• Title/Summary/Keyword: Ethylene-Air

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The Effects of Additives on the Thermal Properties of a Clathrate Compound (II) -The Case of Ethylene Glycol- (포접화합물의 열물성에 미치는 첨가제의 효과 (II) -TMA 물계 포접화합물에 Ethylene Glycol을 첨가한 경우-)

  • 정낙규;김진흥;김창오;김광일
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.6
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    • pp.499-505
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    • 2004
  • The objective of this study is to investigate the effect of supercooling repression on the TMA clathrate by adding ethylene glycol. For this purpose, phase change temperature, supercooling, specific heat, latent heat and rate of volume change were measured and evaluated experimentally for heat source temperatures of -6$^{\circ}C$, -7$^{\circ}C$, -8$^{\circ}C$. The results show that supercooling was decreased. Thus the experimental results are expected to be used for the increase of coefficient of performance of low temperature thermal storage system in the building.

Conjugate Heat Transfer Analysis of an Ethylene Furnace (에틸렌 반응로에 대한 복합 열전달 해석)

  • Ahn, Joon;Park, Jin Woo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.27 no.10
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    • pp.515-519
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    • 2015
  • Conjugate heat transfer analysis for an ethylene furnace was carried out based on numerical simulation. Detailed distributions of velocity vectors, chemical species, and temperature inside the furnace are presented and discussed. Von Mises stress and heat flux at the tube surface were also evaluated to elucidate mechanisms regarding failure of the tube. Maximum stress was found at the upstream elbow of the tube, which did not coincide with the location of maximum heat flux. This implies that thermal stress at a steady state would not be a dominant component of the stress. Degradation of the material, as well as the system arrangement, should be considered in order to accurately predict the lifetime of the tube material in the furnace.

A Study on the Degree of Contamination of Air and Materials in a Hospital (병원내 공기오염과 물품의 항균에 대한 상태조사)

  • 차옥주
    • Journal of Environmental Health Sciences
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    • v.8 no.1
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    • pp.25-30
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    • 1982
  • The incidence of hospital infection has been seriously increased in the general hospital in recent years. This study was performed on hospital air and materials in a General Hospital in Seoul from June to December in 1980. The results were as follows: 1. Air sampling was done in multiple strategic areas by exposing standard petridishes for 5 minutes. There was a significant difference of airborne microbe between places. ($F._{99}$ = 3.2, p < 0.01). 2. The mean colony count was 8.6$\pm$6.2 colonies / plate / 5 minutes. 3. Gram stains of colony in air sampling were Gram (+) cocci 66.5%. Gram (+) rod 18.4%, Gram (-) cocci 1.3%, Gram (-) rod 8.7% Fungus 4.5%. 4. For the evaluation of sterilization of steam sterilizer and ethylene oxide gas sterilizer, biological monitoring were done by commercial spore strip. Positive culture was obtained in 2 out of 41 tests on 3 steam sterilizers, and in 3 out of 13 tests on ethylene oxide gas sterilizer. 5. Product sampling and culture were done for 2 kinds of disinfectants and 30 sets of various operation package or dressing materials. Positive culture was obtained in one disinfectants.

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Ethylene Production and Accumulation in Leaf Sheath and Its Relation to Tillering Suppression of Deep-Irrigated Rice Plants

