• Carbon letters
• /
• v.10 no.4
• /
• pp.314-319
• /
• 2009

The surface treatment effects of reinforcement filler were investigated based on the dynamic mechanical properties of mutiwalled carbon nanotubes (MWCNTs)/epoxy composites. The as-received MWCNTs(R-MWCNTs) were chemically modified by direct oxyfluorination method to improve the dispersibility and adhesiveness with epoxy resins in composite system. In order to investigate the induced functional groups on MWCNTs during oxyfluorination, X-ray photoelectron spectroscopy was used. The thermo-mechanical property of MWCNTs/epoxy composite was also measured based on effects of oxyfluorination treatment of MWCNTs. The storage modulus of MWCNTs/epoxy composite was enhanced about 1.27 times through oxyfluorination of MWCNTs fillers at $25^{\circ}C$. The storage modulus of oxyfluorinated MWCNTs (OF73-MWCNTs) reinforced epoxy composite was much higher than that of R-MWCNTs/epoxy composite. It revealed that oxygen content led to the efficient carbon-fluorine covalent bonding during oxyfluorination. These functional groups on surface modified MWCNTs induced by oxyfluorination strikingly made an important role for the reinforced epoxy composite.

• Journal of the Korean Ceramic Society
• /
• v.35 no.4
• /
• pp.371-377
• /
• 1998

The effect of epoxy resin on the water stability of HAC/PVA based MDF cement composite were stu-died through the three different forming methods calendering extruding and warm pressing. In prexing step the epoxy resin was added in 5-15wt% of cement weight. The 3-point flexural strength of each dry and wet specimen which were immersed in water during 3. 7, 14 days was estmated and the mi-crostructural change of epoxy resin-added MDF cement composite due to water immersion was charac-terized by scanning electron microscopy. As the addition amount of epoxy resin the im-provement of water stability of MDF cement composite was achieved in most case. Especially through the warm press forming method the effectiveness of epoxy resin addition to the water stability was enhanced. When the epoxy resin was added by 5wt% to 7wt% the optimum flexural strength and water stability

• Carbon letters
• /
• v.11 no.2
• /
• pp.107-111
• /
• 2010

We prepared the amine epoxy adducts (AEA)/thin multiwalled carbon nanotubes (TWCNTs) composite particles using nonsolvent based methods including dry mechano-chemical bonding(MCB) process and supercritical fluid (SCF) process. The resulting TWCNTs/AEA composite particles have been used as curing agents for urethane modified bispheol A type epoxy resin. The thermal, thermomechanical properties of the epoxy resins cured with TWCNTs/AEA composite particles were measured by DMA and the dispersion of CNT was characterized by SEM. Because of high degree of CNT dispersion, thermal and mechanical properties of the epoxy resin cured with TWCNTs/AEA composite particles prepared by SCF process are better than those cured with mechano-chemically prepared TWCNTs/AEA composite particles.

• Journal of the Korean Wood Science and Technology
• /
• v.44 no.3
• /
• pp.406-414
• /
• 2016

The lignin-based carbon nanofiber reinforced epoxy composite has been prepared by immersing carbon nanofiber mat in epoxy resin solution in order to evaluate the physical and mechanical properties. The thermal and mechanical properties of the carbon nanofiber reinforced epoxy composite were analyzed using thermogravimetric analysis (TGA), differential scanning calorimeter (DSC) and tensile tester. It was found that the thermal properties of the carbon nanofiber reinforced epoxy composite improved, with its glass-transition temperature ($T_g$) increased from $90.7^{\circ}C$ ($T_g$ of epoxy resin itself) to $106.9^{\circ}C$. The tensile strengths of carbon nanofiber mats made from both lignin-g-PAN copolymer and PAN were 7.2 MPa and 9.4 MPa, respectively. The resulting tensile strength of lignin-based carbon nanofiber reinforced epoxy composite became 43.0 MPa, the six times higher than that of lignin-based carbon nanofiber mats. The carbon nanofibers were pulled out after the tensile test of the carbon nanofiber reinforced epoxy composite due to high tensile strength (478.8 MPa) of an individual carbon nanofiber itself as well as low interfacial adhesion between fibers and matrices, confirmed by the SEM analysis.

