• Title/Summary/Keyword: Energy recycling

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Tungsten Recovery from Tungsten Carbide by Alkali Melt followed by Water Leaching (알칼리 용융 및 수 침출을 이용한 탄화텅스텐으로부터 텅스텐 회수)

  • Kim, Byoungjin;Kim, Suyun;Lee, Jaeryeong
    • Resources Recycling
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    • v.26 no.6
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    • pp.91-96
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    • 2017
  • Tungsten (W) recovery from tungsten carbide (WC) was researched by alkali melt followed by water leaching. The experiments of alkali melt were carried out with the change of the sort of alkali material, heating temperature, and the heating duration. Water leaching of W was performed in the fixed conditions ($25^{\circ}C$, 2 hr., slurry density: 10 g/L). From the mixture of WC and sodium nitrate ($NaNO_3$) in the molar ratio of 1:2, treated at $400^{\circ}C$ for 6 hours, only 63.3% of W might be leached by water leaching. With the increase of sodium hydroxide (NaOH) as a melting additive, the leachability increased. Finally it reached to 97.8 % with the melted mixture of ($WC:NaNO_3:NaOH$) in the ratio of (1:2:2). This imply that NaOH may play a role as a reaction catalyst by lowering Gibb's free energy for alkali melt reaction for WC.

Precipitaion of Acid Mine Drainage Using Coagulants and Flocculants (유기 및 무기응집제를 이용한 산성광산배수 침전 연구)

  • Oh, Taek-Geun;Hwang, Won-Jeong;Lee, Jong-Un;Cha, Jongmun
    • Resources Recycling
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    • v.25 no.3
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    • pp.3-10
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    • 2016
  • The passive treatment was required a large area for the treatment of acid mine drainage (AMD), and pollutants were discharged with mine drainage by the increased flow rate in summer. This study was performed to improve the turbidity and to precipitate the pollutants quickly using coagulants and flocculants in AMD of abandoned mine sites that were difficult to build the passive treatment system. The coagulant PAC (Poly aluminium chloride) and flocculant PAM (Polyacrylamide) were selected to improve turbidity in W mine waters. We also tested the particle size analysis, ICP-OES and/or SEM-EDS for water and sludge samples.

A Study on the Selective Leaching of the Copper Component by Sulfation Process (황산화 배소법에 의한 구리성분의 선택적 침출연구)

  • Kim, Woo Jin;Kim, Joon Soo;Kim, Myong Jun;Tran, Tam;Lee, Jin-Young;Shin, Shun-Myung
    • Resources Recycling
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    • v.25 no.5
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    • pp.57-63
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    • 2016
  • This study were carried out sulfation roasting and selective leaching test for the effective recovery of copper component in concentrate obtained by froth floatation of Autrallian low grade copper ore. The optimum conditions of sulfation roasting were temp. $450^{\circ}C$, $Na_2SO_4$ 2 mole ratio and time 1.5 h, and then selective leaching were room temperature and $H_2O$ or 1M $H_2SO_4$ solutions. Leaching efficiency of optimum sulfation product were 90 wt.% of copper, 20 wt.% of iron and 15wt.% of nickel elements. In this results, it was possible to selective decomposition leaching of the copper component under optimum conditions in this research.

Properties of Shrinkage Reducing Agent used C12A7-Based Slag according to Content of Admixtures (C12A7계(系) 슬래그를 사용(使用)한 수축저감제(收縮低減劑)의 혼합재(混合材) 함량(含量)에 따른 특성(特性))

  • Park, Soo Hyun;Chu, Yong Sik;Seo, Sung Kwan;Park, Jae Wan
    • Resources Recycling
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    • v.22 no.6
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    • pp.12-18
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    • 2013
  • In this Study, it was fabricated that shrinkage reducing agent and mortar used $C_{12}A_7$-based slag enhanced the shrinkage reduction and compressive strength. To reduce cement content, setting time, flow and compressive strength of mortar with varying content of fly ash and blast furnace slag were experimented. The flow increased and setting time delayed as the increase of fly ash and blast furnace slag content. And early strength was lower and long age strength was higher than that of mortar with low content of admixture.

Experimental Study for Separation of Membrane and Recovery of Platinum from MEA (연료전지(燃料電池) 막전극접합체(膜電極接合體)의 막분리(膜分離) 및 백금(白金) 회수(回收)에 관(關)한 연구(硏究))

  • Lee, Jin-A;Kang, Suk-Min;Yoo, Sung-Yeol;Kang, Hong-Yoon;Ryu, Ho-Jin
    • Resources Recycling
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    • v.20 no.4
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    • pp.52-57
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    • 2011
  • Present paper reports a new method to separate the electrolyte membranes and carbon paper without using ultrasonic waves and stirring. In this method, these were separated from fuel cell membrane-electrode assembly(MEA) using the distilled water, butanol and surfactant by dipping method without the dispersion of catalyst particles. Separated carbon paper catalysts and fuel cell Pt/C catalysts were heated in aqua regia at $80{\sim}85^{\circ}C$ and added to precipitant. After calcination, Pt metal was recovered which might be used in fabricating new fuel cells.