  • Myung Eul-Jae;Kwon Yong-Woong;Lee Byun-Woo
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.49 no.5
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    • pp.363-367
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    • 2004
  • The deep irrigation of rice plants brings about some beneficial effects such as reduced tiller production which results in the formation of bigger panicles, prevention of chilling injury, reduced weed growth, etc. The present study was carried out to examine the involvement of ethylene in the suppression of tiller production due to deep water irrigation in rice (cv. Dongjinbyeo). The ethylene production was induced in leaf sheath within 24 hours after the deep water irrigation and has increased even until 30 days after the treatment, recording 4.5-fold increase as compared to the shallow-irrigated rice plants. In the deep water irrigated rice plants, ethylene was accumulated to a high concentration in the air space of submerged leaf sheath as the irrigated water deterred the diffusion of ethylene out of the leaf sheath and ethylene biosynthesis was accelerated by the deep irrigation as well. The ethylene concentration recorded 35-fold increase in the deep-irrigated rice plants for 35 days. The tiller production was reduced significantly by the deep irrigation with water, the tiller bud, especially tertiary tiller bud differentiation being suppressed by the deepwater irrigation treatment, whereas the rice plants deep-irrigated with solutions containing $10^{-5}$ M or $10^{-6}$ M silver thiosulfate (STS), an action inhibitor of ethylene, showed the same or even higher production of tillers than those irrigated shallowly with water. This implies that the ethylene is closely linked with the suppression of tiller production due to deep water irrigation. In conclusion, ethylene, which was induced by hypoxic stress and accumulated in the leaf sheath due to submergence, played a key role in suppressing the tiller production of the deepwater irrigated rice.

OH Radical Distribution and Sooting Characteristics in Co-Flow Diffusion Flames (동축류 확산화염의 OH 라다칼 분포 및 매연 특성)

  • Lee, Won-Nam;Song, Young-Hoon;Cha, Min-Suk
    • 한국연소학회:학술대회논문집
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    • 1997.06a
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    • pp.1-11
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    • 1997
  • The soot and OH radical distributions have been experimentally studied in ethylene and propane laminar diffusion flames. The integrated soot volume fraction was measured along the centerline of a flame using a laser light extinction method. Planar laser light scattering and PLIF techniques are employed for the soot and OH radical distribution measurements utilizing Nd:YAG laser and OPO, FDO system. The concentration of OH radical is rapidly decreased at the edge of sooting region, which implies the importance of OH radical species on the soot oxidation process. For ethylene flames, the addition of air in fuel moves the OH radical distribution towards the center line of a flame at the soot oxidation region, while the concentration of OH radical remains relatively high at the soot formation region. The interaction between soot particles and OH radicals becomes more active with fuel-air at the soot oxidation region. For propane flames, however, any indication of the increased interaction between soot particles and OH radicals with fuel-air was not noticed.

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Combustion/Shock Interactions in a Dual-Mode Scramjet Engine (이중모드 스크램제트 엔진에서 연소와 충격파의 상호작용)

  • Choi, Jeong-Yeol;Noh, Jin-Hyeon;Byun, Jong-Ryul
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.367-370
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    • 2011
  • A high-resolution numerical study is carried out to investigate the transient process of the combustion and the shock-train developments in an ethylene-fueled direct-connect dual-mode scramjet combustor. Air-throttling is then applied at the expansion part of the combustor to provide mass addition to block the flow to subsonic speed, hence to enhance the fuel-air mixing and ignition. Present simulation shows the detailed results for the better understanding of transient processes of the operation regimes in the dual-mode scramjet combustor.

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A Study of the Irradiation Environment Effects on the Electrical Properties of Ethylene Propylene Rubber (방사선 조사 환경에 의한 에칠렌 프로필렌 고무의 전기 특성에 관한 연구)

  • 이성일
    • Journal of the Korea Safety Management & Science
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    • v.2 no.2
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    • pp.187-200
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    • 2000
  • The charge and discharge current in EPR(Ethylene Propylene Rubber), which were irradiated with the radiant capacity of 0~600 [kgy/h], have been measured in order to investigate the influence of the atmosphere (oxygen, air and vacuum) on electrical properties. It has been shown that the charge and discharge current increase as the amount of radiant capacity increases in air and vacuum atmosphere. This electrical property degradation can be speculated due to that the C=O radicals or impurities, which comes from during shaping process, may act as dipoles. On the other hand, the charge and discharge current are shown to be higher in the amount of 1[kgy/h] than these in 10[kgy/h] in air atmosphere, because the charge and discharge current can be increased as the exposure time is extended with slower rate. Under the same amount of irradiation, the charge and discharge current in oxygen atmosphere are shown to be higher than those in vacuum. This is possibly due to that the main chain can be broken by oxidation when it is exposed to the $\gamma$ -rays.