• Carbon letters
• /
• v.24
• /
• pp.41-46
• /
• 2017

The microstructure, flexural properties, electrical conductivity, thermal conductivity and electromagnetic interference (EMI) shielding effectiveness (SE) of epoxy composites filled with multi-walled carbon nanotubes (CNTs), exfoliated graphite nanoplatelets (xGnPs) and CNT-xGnP hybrid filler were investigated. The EMI SE of the CNT-xGnP hybrid composite was higher than 25 dB at 100 MHz while that of the xGnP based composite was almost zero. The flexural modulus of the CNT-xGnP based epoxy composite continuously increased to 3.32 GPa with combined filler content up to 10 wt% while that of the CNT based epoxy composites slightly decreased to 1.96 GPa at 4 wt% CNT, and dropped to 1.57 GPa at 5 wt% loading, which is lower than that of epoxy. The CNT and CNT-xGnP samples had the same EMI SE at the same surface resistivity, because samples with the same surface conductivity have the same amount of the charge carriers.

• Carbon letters
• /
• v.21
• /
• pp.1-7
• /
• 2017

The effects of ammonia-treated graphene oxide (GO) on composites based on epoxy resin were investigated. Ammonia solutions of different concentrations (14-28%) were used to modify GO. Nitrogen functional groups were introduced on the GO surfaces without significant structural changes. The ammonia-treated GO-based epoxy composites exhibited interesting changes in their mechanical properties related to the presence of nitrogen functional groups, particularly amine ($C-NH_2$) groups on the GO surfaces. The highest tensile and impact strength values were 42.1 MPa and 12.3 J/m, respectively, which were observed in an epoxy composite prepared with GO treated with a 28% ammonia solution. This improved tensile strength was 2.2 and 1.3 times higher than those of the neat epoxy and the non-treated GO-based epoxy composite, respectively. The amine groups on the GO ensure its participation in the cross-linking reaction of the epoxy resin under amine curing agent condition and enhance its interfacial bonding with the epoxy resin.

• Textile Coloration and Finishing
• /
• v.27 no.1
• /
• pp.11-17
• /
• 2015

Recently, super fiber reinforced composite materials are widely used in many industries due to high mechanical properties. In this study, 2 different types of composite materials were manufactured in order to compare their mechanical properties. Carbon and Aramid fibers were used for reinforcement materials and Bisphenol-A type epoxy resin was for matrix. Two kinds of fiber-reinforced materials were manufactured by RIM(Resin Injection Molding) method. Before manufacturing composite materials, the optimal manufacturing and curing process condition were established and the ratio of reinforcement to epoxy resin was discussed. FT-IR analysis was conducted to clarify the structure of epoxy resin. Thermal and mechanical property test were also carried out. The cross-section of composite materials was observed using a scanning electron microscope(SEM).

• International Journal of Ocean System Engineering
• /
• v.3 no.3
• /
• pp.136-141
• /
• 2013

The present research was aimed at comparing performance of metallic and polymer composite shells of a typical underwater vessel of length and inner diameter of 1650 mm and 350 mm respectively, based on the critical buckling pressure for operating depth of 1000 m using ANSYS. High strength steel, aluminium alloy, titanium alloy, glass / epoxy and carbon / epoxy materials were examined. The results indicated weight savings of 46 % in carbon/epoxy and 31 % in glass / epoxy when compared with high strength steel, based on the thickness of the shell for sustaining 10 MPa buckling pressure.

• Journal of the Korean Applied Science and Technology
• /
• v.31 no.3
• /
• pp.486-491
• /
• 2014

We have been fabricated Thin-walled carbon nanotubes (TWNTs)/amine epoxy additives composite using Eco-friendly solvent system such as supercritical process and dry mixed process. TWNTs/amine epoxy additives composite has used as a curing agent for urethane based bisphenol A type epoxy resin. The thermo-mechanical property of the epoxy resin cured by TWNTs/amine epoxy additives composite is characterized by dynamic mechanical analysis(DMA) and dispersability of the nanotubes in the epoxy matrix is also confirmed by scanning electron microscope(SEM). As a results, the epoxy resin cured by TWNTs/amine epoxy additives composite with supercritical process shows enhanced dispersability of the TWNTs in the matrix and thermo-mechanical property when compare to dry mixed process.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2002.05a
• /
• pp.219-222
• /
• 2002

A new designed composite archery bow limbs are developed in this study. The characteristic F-X curve in current recurve archery bow is first studied for a reference. Based on this, a composite archery bow is designed to obtain a higher strain Energy and good vibration performance. Carbon/Epoxy prototype archery bow limbs are made from autoclaving and test on INSTRON 5567 test machine. The experimental results show that the new designed archery bow is powerful and stable.