• 한국세라믹학회지
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• 제37권3호
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• pp.271-279
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• 2000

5 m/o Yb-doped SrCeO3 proton conductor was prepared by a solid state reaction method and its total electriccal conductivity measured as a function of both oxygen partial pressure and water vapor partial pressure in the temperature range of 500~100$0^{\circ}C$. From the total conductivity have been deconvoluted the partial conductivities of oxide ions, protons, and holes, respectively, on the basis of the defect model proposed. The equilibrium constant of hydrogen-dissolution reaction, proton concentration, and mobilities of oxygen vacancies and protons have subsequently been evaluated. It is verified that SrCe1-xYbxO3 is a mixed conductor of holes, protons and oxide ions and the proton conduction prevails as temperature decreases and water vapor pressure increases. The heat of water dissolution takes a representative value of $\Delta$HoH=-(140$\pm$20) kJ/mol-H2O, but tends to be less negative with increasing temperature. Migration enthalpies of proton and oxygen vacancy are extracted as 0.83$\pm$0.10 eV and 0.81$\pm$0.01 eV, respectively.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2007년도 동계학술발표대회 논문집
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• pp.618-622
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• 2007

In the present study, the cooling and heating operation characteristics of a multi-heat pump have been experimentally investigated for the number of the indoor units(A, B, C) and the operating conditions. The heat pump was controlled by an inverter scroll compressor. The performance of the heat pump was measured by the multi-calorimeter of an air enthalpy method. Cooling and heating capacities and COPs were obtained at the cooling and heating temperature conditions and the setting temperatures of an indoor unit. With increasing the operation frequency of the compressor, the cooling and heating capacities of the heat pump increased linearly. The operation frequency region of the compressor was different as the combination of the indoor unit and the cooling/ heating condition.

• Bulletin of the Korean Chemical Society
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• 제25권11호
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• pp.1645-1647
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• 2004

Potential energy surfaces for the reaction Al + $O_2{\to}$AlO + O have been calculated with the multireference configuration interaction (MRCI) method using molecular orbitals derived from the complete active space selfconsistent field (CASSCF) calculations. The end-on geometry is the most favourable for the reaction to take place. The small reaction barrier in the present calculation (0.11 eV) is probably an artefact related to the ionicneutral avoided crossing. The charge analysis implies that the title oxidation reaction occurs through a harpooning mechanism. Along the potential energy surface of the reaction, there are two stable intermediates of $AlO_2(C_{{\infty}v}$ and $C_{2v}$) at least 2.74 eV below the energy of reactants. The calculated enthalpy of the reaction (-0.07 eV) is in excellent agreement with the experimental value (-0.155 eV) in part due to the fortuitous cancellation of errors in AlO and $O_2$ calculations.

• 설비공학논문집
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• 제28권12호
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• pp.477-482
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• 2016

Airtight containers have been widely used in many industries and household. They need a packing for sealing between the inside and outside. Previous packing materials have some drawbacks like stench, stickiness, and difficulty of applying to automated manufacturing systems. So, a new packing material which is harmless and suitable for automation is needed. This study performed a hot plate welding process of thermoplastic elastomer (TPE) as the packing material. The hot plate welding process included a phase change process of solidification and melting. The porosity-enthalpy method was adopted in order to simulate phase change problems. The TPE showed non-Newtonian fluid characteristics during the melting process. Since properties of SEBS are not well-defined, we established TPE properties by observing the melting behavior of TPE. In order to find an optimized condition, a parametric study including packing thickness, shapes, hot plate temperature, and thermal resistance, was conducted.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 학술대회 논문집 전문대학교육위원
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• pp.88-93
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• 2002

$Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$ and $Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}:Co^{2+}$ + single crystals were grown by CTR method. The grown single crystals have defect chalcopyrite structure with lattice constant a= 5.5966A. c= 10.8042${{\AA}}$ for the pure. a= 5.6543${{\AA}}$. c= 10.8205${{\AA}}$ for the Co-doped single crystal. respectively. The optical energy band gap was given as indirect band gap. The optical energy band gap was decreased according to add of Co-impurity. Temperature dependence of optical energy band gap was fitted well to the Varshni equation. From this relation. we can deduced the entropy. enthalpy and heat capacity. Also. we can observed the Co-impurity optical absorption peaks assigned to the $Co^{2+}$ ion sited at the $T_d$ symmetry lattice and we consider that they were attributed to the electron transitions between energy levels of ions.

