• Title/Summary/Keyword: Enhancement of conductivity

Search Result 195, Processing Time 0.023 seconds

Synthesis and Properties of Polyimide Composites Containing Graphene Oxide Via In-Situ Polymerization

  • Zhu, Jiadeng;Lee, Cheol-Ho;Joh, Han-Ik;Kim, Hwan Chul;Lee, Sungho
    • Carbon letters
    • /
    • v.13 no.4
    • /
    • pp.230-235
    • /
    • 2012
  • In this study, reduced graphene oxide/polyimide (r-GO/PI) composite films, which showed significant enhancement in their electrical conductivity, were successfully fabricated. GO was prepared from graphite using a modified Hummers method. The GO was used as a nanofiller material for the preparation of r-GO/PI composites by in-situ polymerization. An addition of 20 wt% of GO led to a significant decrease in the volume resistivity of composite films by less than nine orders of magnitude compared to that of pure PI films due to the electrical percolation networks of reduced GO created during imidization within the films. A tensile test indicated that the Young's modulus of the r-GO/PI composite film containing 20 wt% GO increased drastically from 2.3 GPa to 4.4 GPa, which was an improvement of approximately 84% compared to that of pure PI film. In addition, the corresponding tensile strength was found to have decreased only by 12%, from 113 MPa to 99 MPa.

Characterization and Gas-sensing Performance of Spray Pyrolysed In2O3 Thin Films: Substrate Temperature Effect

  • khatibani, A. Bagheri;Ziabari, A. Abdolahzadeh;Rozati, S.M.;Bargbidi, Z.;Kiriakidis, G.
    • Transactions on Electrical and Electronic Materials
    • /
    • v.13 no.3
    • /
    • pp.111-115
    • /
    • 2012
  • Spray pyrolysis method was applied for the preparation of indium oxide ($In_2O_3$) thin films, by varying the substrate temperature range from 400-$600^{\circ}C$. All the samples were characterized at room temperature by using X-Ray diffraction, Scanning electron microscopy, Atomic Force Microscopy, Hall Effect and UV-Visible spectrophotometry. The optimal substrate temperature required for obtaining films of high crystallographic quality was $575^{\circ}C$. By comparing optical transmittance and electrical conductivity it was observed that the best figure of merit for these films was achieved for the same temperature and electrical resistivity was in the order of ${\rho}=1.47{\times}10^{-1}[{\Omega}cm]$. Gas sensing measurements of the films in ethanol showed enhancement with surface roughness and sheet resistance.

Influence of fin partitioning of a Rayeigh-Bénard cavity at low Rayleigh numbers

  • Zilic, Adis;Hitt, Darren L.
    • Advances in aircraft and spacecraft science
    • /
    • v.5 no.4
    • /
    • pp.411-430
    • /
    • 2018
  • This computational study examines the augmentation of classic 2-D Rayleigh-$B{\acute{e}}nard$ convection by the addition of periodically-spaced transverse fins. The fins are attached to the heated base of the cavity and serve to partition the cavity into 'units' with different aspect ratios. The respective impacts upon heat transfer of the fin configuration parameters - including spacing, height, thickness and thermal conductivity - are systematically examined through numerical simulations for a range of laminar Rayleigh numbers (0 < Ra < $2{\times}10^5$) and reported in terms of an average Nusselt number. The selection of the low Rayleigh number regime is linked to likely scenarios within aerospace applications (e.g. avionics cooling) where the cavity length scale and/or gravitational acceleration is small. The net heat transfer augmentation is found to result from a combination of competing fin effects, most of which are hydrodynamic in nature. Heat transfer enhancement of up to $1.2{\times}$ that for a Rayleigh-$B{\acute{e}}nard$ cavity without fins was found to occur under favorable fin configurations. Such configurations are generally characterized by short, thin fins with half-spacings somewhat less than the convection cell diameter from classic Rayleigh-$B{\acute{e}}nard$ theory. In contrast, for unfavorable configurations, it is found that the introduction of fins can result in a significant reduction in the heat transfer performance.

