졌다.

• 한국전기전자재료학회논문지
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• 제29권12호
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• pp.764-768
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• 2016

To investigate excess $Na^+$ effect, $Bi_{0.5}(Na_{0.78+x}K_{0.22})_{0.5}TiO_3$ ($0{\leq}x{\leq}0.05$) (BNKT) ceramics were prepared by using a conventional solid-state reaction method. The structure and ferroelectric properties of BNKT ceramics were characterized by XRD (X-ray diffraction) and polarization dependence by external electric field. Also, the temperature dependence of dielectric constant and loss were studied. From these results, it was found that appropriate excess $Na^+$ into BNKT ceramics compensate the volatility and induce dense ceramics. The enhanced piezoelectric coefficient (158 pC/N) and depolarization temperature ($202^{\circ}C$) were obtained for the x=0.01 composition.

• 한국세라믹학회지
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• 제19권4호
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• pp.281-286
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• 1982

The composition of glasses to be suitable for crystallisation of $BaTiO_3$ by heat-treatment and the dielectric properties of the glass-ceramics were investigated. The composition of the family of glasses was defined by the formula $\chi$ $BaTiO_3 + (100-$\chi$)Al_2O_3$.$2SiO_2$ and excess BaO. Data were presented on dielectric constant and loss tangent at various frequencies. The effects of excess BaO on dielectric properties were investigated. The additions of $Na_2O$ and $Nb_2O_5$ shifted the Curite temperature of these glass-ceramics. The glass composition which was able to be melted at 145$0^{\circ}C$ and moulded as homogeneous glass phase without devitrification should contain $Al_2O_3$.$2SiO_2$ more than 30 mole %. The more the amount of additive BaO increased, the more dielectric constant increased. When the maximum heat-treatment temperature was 105$0^{\circ}C$, we obtained higher dielectric constant than that of 95$0^{\circ}C$. The dielectric constant and the dielectric loss were stable at frequencies between 5$\times$104 and 107 cycle per second. When $Na_2O$ and $Nb_2O_5$ were added, the Curie temperature, presented at 14$0^{\circ}C$ to 15$0^{\circ}C$, shifted to lower temperature. Therefore, the glass-ceramics having high dielectric constant at room temperature were obtained.

• 한국통신학회논문지
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• 제18권11호
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• pp.1714-1725
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• 1993

본 논문에서는 스칼라 인수 a1, a2, a3를 매개변수화하여 갱신항을 첨가한 비선형 적응 알고리즘의 특성을 해석하고 그 구조를 나타낸다. 수렴 특성의 해석에서 평균 필터계수 벡터에 대하여 전이행열의 값이 기술된다. 그 알고리즘이 안정하기 위한 범위도 증명된다. 또한 본 알고리즘의 시정수도 유도되고, Sign 알고리즘, 기존의 LMS 알고리즘, LFG 알고리즘, QFG 알고리즘의 계산량도 비교해 본다. 평균자승의 수렴특성을 해석하고 평균자승 순환식과 초과 평균자승 오차(excess mean square error) 표현식을 유도하고 본 알고리즘이 안정하기 위한 조선도 정한다. 컴퓨터 모의실험(simulation)에서 CFG 알고리즘이 LMS, LFG 및 QFG 알고리즘보다 계산량이 증가하는 반면 수렴속도에서 현저한 향상을 보여준다.

• 한국도로학회논문집
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• 제17권2호
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• pp.1-11
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• 2015

PURPOSES : This study set out to investigate the fundamental properties of alkali-activated concrete (AAC) using modified slag as the pavement maintenance material. METHODS: The material properties of modified slag based alkali-activated concrete (MSAAC) were analyzed and evaluated against those of alkali-activated slag concrete (AASC). Several mix formulations were considered, including one MSACC and four AASCs. The main variables considered in the study were slump, air content, compressive strength, rapid chloride permeability test, scaling resistance, freeze-thaw test, XRD, SEM, and EDS. RESULTS: MSAAC exhibits a compressive strength in excess of 21 MPa six hours after curing. Also, the charge passed of the MSACC was found to be less than 2000 coulombs after seven days and about 1000 coulombs after 28 days. The weight loss determined from a scaling test did not exceed $1kg/cm^2$ in the case of the MSACC, but that of the AASCs had already exceeded $1kg/cm^2$ at the 10th cycle. Based on the results of the freeze-thaw test, the relative dynamic modulus of every mix was found to be in excess of 90%. An energy dispersive spectroscopy(EDS) analysis found that the weight rate percentage of the calcium and aluminum in the MSAAC mix is twice that of the AASC mixes. CONCLUSIONS : It was found that the MSAAC mix exhibits significantly better performance than AASC mixes, based on various fundamental properties.

• 한국전기전자재료학회논문지
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• 제37권3호
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• pp.231-240
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• 2024

Titanium dioxide (TiO₂) holds significant scientific and technological relevance as a key photocatalyst and resistive random-access memory, demonstrating unique physicochemical properties and serving as an n-type semiconductor. Understanding the density and arrangement of oxygen vacancies (VOs) is crucial for tailoring TiO₂'s properties to diverse technological needs, driving increased interest in exploring oxygen vacancy complexes and superstructures. In this mini review, we summarize the recent understandings of the fundamental properties of oxygen vacancies in bulk rutile (R-TiO₂) and anatase (A-TiO₂) based on DFT and beyond method. We specifically focus on the excess electrons and their spatial arrangement of disordered single VO in bulk R and A-TiO₂, aligned with the experimental findings. We also highlight the theoretical works on investigating the geometries and stabilities of ordered VOs complexes in bulk TiO₂. This comprehensive review provides insights into the fundamental properties of excess electrons in reduced TiO₂, offering valuable perspectives for future research and technological advancements in TiO₂-based devices.

• Advances in nano research
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• 제5권3호
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• pp.261-279
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• 2017

Spectroscopic investigation of Si quantum dots (Si-QDs) embedded in silicon nitride was performed over a broad stoichiometry range to optimize light emission. Plasma-enhanced chemical vapor deposition was used to grow the $SiN_x$ films on Si (001) substrates. The film composition was controlled via the flow ratio of silane ($SiH_4$) and ammonia ($NH_3$) in the range of R = 0.45-1.0 allowed to vary the Si excess in the range of 21-62 at.%. The films were submitted to annealing at $1100^{\circ}C$ for 30 min in nitrogen to form the Si-QDs. The properties of as-deposited and annealed films were investigated using spectroscopic ellipsometry, Fourier transform infrared spectroscopy, Raman scattering and photoluminescence (PL) methods. Si-QDs were detected in $SiN_x$ films demonstrating the increase of sizes with Si excess. The residual amorphous Si clusters were found to be present in the films grown with Si excess higher than 50 at.%. Multi-component PL spectra at 300 K in the range of 1.5-3.5 eV were detected and nonmonotonous varying total PL peak versus Si excess was revealed. To identify the different PL components, the temperature dependence of PL spectra was investigated in the range of 20-300 K. The analysis allowed concluding that the "blue-orange" emission is due to the radiative defects in a $SiN_x$ matrix, whereas the "red" and "infrared" PL bands are caused by the exciton recombination in crystalline Si-QDs and amorphous Si clusters. The nature of radiative and no radiative defects in $SiN_x$ films is discussed. The ways to control the dominant PL emission mechanisms are proposed.