• Carbon letters
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• v.11 no.2
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• pp.112-116
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• 2010

The objective of this study was to evaluate the possibility of simultaneous removal of ammonium, nitrate and phosphorus in water using the zeocarbon. In this study, the surface of zeocarbon was modified by acid because of difficulty in application of water treatment. After surface modification, the strength was enhanced about 62% higher than that of original one. The removal efficiency of ammonium and nitrate using the modified zeocarbon was about 47% and 32%, respectively and were higher than that of zeocarbon. In batch type experiment on the simultaneous removal of ammonium, nitrate and phosphorus, the presence of phosphorus did not have influence on nitrogen removal efficiency. Concomitantly, removal efficiency of phosphorus was obtained was about 35%. This indicates that the surface modified zeocarbon can be applied for simultaneous removal of nitrogen and phosphorus. Consequently, our results could be used as basic data to design of one-stage nitrogen/phosphorus simultaneous removal system.

• Journal of Korean Society on Water Environment
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• v.22 no.3
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• pp.566-571
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• 2006

A sequencing batch biofilm reactor (SBBR) operated with a cycle of anaerobic - aerobic - anoxic - aerobic has been evaluated for the nutrient removal characteristics. The sponge-like moving media was filled to about 10% of reactor volume. The sewage was the major substrate while external synthetic carbon substrate was added to the anoxic stage to enhance the nitrogen removal. The operational results indicated that maximum T-N and T-P removal efficiencies were 97% and 94%, respectively were achieved, while COD removal of 92%. The observations of significant nitrogen removal in the first aerobic stage indicated that nitrogen removal behaviour in this SBBR was different to conventional SBR. Although the reasons for aerobic nitrogen removal has speculated to either simultaneous nitrification and denitrification or anoxic denitrification inside of the media, further researches are required to confirm the observation. The specific oxygen uptake rate (SOUR) test with biofilm and suspended growth sludge indicated that biofilm in SBBR played a major role to remove substrates.

• Journal of Environmental Science International
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• v.19 no.4
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• pp.483-490
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• 2010

The purpose of this study is to investigate the effect of influent phosphorus concentration on the nitrogen and phosphorus removal in sequencing batch reactor(SBR) and sequencing batch biofilm reactors(SBBRs) in order to recover the enhanced biological phosphorus removal (EBPR) capacity at the sludge of the deterioration of EBPR capacity. In SBBRs, comparing to SBR, the organic removal was occurred actively at the 1 st non-aeration period because of the active phosphorus release at this period. However, the variation of TOC removal according to the decrease of influent phosphorus concentration was not clearly shown both in SBR and SBBRs. In case of SBR losing EBPR capacity, the EBPR capacity was not recovered by the decrease of the influent phosphorus concentration from 7.5 mg/L to 0.9 mg/L. The nitrogen removal increased by the decrease of influent phosphorus concentration both in SBR and SBBRs.

• Advances in environmental research
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• v.4 no.4
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• pp.263-271
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• 2015

In this study, the effect of initial nitrate loading on nitrate removal and byproduct selectivity was evaluated in a continuous system. Nitrate removal decreased from 100% to 25% with the increase in nitrate loading from 10 to $300mg/L\;NO_3-N$. Ammonium selectivity decreased and nitrite selectivity increased, while nitrogen selectivity showed a peak shape in the same range of nitrate loading. The nitrate removal was enhanced at low catalyst to nitrate ratios and 100% nitrate removal was achieved at catalyst to nitrate ratio of ${\geq}33mg\;catalyst/mg\;NO_3-N$. Maximum nitrogen selectivity (47%) was observed at $66mg\;catalyst/mg\;NO_3-N$, showing that continuous Cu-Pd-NZVI system has a maximum removal capacity of 37 mg $NO_3{^-}-N/g_{catalyst}/h$. The results from this study emphasize that nitrate reduction in a bimetallic catalytic system could be sensitive to changes in optimized regimes.

• Environmental Engineering Research
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• v.24 no.1
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• pp.107-116
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• 2019

Nitrogen removal, nitrous oxide ($N_2O$) emission and microbial community in sequencing batch and continuous-flow intermittent aeration processes were investigated. Two sequencing batch reactors (SBRs) and two continuous-flow multiple anoxic and aerobic reactors (CMRs) were operated under high dissolved oxygen (DO) (SBR-H and CMR-H) and low DO (SBR-L and CMR-L) concentrations, respectively. Nitrogen removal was enhanced under CMR and low DO conditions (CMR-L). The highest total inorganic nitrogen removal efficiency of 91.5% was achieved. Higher nitrifying and denitrifying activities in SBRs were observed. CMRs possessed higher $N_2O$ emission factors during nitrification in the presence of organics, with the highest $N_2O$ emission factor of 60.7% in CMR-L. SBR and low DO conditions promoted $N_2O$ emission during denitrification. CMR systems had higher microbial diversity. Candidatus Accumulibacter, Nitrosomonadaceae and putative denitrifiers ($N_2O$ reducers and producers) were responsible for $N_2O$ emission.