• 한국산학기술학회논문지
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• 제16권6호
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• pp.4253-4259
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• 2015

본 연구에서는 자연외기를 활용하여 건물의 에너지절약을 위한 외기냉방제어 시스템에 대하여 다양한 제어방법에 따른 제어특성 및 에너지 소비량에 미치는 영향에 관해 시뮬레이션 연구를 수행하였다. 연구 방법으로는 TRNSYS 프로그램을 활용하여 시스템 해석 모델링을 수행하였으며, 외기 냉방을 하지 않은 경우와 기존의 외기냉방 제어방법들을 적용하였을 경우에 대해 제어성능에 대한 비교 분석이 이루어졌다. 연구 결과로 외기온도 변화에 따라 적절한 외기도입 온도조건을 선정하는 것이 에너지 절감에 효과적이며, 외기와 환기온도를 비교하여 온도제어하는 방법이 에너지 절감효과가 가장 크게 나타남을 알 수 있었다.

• 한국표면공학회지
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• 제26권4호
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• pp.192-202
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• 1993

The characteristics of the high-performance ceramic coatings fabricated on the optimum processings con-ditions for the atmospheric plasma spraying are evaluated by various material tests and analyses. The opti-mum processing parameters for the plasma spraying are determined by using the two-level orthogonal arrays of fractional factorial testing method as a statistical approach. Material tests for the coating specimens are carried out to evaluate microstructure, hardness, adhesion strength, and deposition efficiency. The properties of Al2O3-13%TiO2 coating are discussed with regard to the effective processings parameters. The decarburization effects of WC-12%Co coating is examined by XRD analysis in terms of the arc power and the secondary gas species. The hardness of Al2O2-13%TiO2 coating is increased with the arc power and shows the maximum value at around 40 lpm of Ar gas flowrate, which appears to be the most critical parame-ter on the deposition efficiency. For reducing the decarburization of WC-12%Co coating, the injection of inert He gas instead of reactive H2 gas as a secondary gas is more effective than the dropping of arc power to lessen the plasma enthalpy.

• Bulletin of the Korean Chemical Society
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• 제4권3호
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• pp.115-119
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• 1983

The ionic association constants (K) of 2, N-dimethyl pyridinium iodide (2NDMPI) in 95 volume percentage ethanol-water mixture were determined by a modified UV and conductance method at $20^{\circ}C{\sim}50^{\circ}C$ under 1 to 2000 bars. The K values increase with increasing pressure and decrease with temperature. The total partial molar volume change (${\Delta}V$) has relatively small negative value and the absolute ${\Delta}V$ value decrease with increasing pressure and temperature. The ion size (a) and solvation number (n) of 2NDMPI were about 5 $\AA$ and changed from 1 to 3 with decreasing temperature. Other thermodynamic parameters such as enthalpy (${\Delta}H^{\circ}$) and entropy (${\Delta}S^{\circ}$) for the equilibrium of the 2NDMPI were evaluated. From all the parameters mentioned above, we came to conclusion that the electrostriction effect of 2NDMPI in the ethanol-water mixture is enhanced with increasing pressure and decreasing temperature.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2012년도 제38회 춘계학술대회논문집
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• pp.397-402
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• 2012

본 논문에서는 미지의 두 열물성 값인 열전도율과 열확산율을 구하기 위하여 Levenberg-Marquardt 방법에 의한 역해석 기법을 도입하였다. 일차원 열전도 문제에 대하여 연산식을 유도하였으며, 시편에 대하여 두 지점의 온도 및 입력유동의 열유속 측정값을 적용하였다. 예측된 열전도율 및 열확산율은 알려진 그라파이트 시편에 대한 열물성 값과 비교하였으며 그 결과 본 논문에서 제시된 역해석 예측 기법 실험의 유효성이 파악되었다.

• International Journal of Air-Conditioning and Refrigeration
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• 제17권4호
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• pp.129-134
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• 2009

The objectives of this paper are to study the effects of thermal and geometric conditions on the performance of indoor heat exchangers with R-410A for Gas Engine Driven Heat Pump (GHP) application and to find the optimum design conditions of indoor heat exchangers by parametric analysis for the key parameters. The key parameters are number of tube row, number of tube pipe, fin pitch and transverse tube pitch. In the air side, moisture out of the humid air condenses on the fin surface while the refrigerant (R-410A) boils inside the smooth tube. Therefore this study uses Log Mean Enthalpy Difference (LMHD) method to analyze the heat transfer from the humid air to the refrigerant. This study determines the heat exchanger size, air side/refrigerant side pressure drop and overall heat transfer coefficient. Optimum design conditions for the key parameters are also determined by the parametric analysis. The results show that number of rows and pipes, fin pitch have significant effect on the heat exchanger size. It is also found that the tube length of the louver fin is $17{\sim}30%$ shorter than that of the plate fin.