• 제목/요약/키워드: Ex-situ

검색결과 243건 처리시간 0.022초

NH$_3$-pplasma Treatment of GaAs Surface at High Tempperature in RF pparallel pplate pplasma Reactor

  • ppark, Kyoung-Wan;Lee, Seong-Jae-;Kim, Gyungock-;Lee, El-Hang-
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1993년도 제4회 학술발표회 논문개요집
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    • pp.29-31
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    • 1993
  • NH3-pplasma treatment has been used for ppassivation of native-oxide-contaminated GaAs surface. Ex-situ band-gapp pphotoluminescence(ppL) measurement shows enhanced intensity for the treated surfaces. Auger electron sppectroscoppy(AES) shows that the treated surface contains nitrogen atoms but no arsenic atoms, which leads us to sppeculate that the graded GaN thin layer was formed on the surface. Based on these results, new metal-insulator-GaAs structure is ppropposed.

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보호종인 히어리의 자생지내외 보전과 지역사회 협력 모델 개발 - I . 히어리 자연집단과 절개 집단간 개체군 동태 (A Study on the Operating Conditions and the Direction of Improving Environmental Interpretation Program in Recreational Forests Conservation of an endangered Corylopsis coreana Uyeki in and ex situ and Development of cooperative model within local community - III. Populational Dynamics between the natural groups and the pruned groups of the Corylopsis coreana $U_{YEKI}$)

  • 임동옥;황인천;정홍락;유윤미;박양규
    • 한국환경생태학회:학술대회논문집
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    • 한국환경생태학회 2005년도 임시총회 및 학술논문발표회
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    • pp.53-55
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    • 2005
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Development of Miniaturized Automatic Chromatography System for Column Performance Validation : MiniValChrom

  • 박재하;이은규
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 추계학술발표대회 및 bio-venture fair
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    • pp.147-150
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    • 2000
  • 크로마토그래피 칼럼 검증전용으로 미니 칼럼을 이용한 자동화된 크로마토그래피 시스템(MiniValChrom)을 개발하였다. 이 시스템은 생산용 칼럼을 scale-down한 미니칼럼을 자동적으로 반복사용 하면서 실험실 내에서 ex-situ로 크로마토그래피 공정의 검증을 수행할 수 있게 설계되었다.

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Binary Compound Formation upon Copper Dissolution: STM and SXPS Results

  • Hai, N.T.M.;Huemann, S.;Hunger, R.;Jaegermann, W.;Broekmann, P.;Wandelt, K.
    • Corrosion Science and Technology
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    • 제6권4호
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    • pp.198-205
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    • 2007
  • The initial stages of electrochemical oxidative CuI film formation on Cu(111), as studied by means of Cyclic Voltammetry (CV), in-situ Scanning Tunneling Microscopy (STM) and ex-situ Synchrotron X-ray Photoemission Spectroscopy (SXPS), indicate a significant acceleration of copper oxidation in the presence of iodide anions in the electrolyte. A surface confined supersaturation with mobile CuI monomers first leads to the formation of a 2D-CuI film via nucleation and growth of a Cu/I-bilayer on-top of a pre-adsorbed iodide monolayer. Structurally, this 2D-CuI film is closely related to the (111) plane of crystalline CuI (zinc blende type). Interestingly, this film causes no significant passivation of the copper surface. In an advanced stage of copper dissolution a transition from the 2D- to a 3D-CuI growth mode can be observed.

