• Title/Summary/Keyword: Environmental Upgrading

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Evaluation of the Efficiency of Solvent Systems to Remove Acetic Acid Derived from Pre-pulping Extraction

  • Park, Seong-Jik;Moon, Joon-Kwan;Um, Byung-Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.5
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    • pp.447-455
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    • 2013
  • Hemicellulose extract obtained by pre-pulping extraction of woodchips, is very diluted acidic in nature. The major component responsible for this weak acidity is acetic acid, present in levels up to 5~10 g/L. Here, we report an exploratory study on the extract upgrading by reactive solvent extraction of acetic acid as well as ASPEN simulation. In this study, liquid-liquid equilibria for the ternary systems (water + acetic acid + ethyl acetate) were measured at the temperature of 298.15 K and 10 (pH = 2.02), 5 (pH = 2.17), and 1 (pH = 2.48) percent of acetic acid samples were used to carry out liquid-liquid extraction studies using ethyl acetate. In a one-stage batch experiment, 96.0% of acetic acid could be extracted for the solvent when the ratio of organic-to-aqueous phases is 4:1. For simulation results, they were used to estimate the interaction parameters between each of the three compounds of the systems studied for the NRTL and UNIQUAC models. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the two models.

Recycling Technologies of Aluminum (알루미늄의 리사이클링 기술)

  • Sohn, Ho-Sang
    • Resources Recycling
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    • v.28 no.2
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    • pp.3-13
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    • 2019
  • Aluminum is the most abundant metal and the second most plentiful metallic element in the earth's crust, after silicon. Aluminum is a light, conductive, and corrosion resistant metal with strong affinity for oxygen. However, the primary aluminum production process is highly energy intensive. The recycling of aluminum scrap reduces the energy consumption and environmental burden, comparing to the primary metal production. However, the amount of the recovered metal from scrap is limited because of the difficulties to remove the impurities in the scrap. This work provides an overview of the aluminum production and recycling process, from the preparation of alumina to the scrap upgrading and the melting process.

Technical preparedness in Southeast Asia region for onshore dismantling of offshore structures: Gaps and opportunities

  • Jing-Shuo Leow;Jing-Shun Leow;Hooi-Siang Kang;Omar Yaakob;Wonsiri Punurai;Sari Amelia;Huyen Thi Le
    • Ocean Systems Engineering
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    • v.13 no.1
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    • pp.79-95
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    • 2023
  • An onshore dismantling yard is an important part in the supply chain of the offshore oil and gas decommissioning industry. However, despite having more than 500 offshore structures to be decommissioned in the Southeast Asia region, there are a very limited number of well-equipped dismantling yards to fully execute the onshore dismantling. Recent investigations discovered that shipbuilding and offshore structure fabrication yards are still potential options for upgrades to include dismantling. Despite the huge potential opportunities from upgrading to dismantling, research studies on this area are relatively scarce, and most past studies mainly focused on the North Sea region. To date, the potential opportunities of Southeast Asia and Malaysia yards to develop onshore dismantling capability are still unclear. The aim of this study is to identify the criteria to develop a technical preparedness checklist to evaluate an onshore dismantling yard; consequently, this will assist with assessing and bridging the gaps and identify the opportunity of developing an onshore dismantling yard in Southeast Asia region. Requirements for onshore dismantling and related rules and regulations have been investigated and summarized in the form of checklist. Findings from this study can help local oil and gas operators to pursue more local solutions and resilient supply chain performance.

Suitability of Counter-current Model for Biogas Separation Processes using Cellulose Acetate Hollow Fiber Membrane (셀룰로오스 아세테이트 중공사 분리막을 이용한 바이오가스 분리에 대한 향류 흐름 모델의 적용성)

  • Jung, Sang-Chul;Kwon, Ki-Wook;Jeon, Mi-Jin;Jeon, Yong-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.4
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    • pp.43-52
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    • 2020
  • As the membrane gas separation technology grows, various models were developed by numerous researchers to describe the separation process. In this work, the counter-current model was compared thoroughly with experimental data. Experimentally, hollow fiber membrane using CA module was prepared for the separation of biogas. The pure gas permeation properties of membrane module for methane, nitrogen, oxygen, and carbon dioxide were measured. The permeance of CO2 and CH4 were 25.82 GPU and 0.65 GPU, respectively. The high CO2/CH4 selectivity of 39.7 was obtained. the separation test for three different simulated mixed gases were carried out after pure gas test, and the gas concentration of the permeate at various stage-cut were measured from CA membrane module. Results showed that the experimental data agreed with the numerical simulation. A mathematical model has implemented in this study for the separation of biogas using a membrane module. The finite difference method (FDM) is applied to calculate the membrane biogas separation behaviors. Futhermore, the counter-current model can be considered as a convenient model for biogas separation process.