The Survey on Froth Floatation of Low Grade Copper Ore from the Australia (호주산 저품위 동광의 부유선별에 관한 특성조사)

  • Kim, Joon Soo;Kim, Woo Jin;Hwang, Ha;Kim, Myong Jun;Kim, Wantae
    • Resources Recycling
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    • v.25 no.6
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    • pp.98-104
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    • 2016
  • The purpose of this study is to obtain an optimum condition of the concentrate by floatation using Australian low grade copper ore of suitable particle size by crushing, grinding and sizing. The effect of the dosage of collector, activator, depressant and change of acidity on the floatation was investigated. The floatation conditions comprising of pH 9.0 acidity, 500g/t $CuSO_4{\cdot}5H_2O$ activator, 500g/t K.E.X. collector, 1500g/t $Na_2SO_3$ depressant and 25wt.% plup density were optimized. Grade and recovery of copper in the concentrate obtained by froth floatation under optimum conditions were 4wt.% and 65wt.% respectively.

Energy production from organic waste by anaerobic treatment (I) : Hydrogen production from food waste (혐기성 처리에 의한 유기성 폐기물 에너지화 (I) : 음식폐기물의 수소화)

  • Han, Sun-Kee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.1
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    • pp.102-108
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    • 2011
  • Characteristics of hydrogen production from various food wastes in anaerobic batch reactors were evaluated to assess the energy potential of organic wastes. Organic wastes which were used in this study were scallion as vegetable, apple as fruit, rice as grain and pork as meat. Ultimate hydrogen yield of scallion, apple, rice and pork were 0.46, 0.47, 0.62 and $0.05mol\;H_2/mol\;hexose$, respectively. On the other hand, hydrogen production rates of scallion, apple, rice and pork were 0.013, 0.021, 0.014 and $0.005mol\;H_2/mol\;hexose/h$, respectively. These results indicated that anaerobic hydrogen fermentation from food waste except for meat was effective in removing organic material as well as producing renewable energy. Volatile fatty acids increased as hydraulic retention time was increased. In the hydrogen fermentation, acidification degree of rice was measured as the highest rate of 75.8% whereas pork was found as the lowest rate of 35.2%.

A Study on the Method and Application of Shaft Repair using Directed Energy Deposition Process (직접식 에너지 용착 공정을 활용한 축 보수 방법 및 활용 사례 연구)

  • Lee, Yoon Sun;Lee, Min Kyu;Sung, Ji Hyun;Hong, Myeong Pyo;Son, Yong;An, Seouk;Jeong, Oe Cheol;Lee, Ho Jin
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.9
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    • pp.1-10
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    • 2021
  • Recently, the repair and recycling of damaged mechanical parts via metal additive manufacturing processes have been industrial points of interest. This is because the repair and recycling of damaged mechanical parts can reduce energy and resource consumption. The directed energy deposition(DED) process has various advantages such as the possibility of selective deposition, large building space, and a small heat-affected zone. Hence, it is a suitable process for repairing damaged mechanical parts. The shaft is a core component of various mechanical systems. Although there is a high demand for the repair of the shaft, it is difficult to repair with traditional welding processes because of the thermal deformation problem. The objective of this study is to propose a repair procedure for a damaged shaft using the DED process and discuss its applications. Three types of cases, including a small shaft with a damaged surface, a medium-size shaft with a worn bearing joint, and a large shaft with serious damage, were repaired using the proposed procedure. The microstructure and hardness were examined to discuss the characteristics of the repaired component. The efficiency of the repair of the damaged shaft is also discussed.

Research on Improving Drying Technology For Sewage Waste Using Direct Flotation Using Heat Storage Media (축열메디아 활용 직접부상방식을 이용한 하수찌꺼기의 건조기술 향상에 관한 연구)

  • Sung-Il Noh;Ung-Yong Kim;Sung-Gyun Jo;Hyun-Gon Shin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.4
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    • pp.5-11
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    • 2023
  • This study was conducted to improve energy efficiency and problems such as clumping and fouling in the glue zone that occur in the moisture content range of 40 to 60% when sewage dehydration residue is directly fed into the dryer. The temperature of the hot air is low at 270~300℃, and the paddle-type flotation method and dehydrated residue are applied to the circulated heat storage media to increase the contact area with the hot air, thereby reducing energy recovery and gas emissions. The water content of the dried residue is 2.7. ~7 .5%, the heat of evaporation of moisture was 608.0~690.6 kcal/kg·H2O, which confirmed an energy saving effect of about 8.8% compared to the heat of evaporation of moisture of 714.5 kcal/kg·H2O when no heat storage media was used.

A Study on the new MBT management system with variations of MSW's seasonal emission characteristics (생활폐기물의 계절별 성상변화에 따른 MBT 시스템 관리에 관한 연구)

  • Min, Byong-Hoon;Chung, Chan-Kyo;Kim, Jong-Moon;Min, Dul-le;Lim, Seung-Bin;Lee, Chae-Young;Kim, Hyung-Jin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.4
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    • pp.54-63
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    • 2010
  • When MBT(Mechanical Biological Treatment) facility is designed, the management system adequate for domestic circumstance in Korea has been insufficient and power plant's load on seasonal variation has not been resolved yet. Thus, this study introduced MBT facility and MSW(Municipal Solid Waste)'s seasonal emission characteristics were investigated in order to establish new MBT management system. and additional thermal buffer-materials's calorific values were also considered to reduce the power plant's load. The results showed that the screening efficiency of MBT facility and the physical characteristics of each waste can be identified, and the calorific value by seasonal variation for MBT facility can be kept constant all the year round by using an additional thermal buffer-materials.