Effects of Hydrogen on the PWSCC Initiation Behaviours of Alloy 182 Weld in PWR Environments

  • Kim, H.-S.;Hong, J.-D.;Lee, J.;Gokul, O.S.;Jang, C.
    • Corrosion Science and Technology
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    • 제14권3호
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    • pp.113-119
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    • 2015
  • Alloy 82/182 weld metals had been extensively used in joining the components of the PWR primary system. Unfortunately, there have been a number of incidents of cracking caused by PWSCC in Alloy 82/182 welds during the operation of PWR worldwide. To mitigate PWSCC, optimization of water-chemistry conditions, especially dissolved hydrogen (DH) and Zn contents, is considered as the most promising and effective remedial method. In this study, the PWSCC behaviours of Alloy 182 weld were investigated in simulated PWR environments with various DH content. Both in-situ and ex-situ oxide characterizations as well as PWSCC initiation tests were performed. The results showed that PWSCC crack initiation time was shortest in PWR water (DH: 30cc/kg). Also, high stress reduced crack initiation time. Oxide layer showed multi-layered structures consisted of the outer needle-like Ni-rich oxide layer, Fe-rich crystalline oxide, and inner Cr-rich inner oxide layers, which was not altered by the level of applied stress. To analyse the multi-layer structure of oxides, EIS measurement were fitted into an equivalent circuit model. Further analyses including TEM and EDS are underway to verify appropriateness of the equivalent circuit model.

Epitaxial Growth of MgO and CoFe/MgO on Ge(001) Substrates by Molecular Beam Epitaxy

  • Jeon, Kun-Rok;Park, Chang-Yup;Shin, Sung-Chul
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2009년도 정기총회 및 동계학술연구발표회
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    • pp.190-190
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    • 2009
  • We report the epitaxial growth of MgO and CoFe/MgO on Ge (001) substrates using molecular beam epitaxy. It was found that the epitaxial growth of a MgO film on Ge could be realized at a low growth temperature of $125{\pm}5^{\circ}C$ and the MgO matches the Ge with a cell ratio of $\sqrt{2}$:1 which renders MgO rotated by $45^{\circ}$ relative to Ge. In-situ and ex-situ structural characterizations reveal the epitaxial crystal growth of bcc CoFe/MgO on Ge with the in-plane crystallographic relationship of CoFe(001)[100] || MgO(001)[110] || Ge(001)[100], exhibiting sharp interfaces in the (001) matching planes. The saturation magnetization of the sample is $1430{\pm}20$ emu/cc, which is comparable to the value of bulk CoFe.

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Ex-situ 화학적 산화처리 적용을 위하여 다양하게 활성화(heat, Fe2+, UV)된 persulfate를 이용한 TCE 분해에 대한 연구 (Degradation of TCE by Persulfate Oxidation with Various Activation Methods (heat, Fe2+, and UV) for ex-situ Chemical Oxidation Processes)

  • 김한솔;도시현;박기만;조영훈;공성호
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제17권6호
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    • pp.43-51
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    • 2012
  • Rreactivity of persulfate (PS) for oxidation of TCE under various conditions such as heat, $Fe^{2+}$, and UV was investigated. It was found that degradation rate of TCE increased with increasing temperature from 15 to $35^{\circ}C$. At pH 7.0, the rate constants (k) at 15, 25, 30, and $35^{\circ}C$ were 0.07, 0.30, 0.74, and $1.30h^{-1}$, respectively. For activation by $Fe^{2+}$, removal efficiency of TCE increased with increasing $Fe^{2+}$ concentration from 1.9 mM to 11 mM. The maximum removal efficiency of TCE was approximately 85% when pH of the solution dropped from 7.0 to 2.5. Degradation of TCE by UV-activated PS was the most effective, showing that the degradation rate of TCE increased with inreasing PS dosage; the rate constants (k) at 0.5, 2.5, and 10 mM were 34.2, 40.5, and $55.9h^{-1}$, respectively. Our results suggest that PS activation by UV/PS process could be the most effective in activation processes tested for TCE degradation. For oxidation process by PS, however, pH should be observed and adjusted to neutral conditions (i.e., 5.8-8.5) if necessary.