Low-Temperature Solution Process of Al-Doped ZnO Nanoflakes for Flexible Perovskite Solar Cells

  • Nam, SeongSik;Vu, Trung Kien;Le, Duc Thang;Oh, Ilwhan
    • Journal of Electrochemical Science and Technology
    • /
    • v.9 no.2
    • /
    • pp.118-125
    • /
    • 2018
  • Herein we report on the selective synthesis and direct growth of nanostructures using an aqueous chemical growth route. Specifically, Al-doped ZnO (AZO) nanoflakes (NFs) are vertically grown on indium tin oxide (ITO) coated flexible polyethylene terephthalate (PET) sheets at low temperature and ambient environment. The morphological, optical, and electrical properties of the NFs are investigated as a function of the Al content. Furthermore, these AZO-NFs are integrated into perovskite solar devices as the electron transport layer (ETL) and the fabricated devices are tested for photovoltaic performance. It was determined that the doping of AZO-NFs significantly increases the performance metrics of the solar cells, mainly by increasing the short-circuit current of the devices. The observed enhancement is primarily attributed to the improved conductivity of the doped AZO-NF, which facilitates charge separation and reduces recombination. Further, our flexible solar cells fabricated through this low temperature process demonstrate an acceptable reproducibility and stability when exposed to a mechanical bending test.

Quaternary Ammonium-Based Room Temperature Ionic Liquids as Components of Carbonate Electrolytes for Li-ion Batteries: Electrochemical Performance and Thermal Properties

  • Chernyshov, Denis V.;Shin, Woo Cheol
    • Journal of Electrochemical Science and Technology
    • /
    • v.5 no.4
    • /
    • pp.95-104
    • /
    • 2014
  • Electrochemical performance of Li-ion cells with $LiMn_2O_4$ cathodes and graphite anodes with carbonates electrolytes containing quaternary ammonium-based room temperature ionic liquids (ILs) is investigated. Eight different ILs based on tetraalkylammonium, pyrrolidinium or piperidinium cations paired with bis(trifluoromethylsulfonyl)imide or tris(pentafluoroethyl)trifluorophosphate anions are examined in combination with dimethyl carbonate as a main solvent and fluoroethylene carbonate as a solid electrolyte interface forming agent. It is shown that cycling properties of the cells are strongly affected by the content of ILs in the electrolyte mixtures and its increase corresponds to lower discharge capacity retention. Since viscosity and conductivity of ILs are of a great importance for the electrolytes formulation, some kind of combined parameter should be used for the assessment of IL applicability and calculated values of Walden products for neat ILs represent one of the possible options. Besides, positive effect of ILs on reduction of flammability and enhancement of thermal stability of electrolytes in contact with charged electrodes have been demonstrated by means of self-extinguishing time test and differential scanning calorimetry respectively.

A Study on the Effects of CNC Addition on Electrochemical Properties of Lead-acid Battery (CNC 첨가에 따른 납축전지의 전기화학적 특성연구)

  • Kim, Jee-Hoon;Mun, Jun-Ho;Moon, Seong-Yong;Ku, Bon-Keun;Kim, Ki-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.21 no.3
    • /
    • pp.279-285
    • /
    • 2008
  • CNC (Carbon Nano Colloid) was used as an additive to the positive electrode to improve the discharge performance of sealed lead-acid batteries, The cathode active material ($PbO_2$) has a relatively low utility of less than 60 % compared with other kind of batteries, such as Ni-MH and Lithium ion, In this study, to overcome the above-mentioned problem we investigated the effects of CNC addition on the enhancement of electrical connection with not-utilized $PbO_2$ and resultantly electrical conductivity of electrode, We examined low rate discharge capacities, high rate discharge capacities and internal resistances of the batteries containing various amounts of CNC. From these results, we found out that the addition of CNC into the positive electrode made a significant improvement in high rate discharge capacity, We also suggested the optimum content of CNC material in positive electrode.

