• Bulletin of the Korean Chemical Society
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• v.25 no.10
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• pp.1508-1512
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• 2004

A gas chromatography/mass spectrometric (GC/MS) method has been developed for the determination of trace mono-n-butyltin (MBT), di-n-butyltin (DBT), and tri-n-butyltin (TBT) compounds in sediments. Samples were extracted by 10% acetic acid in methanol containing 0.03% tropolone and were then derivatized for GC/MS analysis. Ethylation by sodium tetraethylborate and phenylation by sodium tetraphenylborate were evaluated as a derivatization reaction of the organotins in sample extract. n-Hexane was added into reaction media in the beginning of the reaction for the continuous extraction of derivatized organotins. Ethylation requires less than 2 hours to get proper derivatization yields for MBT, DBT, and TBT altogether and produces relatively low amounts of side reaction products. Compared to ethylation, phenylation requires much longer time but provides relatively lower yield and produces considerable amounts of side reaction products. Therefore, the ethylation reaction was applied for the analysis of organotin compounds in sediment. An isotope dilution mass spectrometric (IDMS) method based on GC/MS has been applied to the accurate determination of DBT compounds in the sediments. The IDMS results from the analyses of sediment samples showed a reasonable repeatability and a good agreement with the values obtained by IDMS based on liquid chromatography/induced coupled plasma/mass spectrometry.

• Tribology and Lubricants
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• v.11 no.4
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• pp.21-27
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• 1995

The effects of interface boundary strength on wear and wear transition during sliding have been investigated in silicon carbide ceramics. Three different microstructures, i.e., solid state sintered silicon carbide, liquid phase sintered silicon carbide and liquid phase sintered silicon carbide composite reinforced with TiB$_{2}$ particulates, were designed by hot pressing. Examinations of crack patterns and fracture modes indicated that interface boundaries were relatively strong between silicon carbide grains in the solid state sintered silicon carbide, intermediate in the liquid phase sintered silicon carbide and weak between silicon carbide grains and TiB$_{2}$ particles in the composite. Wear data and examinations of worn surfaces revealed that the wear behavior of these silicon carbide ceramics could be significantly affected by the interface strength. In the solid state sintered silicon carbide, the wear occurred by a grooving process. In the liquid phase sintered silicon carbide and composite, on the other hand, an abrupt transition in wear mechanism from initial grooving to grain pull-out process occurred during the test. The transition occurred significantly earlier in the composite than in the carbide.

• Nuclear Engineering and Technology
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• v.54 no.9
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• pp.3272-3282
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• 2022

To improve the safety and life extension qualities of nuclear fuel rods which is currently made of zirconium (Zr) alloy, research on the application of chromium (Cr) coating was conducted. Cr coating has advantages such as increased corrosion resistance and reduced oxidation rate, but non-destructive thickness evaluation studies are needed to ensure the reliability of the steps taken to provide uniform coating thickness. Eddy current testing (ECT) is a representative non-destructive technique for such as thickness evaluation and surface defect inspection. To inspect changes in thickness at micron scale, the Swept Frequency Eddy Current Testing (SFECT) method was applied to select a frequency range sensitive to changes in thickness. The coating thickness was evaluated using changes in signals, such as that for impedance. In this study, basic research was performed to evaluate the thickness of the Cr coating on a rod using an encircling sensor and the SFECT technique. The sensor design parameters were determined through simulation, after which the new sensor was manufactured. A sensor capable of measuring the thickness of a non-uniformly Cr-coating rod was selected through an experiment evaluating the performance of the manufactured sensor. This was done using the impedance-difference of a Cr-coating rod and a Zr alloy rod. The possibility of evaluation of the Cr coating thickness was confirmed by comparing the experimental results with the selected sensor and the signals of the measured Cr-coating rod. All simulation results were verified experimentally.