미세기공 제올라이트를 이용한 국내 수종 굴참나무의 간접 촉매 열분해 (Ex-situ Catalytic Pyrolysis of Korean Native Oak Tree over Microporous Zeolites)

  • 김영민;김범식;채광석;조태수;김승도;박영권
    • 공업화학
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    • 제27권4호
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    • pp.407-414
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    • 2016
  • 고정층 반응기를 이용하여 제올라이트(HZSM-5, HBeta, HY) 상에서 국내 수종 굴참나무의 간접 촉매 열분해를 수행하였다. 고품질 바이오오일 생산 최적 조건을 도출하기 위해 시료와 촉매의 비율과 반응 온도의 영향 또한 고찰하였다. 세 종의 촉매 중에서 HZSM-5가 적절한 기공크기와 강한 산도로 인해 가장 높은 방향족 화합물 형성능을 나타내었다. HY와 HBeta 또한 촉매능을 가졌으나, 큰 기공크기로 인해 많은 양의 코크가 형성되었다. HZSM-5 상에서 참나무의 촉매 열분해를 통해 방향족 화합물의 수율을 극대화하기 위해서는 낮은 시료/촉매비와 높은 반응 온도가 요구됨을 확인하였다.

Enhanced Low-field Magnetoresistance of La0.7Sr0.3Mn1+dO3-Mn3O4 Composite Films Prepared by ex-situ Solid Phase Crystallization

  • Kang, Young-Min;Kim, Hyo-Jin;Yoo, Sang-Im
    • Journal of Magnetics
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    • 제17권4호
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    • pp.265-270
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    • 2012
  • We report improved low-field magnetoresistance (LFMR) effects of the $La_{0.7}Sr_{0.3}Mn_{1+d}O_3-Mn_3O_4$ composite films with the nominal composition of $La_{0.7}Sr_{0.3}MnO_3$(LSMO)-50 mol% $Mn_3O_4$. The composite films were fabricated by ex-situ solid phase crystallization (SPC) of amorphous films at the annealing temperature region of $900-1100^{\circ}C$ for 2 h in a pure oxygen atmosphere. The amorphous films were deposited on polycrystalline $BaZrO_3$ (poly-BZO) substrates by dc-magnetron sputtering at room temperature. The Curie temperatures ($T_C$) of all composite films were insignificantly altered in the range of 368-372 K. The highest LFMR value of 1.29 % in 0.5 kOe with the maximum dMR/dH value of $37.4%kOe^{-1}$ at 300 K was obtained from 900 nm-thick composite film annealed at $1100^{\circ}C$. The improved LFMR properties of the composite films are attributed to effective spin-dependent scattering at the $La_{0.7}Sr_{0.3}Mn_{1+d}O_3$ grain boundaries sharpened by adjacent chemically compatible $Mn_3O_4$ grains.

주파수 70 kHz를 이용한 보름달물해파리의 유영 자세각과 박동에 따른 초음파산란강도 (Ex situ acoustic target strength by tilt angle and pulsation of moon jellyfish (Aurelia aurita) using frequency 70 kHz)

  • 윤은아;황두진;히로세 미유키;사와다 코유이치;후쿠다 요시아키;무카이 토오루
    • 수산해양기술연구
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    • 제51권3호
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    • pp.295-301
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    • 2015
  • Target strength (TS) information is an important parameter that estimates the detection, distribution, and abundance of Aurelia aurita. In order to investigate the biological TS of jellyfish, some factors such as size (bell diameter), tilt angle, pulsation, and symbion should be known. In the ex situ TS measurements, the tilt angles and pulsation from synchronized swimming behavior of four live A. aurita (bell diameters in the air: 54.2 ~ 94.2 mm) were measured with the acoustic data at 70 kHz. The reduced target strength (RTS) of A. aurita was found to change ranged from 13.4 ~ 16.5 dB according to the incidence angles from $-30^{\circ}$ to $24^{\circ}$. When the change rate of bell diameter in the water was 0.2, the TS value showed a 7.2 dB change. These results could be utilized as an important data to understand the acoustic characteristic scattering of A. aurita.