An Experimental Study on the Performance of Plastic Plate Heat Exchanger (플라스틱 판형 열교환기의 성능에 관한 실험적 연구)

  • Yoo Seong Yeon;Chung Min Ho;Kim Ki Hyung;Lee Je Myo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.17 no.2
    • /
    • pp.117-124
    • /
    • 2005
  • Aluminum plate heat exchanger, rotary wheel heat exchanger, and heat pipe heat exchanger have been used (or ventilation heat recovery in the air-conditioning system. The purpose of this research is to develop high efficiency plastic plate heat exchanger which can substitute aluminum plate heat exchanger. Because thermal conductivity of plastic is quite small compared to that of aluminum, various heat transfer enhancement techniques are applied in the design of plastic plates. Five types of heat exchanger model are designed and manufactured, which are plate type, plate-fin type, turbulent promoter type, corrugate type, and dimple type. Thermal performance and pressure loss of each heat exchangers are measured in various operating conditions, and compared each other. Test results show that heat transfer performance of corrugate type, turbulent promoter type, and dimple type are increases about $43\%$, $14\%$, and $33\%$ at the equivalent fan power compared to those of plate type, respectively. On the other hand, the heat transfer performance of plate-fin type decreases $9\%$ because fins can not play their own role.

GEOPHYSICAL CHARACTERIZATION OF MARINE CLAYS - FROM GEOTECHNICAL PARAMETER ESTIMATION TO PROCESS MONITORING -

  • Choi, Gye-Chun;Chang, Il-Han;Oh, Tae-Min;Kim, Hak-Sung
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 2010.09c
    • /
    • pp.37-46
    • /
    • 2010
  • Marine clays are soft soil deposits having complicated mineralogy and formation characteristics. Thus, characterization of its geotechnical behavior has been a main issue for geotechnical engineers. Nowadays, the importance and applications of geophysical exploration on marine clays are increasing significantly according to the accuracy, efficiency, and reliability of geophysical survey technology. For marine clays, seismic survey is effective for density and elasticity characterization, while electro-magnetic wave provides the information about the fluid conductivity phenomena inside soil. For practical applications, elastic wave technology can evaluate the consolidation state of natural marine clay layers and estimate important geotechnical engineering parameters of artificially reclaimed marine deposits. Electrical resistivity can provide geophysical characteristics such as particle cementation, pore geometry shape, and pore material phase condition. Furthermore, nondestructive geophysical monitoring is applicable for risk management and efficiency enhancement during natural methane gas extraction from gas hydrate-bearing sediments.

  • PDF

Process Development for Enhancement of High Temperature Thermoelectric Properties in a p-Type Skutterudite (P-형 Skutterudite 소재의 고온 열전물성 제어를 위한 공정 개발)

  • Liu, Peng Ju;Nou, Chang Wan;Choi, Soon-Mok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.33 no.6
    • /
    • pp.495-499
    • /
    • 2020
  • Power factor improvement at high temperatures has been a major research topic for the development of skutterudite thermoelectric materials. Here, we attempted to optimize the process parameters for manufacturing skutterudite materials, especially for p-type systems. We focused on the effect of aging time variation to maximize the high-temperature performance of the Ce-filled Fe3CoSb12 skutterudite system. The optimized aging time was concluded to be a key parameter for the formation of single-phase nanostructures in this p-type skutterudite system. The optimized condition was effective in reducing the bipolar effect at high temperature ranges by increasing the carrier concentration in the p-type system. To confirm the conclusions, the electrical conductivity, Seebeck coefficient, and power factor were measured. The results matched well with the microstructure and with those of an XRD analysis performed for the system.

Experimental Study of Evaporation of Nanofluid Droplet (나노유체 액적의 증발에 관한 실험적 연구)

  • Kim, Yeung Chan
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.37 no.7
    • /
    • pp.647-653
    • /
    • 2013
  • The evaporation characteristics of nanofluid droplets on a heated solid surface were experimentally investigated. The experiments were conducted using pure water and a nanofluid of water mixed with CuO nanoparticles, and the solid surface was made of a copper block heated by a nine cartridge heater. The experimental results showed that the evaporation rate of the nanofluid droplet was higher than that of the pure water droplet on the heated solid surface because nanoparticles increased the thermal conductivity of the nanofluid. Furthermore, it was found that the evaporation rate of the nanofluid droplet increased with the solid surface roughness. This may be because the actual area of the liquid-solid interface increased with the solid surface roughness.