• Journal of Environmental Science International
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• v.17 no.11
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• pp.1265-1271
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• 2008

Aerated submerged bio-film (ASBF) pilot plant has been developed. The presented studies optimized an inexpensive method of enhanced wastewater treatment. The objectives of this research were to describe pilot scale experiments for efficient removal of dissolved organic and nitrogen compounds by using ASBF reactor in plug-flow reactor (PFR) and improve understanding of dissolved organic matter and nitrogen compounds removal rates with dynamic relationships between heterotrophs and autotrophs in the fixed-film reactor. This research explores the possibility of enhancing the performance of shallow wastewater treatment lagoons through the addition of specially designed structures. This direct gas-phase contact should increase the oxygen transfer rate into the bio-film, as well as increase the micro-climate mixing of water, nutrients, and waste products into and out of the bio-film. This research also investigated the efficiency of dissolved organic matter and ammonia nitrogen removals in the ASBF. As it was anticipated, nitrification activity was highest during periods when the flow rate was lower, but it seemed to decline during times when the flow rate was highest. And ammonia nitrogen removal rates were more sensitive than dissolved organic matter removal rates when flow rates exceeded 2.2 L/min.

• Membrane and Water Treatment
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• v.3 no.2
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• pp.133-140
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• 2012

The overall performance of BNR-MBR, so-called Anoxic-Anaerobic-Aerobic Membrane Bioreactor ($A^3$-MBR), developed for nutrient removal was studied to determine the efficiencies and mechanisms under different solid retention time (SRT). The reactor was fed by synthetic high-rise building wastewater with a COD:N:P ratio of 100:10:2.5. The results showed that TKN, TN and phosphorus removal by the system was higher than 95%, 93% and 80%, respectively. Nitrogen removal in the system was related to the simultaneous nitrification-denitrification (SND) reaction which removed all nitrogen forms in aerobic condition. SND reaction in the system occurred because of the large floc size formation. Phosphorus removal in the system related to the high phosphorus content in bacterial cells and the little effects of nitrate nitrogen on phosphorus release in the anaerobic condition. Therefore, high quality of treated effluent could be achieved with the $A^3$-MBR system for various water reuse purposes.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.493-500
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• 2023

The use of TiO₂ photocatalyst in the production of concrete blocks for the purpose of nitrogen oxide reduction is an issue of controversy due to the conflicting evidence on its effectiveness. Efforts have been made to reduce the level of nitrogen oxides in the environment by using of titanium dioxide (TiO₂). This study examined the effect of incorporating activated carbon into concrete blocks on the reduction of nitrogen oxides released into the atmosphere and the durability of the blocks. The efficiency of photocatalyst was enhanced through the addition of a surrounding conductive substance. The addition of activated carbon resulted in a significant increase in the electrical conductivity of photocatalytic blocks and improved durability. The cement mixture using 5 % TiO₂ and 15 % activated carbon exhibited the optimal mixing ratio for the purpose of nitrogen oxide removal. The effect of the addition of conductive carbon to the photocatalytic blocks was discussed with the results of conductivity, flexural and comprssive strength and nitrogen oxide removal test. The relationship between the addition of conductive carbon to the photocatalytic blocks and its resulting effects have been studied by several tests, including conductivity, flexural and compressive strength, and nitrogen oxide removal.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.3
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• pp.307-312
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• 2011

The potential of algal-bacterial culture was investigated for advanced treatment of animal wastewater. Fed-batch experiments were carried out to examine treatability of nitrogen and phosphorus in different microbial consortium: Chlorella vulgaris, activated sludge, three microalgae strains (Scenedesmus, Microcystis, Chlorella) and Bacillus consortium, and three microalgae strains and sludge consortium. Single culture of C. vugaris showed the better efficiency for nitrogen removal but was not good at organic matter and phosphorus removal compared with activated sludge. Three microalgae and Bacillus consortium was best culture among the culture and consortium for pollutants removal tested in this experiment. Effect of $CO_2$ addition was studied by using three microalgae and Bacillus consortium. $CO_2$ addition enhanced T-P removal efficiency up to 60%. However, removal efficiencies of T-N and ammonia nitrogen reduced on the contrary.

• Journal of Wetlands Research
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• v.21 no.4
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• pp.334-343
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• 2019

A lab-scale vertical flow subsurface (VFS) wetland composed of three parallel columns with polypropylene synthetic fiber as main substrate was operated. Piggery stormwater diluted from swine excreta was fed to the wetland on the basis of three different hydraulic regimes or hydraulic retention time (HRT) of 2, 4, and 8 days with daily internal recirculation. Then, monitoring of common water quality parameters was carried out. Unexpectedly, an increase of effluent COD concentration accompanying the appearance of foams was observed during a distinct period in the wetland with HRT 2, 4, and 8 days, successively. Subsequently, a series of experiments was conducted to investigate the origin of the foams. Foams and the increase of COD concentration were found to be induced by the release of organic matter from the synthetic polypropylene fiber which was fed with piggery stormwater. Meanwhile, nitrogen removal was found to be enhanced during a period which overlapped the distinct foaming period signifying that foaming played two important functions in biological nitrogen removal. Foams which form rapidly and then burst easily could hold up and then release oxygen for nitrification. Foams which contain organic surfactants could serve as carbon sources for denitrification as well. Hence, nitrogen removal was enhanced during the foaming stage. After that, COD concentration decreased slowly to a level prior to the foaming stage, and nitrogen removal efficiency declined as well.