• Korean Institute of Interior Design Journal
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• v.15 no.3 s.56
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• pp.136-143
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• 2006

This research proposes the importance of physical environment if integrated early childhood education. For a successful integration of children's education, we processed fundamental research on requirements of facility and equipments, looking at related standards and code on handicapped person's convenience facility. Also, this research alms at providing first step to establish evaluation method and quality assurance standards of integrated child care facility, regarding space planning of handicapped children. By examining home and abroad material and analyzing handicapped children's convenience facility standards, this research pursues improving the basis of planning criteria. As present criteria of relevant regulations appears not to handle detailed facility standards, and the handicapped people's facility is for childhood education, it is necessary first to differentiate indispensable equipments from optional one, then categorize them into more specific needs.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.1704-1705
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• 2007

A step-down procedure employing low voltage thermal transfer standard(LVTS) and micropotentiometer is described for the establishing the ac low voltage standards in the range of 2 mV to 200 mV below 1 MHz. Techniques are given for measuring input impedance with insertion method and calculating the loading error for the ac-dc transfer difference of the LVTS.

• Wind and Structures
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• v.1 no.1
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• pp.77-109
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• 1998

An evaluation and comparison of seven of the world's major building codes and standards is conducted in this study, with specific discussion of their estimations of the alongwind, acrosswind, and torsional response, where applicable, for a given building. The codes and standards highlighted by this study are those of the United States, Japan, Australia, the United Kingdom, Canada, China and Europe. In addition, the responses predicted by using the measured power spectra of the alongwind, acrosswind and torsional responses for several building shapes tested in a wind tunnel are presented and a comparison between the response predicted by wind tunnel data and that estimated by some of the standards is conducted. This study serves not only as a comparison of the response estimates by international codes and standards, but also introduces a new set of wind tunnel data for validation of wind tunnel-based empirical expressions.

• Proceedings of the KIEE Conference
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• 2008.09a
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• pp.61-63
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• 2008

We established a system to evaluate the ratio error and phase angle error of electronic voltage transformer using high voltage capacitance bridge and standard capacitors. The uncertainty of evaluation system is about 0.005% in ratio error and 1.5 min in phase angel error.

• Proceeding of Spring/Autumn Annual Conference of KHA
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• 2003.11a
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• pp.83-87
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• 2003

In recent days, IAQ(Indoor Air Quality) is regarded as one of the most important environmental factors as well as thermal and acoustic comfort. Various architectural materials are applied and air-tightness of the building is more strengthening to save energy consumption. This is why the air quality of the newly built houses became worse. In this study, contaminants(CO, CO$_2$, Radon, TVOCs, HCHO) density was measured in a newly built house and evaluation was carried out by ASHRAE and EPA Standards. As a result, CO, CO$_2$, TSP and Radon density of the newly built house was in a range of ASHRAE and EPA Standards, but it turned out TVOCs and HCHO density exceeds almost 3${\sim}$5 times in comparison with that of ASHRAE and EPA Standards.

• KIEAE Journal
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• v.9 no.6
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• pp.19-26
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• 2009

In modern architecture, the air-tight construction aimed at saving the energy rather causes ventilation problems and the artificial materials for cost reduction worsen the residential quality. To deal with such negative effect, the study on evaluating the health performance becomes increasingly critical. Among the various factors such as design quality, selected material, construction method and mechanical system that shall be subject to evaluation to identify the health performance of the building, the study was aimed at investigating the legal standards associated with healthy building in various countries. Such evaluation items will provide inputs for an attempt to build legal criteria for a building health performance rating system in Korea.

• Bulletin of the Korean Chemical Society
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• v.35 no.4
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• pp.1057-1060
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• 2014

In our previous articles, an approach has been proposed for the evaluation of the uncertainty of overall result from multiple measurements. In the approach, uncertainty sources were classified into two groups: the first including those giving same 'systematic' effect on each individual measurement and the second including the others giving 'random' effect on each individual measurement and causing a variation among individual measurement results. The arithmetic mean of the replicated measurements is usually assigned as the value for the overall result. Uncertainty of the overall result is determined by separately evaluating and combining an overall uncertainty from sources of the 'systematic' effect and another overall uncertainty from sources of the 'random' effect. This conceptual approach has been widely adopted in chemical metrology society. In this study, further logical proof with more detailed mathematical expressions is provided on the approach.