Development Status of BTL (Biomass to Liquid) Technology (BTL(Biomass to Liquid) 기술 현황)

  • Chae, Ho-Jeong;Jeong, Kwang-Eun;Kim, Chul-Ung;Jeong, Soon-Yong
    • Journal of Energy Engineering
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    • v.16 no.2
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    • pp.83-92
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    • 2007
  • In view of stringent environment regulations to control the emission of green house gases and also depleting fossil fuel reserves, it is high quality desirable to develop alternative technologies to produce high quality fuels. To this end Biomass to Liquid (BTL) technology has received much attention in recent years. BTL process generally consists of gasification of biomass to produce bio-syngas, cleaning and control of $H_{2}/CO$ mole ratio of bio-syngas and Fischer-Tropsch synthesis & upgrading systems. Choren, Germany has first developed the commercial BTL process using unique gasification system i.e., Carbo-V. A new technology to remove tars and BTX has been developed by ECN in Netherlands employing a gasification system combined with OLGA technology. Several other countries including USA and Japan are showing great interest in BTL technology. Thus in view of our national energy security and also the environmental regulations, it is essential to develop alternative technologies like BTL in order to meet the increasing demand of energy though our insufficient biomass resources. In this paper we present an overview and development status of BTL-diesel technology.

The Analysis of the Educational Conditions of Interior Design in Korea - Focused on the Curriculum of 4 year Universities (한국 실내디자인 분야의 교육현황 분석 - 4년제 대학교의 교과과정을 중심으로 -)

  • 신경주
    • Korean Institute of Interior Design Journal
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    • no.38
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    • pp.3-13
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    • 2003
  • Now that 15 years have passed since its introduction to 4 year college in Korea and we have 51 majors in the field of Intoner design established at 47 universities as of 2003, we are in the position to seek the improvement of its educational qualify. With a view to provide data for the setup of proper educational purpose, it has classified their divisions(departments) according to their major names and belonged colleges of the universities and considered their geographical distributions, groupings of curriculum, their framing and features of a standard curriculum. 1)Divisions of the universities where the major of interior design belongs are divided into three categories of design division (design 8t arts, arts), home economics division (home economics, natural science) and architectural division. For the development of the major, universities to which circumstances permit are recommended to establish an independent college of interior design following the . cases in the US. 2) Geographical preponderance of interior design major on Seoul and Gyeongsang Province is desired to be improved. 3) Curriculum of interior design, which is classified into introduction, history of interior design, theory of interior design, design of interior space, digital technology, design elements of inner space, technology of interior design, behavior of environmental psychology, design management and other subjects, was made into a table by divisions. To sum up, curriculum of interior design concentrates on basic design theory throughout all divisions. In connection with the selection of division by high school-graduates or their parents, design division is recommended for those who desire to major in design elements and design management, home economics division for those who desire to major in space design and behavior of environmental psychology and architectural division for those who desire to major in Interior space design, interior design technology and regulations. 4) This research can contribute to the settlement of desirable curriculum for the interior design education, thus upgrading the education level of the major in Korea.

Study on the response surface optimization of online upgrading of bio-oil with MCM-41 and catalyst durability analysis

  • Liu, Sha;Cai, Yi-xi;Fan, Yong-sheng;Li, Xiao-hua;Wang, Jia-jun
    • Environmental Engineering Research
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    • v.22 no.1
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    • pp.19-30
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    • 2017
  • Direct catalysis of vapors from vacuum pyrolysis of biomass was performed on MCM-41 to investigate the effects of operating parameters including catalyzing temperature, catalyzing bed height and system pressure on the organic yields. Optimization of organic phase yield was further conducted by employing response surface methodology. The statistical analysis showed that operating parameters have significant effects on the organic phase yield. The organic phase yield first increases and then decreases as catalyzing temperature and catalyzing bed height increase, and decreases as system pressure increases. The optimal conditions for the maximum organic phase yield were obtained at catalyzing temperature of $502.7^{\circ}C$, catalyzing bed height of 2.74 cm and system pressure of 6.83 kPa, the organic phase yield amounts to 15.84% which is quite close to the predicted value 16.19%. The H/C, O/C molar ratios (dry basis), density, pH value, kinematic viscosity and high heat value of the organic phase obtained at optimal conditions were 1.287, 0.174, $0.98g/cm^3$, 5.12, $5.87mm^2/s$ and 33.08 MJ/kg, respectively. Organic product compositions were examined using gas chromatography/mass spectrometry and the analysis showed that the content of oxygenated aromatics in organic phase had decreased and hydrocarbons had increased, and the hydrocarbons in organic phase were mainly aliphatic hydrocarbons. Besides, thermo-gravimetric analysis of the MCM-41 zeolite was conducted within air atmosphere and the results showed that when the catalyst continuously works over 100 min, the index of physicochemical properties of bio-oil decreases gradually from 1.15 to 0.45, suggesting that the refined bio-oil significantly deteriorates. Meanwhile, the coke deposition of catalyst increases from 4.97% to 14.81%, which suggests that the catalytic activity significantly decreases till the catalyst completely looses its activity.