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Various Alcohols as Electrolysis Suppressants in Zn-air Secondary Batteries

  • Yang, Soyoung;Kim, Ketack
    • Journal of Electrochemical Science and Technology
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    • v.9 no.4
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    • pp.339-344
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    • 2018
  • The gelling agent used in Zn-air cells plays a role in improving battery life. It prevents the evaporation of water and diffusion of $Zn^{2+}$ ions away from the current collector. Additional functionality was incorporated by replacing some of the gelling agents with new materials. Alcohols with moderate viscosity, namely maltose, sucrose, poly ethylene glycol 600, and 2-hydroxyethyl cellulose, were used to replace some gelling agents in this work. Among these alcohols, poly ethylene glycol 600 and 2-hydroxyethyl cellulose improved the cycle life of full cells. This improved cycle life was attributed to the inhibition of water electrolysis and the improved cycle life of the anode.

Ecotoxicity Estimation of Hazardous Air Pollutants Emitted from Semiconductor Manufacturing Processes Utilizing QSAR

  • Park, Hyung-Geun;Yeo, Min-Kyeong
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3755-3761
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    • 2013
  • This study aims to assess the ecological risk of the hazardous air pollutants (HAPs) emitted in the semiconductor manufacturing processes in Korea by using Quantitative Structure Activity Relationship (QSAR, EPA, US, EPI $Suite^{TM}$ 4.1). Owing to the absence of environmental standards of hazardous air pollutants in the semiconductor manufacturing processes in Korea, 18 HAPs in the semiconductor field included in both the US EPA NESHAPs and the hazardous air pollutant list of Ministry of Environment in Korea were selected. As a results 8 chemicals (44.4%) of the selected 18 HAPs were VOCs. Cyanides (cyanides) and ethylene oxides (epoxy resins), and tetrachloro-ethylene (aliphatic compounds, halides) showed long half-lives. Cyanide HAPs especially had the highest half-life with the estimated value of 356.533 days. Nickel compounds (heavy metal compounds) possessed the highest water solubility followed by acetaldehyde (aldehyde compounds), ethylene oxides, and 1,4-dioxanes. The halides, including tetrachloro-ethylenes, carbon tetra-chlorides, benzene (aromatic compounds), and lead (heavy metals), are estimated to take the longest time for biodegradation. Tetrachloroethylene, with the acute toxicity end point of 3.685-7.033 mg/L, was assessed to be the most highly toxic substance among the 18 HAPs. However, considering the absence of the HAPs in the common category of log $K_{ow}{\geq}4$and $BCF{\geq}500$, which indicates the standard of bioconcentration potentials, potentials of the bioconcentration are considered to be low.

The Investigation of Detonation Characteristics of Ethylene Oxide Mixture by Using Incident Shock Tube Technique (입사 충격파관을 이용한 에틸렌 옥사이드 혼합물의 데토네이션 특성연구)

  • Moon, J.H.;Chung, J.D.;Kang, J.G.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.2 no.5
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    • pp.121-134
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    • 1994
  • Shock tube investigation of ethylene oxide-$0_{2}-N_{2}$ mixture have been performed to reveal detonation characteristics of the mixture in terms of detonation pressure and speed. Theoretical calculation of thermodynamic parameters at the Chapmann-Jouguet detonation of the mixture has been also performed. A comparision of the observed results with the calculated ones can lead us to predict the detonation parameters of ethylene oxide in an artificial air. In addition, we have observed ignition delay times of ethylene oxide mixtures. The best fit of the observed delay times to Arrhenius gas kinetic relation gives : ${\tau}=10^{-144}{e{xp}}(E_a/RT)[C_{2}H_{4}O]^{-4.8}[O_{2}]^{-12.4}[N_{2}]^{-14.1}$ $E_a=3.67kcal/mole$ The observed activation energy is markedly reduced, compared with the case of ethylene oxide diluted in Ar. It could be due to the factor that $N_2$ play a role as detonation promoter yielding very reactive NOx radicals.

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