Numerical Formulation of Consolidation Based on Finite Strain Analysis (대변형 압밀방정식의 수식화)

  • Shin, Ho-Sung;Lee, Seung-Rae
    • Journal of the Korean Geotechnical Society
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    • v.29 no.6
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    • pp.77-86
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    • 2013
  • Embankments on soft ground experience significant deformation during time-dependent consolidation settlement, as well as an initial undrained settlement. Since infinitesimal strain theory assumes no configuration change and minute strain during deformation, finite strain analysis is required for better prediction of geotechnical problems involving large strain and geometric change induced by imposed loadings. Updated Lagrangian formulation is developed for time-dependent consolidation combining both force equilibrium and mass conservation of fluid, and mechanical constitutive equation is written in Janumann stress rate. Numerical convergence during Newton's iteration in large deformation analysis is improved by Nagtegaal's approach of considering the effect of rotation in mechanical constitutive relationship. Numerical simulations are conducted to discuss numerical reliability and applicability of developed numerical code: deformation of cantilever beam, two-dimensional consolidation. The numerical results show that developed formulation can efficiently describe large deformation problems. Proposed formulation is expected to facilitate the upgrading of a numerical code based on infinitesimal strain theory to that based on finite strain analysis.

Landscape Management Strategies Based on Landscape Assessment of Riparian Buffer Zone in the Han River: Focused on Gyeongan Stream (경관평가 기반 수변구역의 경관관리 전략 - 경안천 수변구역을 대상으로 -)

  • Park, Chang Sug;Bae, Min-Ki
    • Journal of Environmental Impact Assessment
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    • v.21 no.6
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    • pp.903-916
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    • 2012
  • We need to use aesthetic landscape assessment(ALA) as the means of riparian buffer zone(RBZ) management. This study verified the political validity of designation policy of RBZ and land purchase policy. The purpose of this study was to propose RBZ landscape management strategies through ALA of RBZ in Gyeongan Stream for the better attractive and healthy riparian landscapes. The natural type landscape units(LUs) covered 40.9% of the entire area and the cultivated land type LUs covered 20.58%. Landscape assessment consisted of landscape quality and landscape integration assessment. The criteria for assessing landscape quality(LQ) were naturalness, interest, uniqueness, and landscape function. LQ was ranked into five grades using a matrix. The landscape integration assessment consisted of an inner integration assessment in each LU and outer integration assessment among LUs. To review the propriety of designating the riparian area and the riparian ecological belt, differences in ecological appraisal and aesthetic valuation were reviewed through a t-test, Oneway ANOVA, and logistic analysis. The results of ALA, 29.15% of the entire area scored at grade 1 in LQ, while 31.95% scored at grade 5, indicating that grade 5 areas occupied a high share. Surveyed areas were divided into designated RBZ and undesignated RBZ. Results indicated that designated RBZ scored grade 1 in LQ took up 33.2% of the total, significantly higher than the 23.3% taken up by undesignated RBZ. When examined according to buffer distance, grade 1 areas within 50m took up 50.2% of the total area, lower than the 32.7% at buffer distances of 500m-1km. Results indicated a 1% statistically significant difference. Accordingly, analysis was undertaken for the expansion of designation of the riparian area and the selection of appropriate land for formation of a riparian ecological belt, and was designated at priority 1 and 2 for land purchase. This study can also contribute to the formation of a riverine eco-belt through discovery of design factors for upgrading the ecology, aesthetics, and landscape of the riparian area and application in determining land purchase priorities.

Investigation of Demand Technology and Construction of Technology Roadmap for Short and Middle-term Research and Development with Focus on the Consensus Link Between Fisheries Specialists and Managers in Marine Production Field (해양생산분야의 요구기술 수요조사 및 전문가의 의견을 반영한 단·중기 기술 로드맵 작성 연구)

  • LEE, Dae-Jae
    • Journal of Fisheries and Marine Sciences Education
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    • v.17 no.2
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    • pp.193-208
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    • 2005
  • The object of this study is to provide a framework of increasing the effectiveness of the R&D planning of experts in fisheries and the education of students with the theoretical background and analytical skills through the adoption of technology roadmapping process in the marine production industry. The study was conducted by fact-finding surveys and the response content for surveys obtained from each expert advisor in the field of fisheries and maritime affairs such as fishery industries, some government organizations and research institutes including the Ministry of Maritime Affairs and Fisheries (MOMAF), National Fisheries Research and Development Institute (NFRDI) and fisheries-related universities was analyzed. The major implementation tasks to effectively achieve the basic goals of technology roadmap for short and middle-term research and development in the fisheries production field are as follows: 1. Research in order to achieve the realization of community-based resource management fisheries or fishermen-oriented co-management fisheries with paradigm shift in fisheries management. 2. Research in order to derive the construction of cost reducing and manpower saving systems in fishery-related science, technology and engineering. 3. Research in order to create the high value-added fisheries products with a focus on the upgrading of processing, freezing and refrigerating facilities, the reduction of logistics costs and the minimization of distribution steps. 4. Research in order to achieve the realization and development of environmental-friendly fisheries and internationally competitive fisheries through restructuring the entire fishing industries, in particular, small-scale fisheries. 5. Research in order to achieve the effective utilization of fisheries resources with a new creation of clean and living marine environment by fisherman under the balanced management and protection of marine living resources and fishing grounds.